Dioxygen monofluoride

Dioxygen monofluoride
Names
	Other names (Fluoroperoxy)radical; Fluoroperoxyl; Fluorine superoxide; Fluorodioxidanyl; ;
Identifiers
CAS Number	15499-23-7 ;
3D model (JSmol)	Interactive image;
ChemSpider	123417;
PubChem CID	139943;
CompTox Dashboard (EPA)	DTXSID50165779;
	InChI InChI=1S/FO2/c1-3-2 Key: GQRAHKRZRKCZPQ-UHFFFAOYSA-N;
	SMILES [O]OF;
Properties
Chemical formula	FO2
Molar mass	50.996 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Dioxygen monofluoride is a binary inorganic compound radical of fluorine and oxygen with the chemical formula O₂F.^[1]^[2]^[3] The compound is stable only at low temperature. This is one of many known oxygen fluorides.^[4]

Synthesis

Thermal decomposition of dioxygen difluoride:^[5]

O₂F₂ → F + O₂F

F + F → F₂

Photolysis of F₂ and O₂ dilute in argon:

F₂ → 2F

F + O₂ → O₂F

Physical properties

Dioxygen monofluoride is a strong oxidizing agent, can be prepared in the coaxial reactor.^[6]

References

^ Sen, K. D. (27 August 2011). Statistical Complexity: Applications in Electronic Structure. Springer Science & Business Media. p. 199. ISBN 978-90-481-3890-6. Retrieved 18 May 2023.
^ Campbell, G.M. (March 1990). "A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride". Journal of Fluorine Chemistry. 46 (3): 357–366. doi:10.1016/S0022-1139(00)82921-8.
^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. p. 757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.
^ Spratley, Richard D.; Turner, J. J.; Pimentel, George C. (March 1966). "Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding". The Journal of Chemical Physics. 44 (5): 2063–2068. doi:10.1063/1.1726981.
^ Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. pp. 756–757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.
^ Council, National Research; Studies, Division on Earth and Life; Resources, Commission on Geosciences, Environment and; Wastes, Molten Salt Panel of the Committee on Remediation of Buried and Tank (26 February 1997). Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts. National Academies Press. p. 104. ISBN 978-0-309-17492-3. Retrieved 18 May 2023.{{cite book}}: CS1 maint: multiple names: authors list (link)

[1] Sen, K. D. (27 August 2011). Statistical Complexity: Applications in Electronic Structure. Springer Science & Business Media. p. 199. ISBN 978-90-481-3890-6. Retrieved 18 May 2023.

[2] Campbell, G.M. (March 1990). "A kinetic study of the equilibrium between dioxygen monofluoride and dioxygen difluoride". Journal of Fluorine Chemistry. 46 (3): 357–366. doi:10.1016/S0022-1139(00)82921-8.

[3] Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. p. 757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.

[4] Spratley, Richard D.; Turner, J. J.; Pimentel, George C. (March 1966). "Dioxygen Monofluoride: Infrared Spectrum, Vibrational Potential Function, and Bonding". The Journal of Chemical Physics. 44 (5): 2063–2068. doi:10.1063/1.1726981.

[5] Ebsworth, E. A. V.; Connor, J. A.; Turner, J. J. (6 June 2016). The Chemistry of Oxygen: Pergamon Texts in Inorganic Chemistry. Elsevier. pp. 756–757. ISBN 978-1-4831-3789-6. Retrieved 18 May 2023.

[6] Council, National Research; Studies, Division on Earth and Life; Resources, Commission on Geosciences, Environment and; Wastes, Molten Salt Panel of the Committee on Remediation of Buried and Tank (26 February 1997). Evaluation of the U.S. Department of Energy's Alternatives for the Removal and Disposition of Molten Salt Reactor Experiment Fluoride Salts. National Academies Press. p. 104. ISBN 978-0-309-17492-3. Retrieved 18 May 2023.{{cite book}}: CS1 maint: multiple names: authors list (link)

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