Lithium hexafluorotitanate
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| Other names
dilithium hexafluorotitanate, titanium lithium hexafluoride
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
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PubChem CID
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| Properties | |
| F6Li2Ti | |
| Molar mass | 175.74 g·mol−1 |
| Appearance | solid |
| Density | 2.89 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lithium hexafluorotitanate is an inorganic compound of lithium, fluorine, and titanium with the chemical formula Li2TiF6.[1][2]
Synthesis
[edit]Interaction of titanium hydroxide or oxide and lithium fluoride with hydrofluoric acid.[3]
Physical properties
[edit]The compound forms crystals of tetragonal crystal system with a space group of P42/mnm (no. 136).[4]
Chemical properties
[edit]The compound forms hydrates Li3TiF6*xH2O.[5][6]
References
[edit]- ^ "Lithium Hexafluorotitanate". American Elements. American Elements. Retrieved 16 February 2024.
- ^ "LITHIUM HEXAFLUOROTITANATE". chemsrc.com. Retrieved 16 February 2024.
- ^ Tikhomirova, E. L.; Nesterov, D. P.; Gromov, O. G.; Lokshin, E. P.; Kalinnikov, V. T. (1 June 2013). "Synthesis of lithium hexafluorotitanate". Russian Journal of Applied Chemistry. 86 (6): 831–835. doi:10.1134/S1070427213060074. ISSN 1608-3296. S2CID 97687706. Retrieved 16 February 2024.
- ^ "mp-7603". Materials Project. Retrieved 16 February 2024.
- ^ Marseglia, E. A.; Brown, I. D. (15 June 1973). "Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 29 (6): 1352–1354. Bibcode:1973AcCrB..29.1352M. doi:10.1107/S0567740873004498. ISSN 0567-7408. Retrieved 16 February 2024.
- ^ Nyquist, Richard A.; Putzig, Curtis L.; Kagel, Ronald O.; Leugers, M. Anne (28 December 1971). Handbook of Infrared and Raman Spectra of Inorganic Compounds and Organic Salts: Infrared Spectra of Inorganic Compounds. Academic Press. p. 32. ISBN 978-0-12-523450-4. Retrieved 16 February 2024.