Bromyl fluoride
| Names | |
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| Other names
Bromine fluoride dioxide
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| BrFO2 | |
| Molar mass | 130.900 g·mol−1 |
| Appearance | colorless liquid |
| Melting point | −9 °C (16 °F; 264 K) |
| reacts with water | |
| Related compounds | |
Related compounds
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Iodyl fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Bromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO2F.[1][2]
Synthesis
[edit]- A reaction of K[BrF4O] with HF.[3]
- Also, reactions of BrF5 with IO2F, IOF3, and I2O5 produce BrO2F.[3]
- Hydrolysis of bromine pentafluoride at low temperatures:
- BrF5 + 2H2O → BrO2F + 4HF
Physical properties
[edit]The compound forms a colorless volatile liquid that decomposes at temperatures above 10°C. Corrodes glass at room temperature. Highly reactive and unstable.[4]
Chemical properties
[edit]- Decomposes when heated:
- 3BrO2F → BrF3 + Br2 + 3O2
- Reacts violently with water (with an explosion):
- BrO2F + H2O → HBrO3 + HF
- Reacts with alkalis:
- BrO2F + 2NaOH → NaBrO3 + NaF + H2O
References
[edit]- ^ Christe, Karl O.; Curtis, E. C.; Jacob, Eberhard (1 October 1978). "Bromyl fluoride. Vibrational spectra, force field, and thermodynamic properties". Inorganic Chemistry. 17 (10): 2744–2749. doi:10.1021/ic50188a011. ISSN 0020-1669. Retrieved 5 June 2023.
- ^ Baran, Enrique J. (January 1976). "Vibrational Properties of Bromyl Fluoride". Spectroscopy Letters. 9 (6): 323–327. doi:10.1080/00387017608067443. ISSN 0038-7010. Retrieved 5 June 2023.
- ^ a b Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN 1364-5447. Retrieved 5 June 2023.
- ^ Seppelt, Konrad (19 December 2019). "Reactions of Bromine Fluoride Dioxide, BrO 2 F, for the Generation of the Mixed‐Valent Bromine Oxygen Cations Br 3 O 4 + and Br 3 O 6 +". Angewandte Chemie International Edition. 58 (52): 18928–18930. doi:10.1002/anie.201912271. ISSN 1433-7851. PMC 6973041. Retrieved 5 June 2023.