Iodine trifluoride dioxide
| Names | |
|---|---|
| Other names
Iodyl trifluoride
| |
| Identifiers | |
3D model (JSmol)
|
|
| |
| |
| Properties | |
| F3IO2 | |
| Molar mass | 215.898 g·mol−1 |
| Appearance | yellow crystals |
| Melting point | 41 °C (106 °F; 314 K) |
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
Main hazards
|
ignites on contact with flammable organic substances |
| Related compounds | |
Related compounds
|
Iodosyl trifluoride Iodosyl pentafluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Iodine trifluoride dioxide is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO2F3.[1][2][3] The compound was first obtained by Engelbrecht and Petersy in 1969.[4]
Synthesis
[edit]Iodine trifluoride dioxide may be formed by the reaction of HOIOF4 and oleum.[4]
Physical properties
[edit]Iodine trifluoride dioxide forms yellow crystals, which melt at 41 °C.[5] Decomposes under direct sunlight or heating.
The molecules in the crystals are dimers. The compound is monomeric above 100 °C.[6]
Chemical properties
[edit]Iodine trifluoride dioxide decomposes when heated:
- 2IO2F3 → 2IOF3 + O2
References
[edit]- ^ Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-67. ISBN 978-1-4822-0868-9. Retrieved 24 May 2023.
- ^ "iodine trifluoride dioxide". ChemSrc. Retrieved 24 May 2023.
- ^ Carter, H. A.; Ruddick, J. N.; Sams, J. R.; Aubke, F. (1 January 1975). "Some reactions of iodine(VII) dioxide trifluoride, IO2F3". Inorganic and Nuclear Chemistry Letters. 11 (1): 29–34. doi:10.1016/0020-1650(75)80142-5. ISSN 0020-1650. Retrieved 24 May 2023.
- ^ a b Advances in Inorganic Chemistry. Academic Press. 1 November 1983. p. 180. ISBN 978-0-08-057876-7. Retrieved 24 May 2023.
- ^ Downs, A. J.; Adams, C. J. (4 May 2017). The Chemistry of Chlorine, Bromine, Iodine and Astatine: Pergamon Texts in Inorganic Chemistry, Volume 7. Elsevier. p. 1395. ISBN 978-1-4831-5832-7. Retrieved 24 May 2023.
- ^ Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. Retrieved 24 May 2023.