Periodyl fluoride
| Names | |
|---|---|
| Other names
Periodylfluoride
| |
| Identifiers | |
3D model (JSmol)
|
|
PubChem CID
|
|
| |
| |
| Properties | |
| FIO3 | |
| Molar mass | 193.900 g·mol−1 |
| Appearance | colorless crystals |
| Related compounds | |
Related compounds
|
Iodosyl trifluoride Perchloryl fluoride Perbromyl fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Periodyl fluoride is an inorganic compound of iodine, fluorine, and oxygen with the chemical formula IO3F.[1] The compound has been initially synthesized around 1950.[2]
Synthesis
[edit]Synthesis of periodyl fluoride is by fluorination of KIO4 in liquid HF:[3]
- KIO4 + 2HF → IO3F + KF + H2O
Physical properties
[edit]Periodyl fluoride forms colorless crystals.[4] Decomposes at 90 to 100 °C.[5]
References
[edit]- ^ Advances in Inorganic Chemistry and Radiochemistry. Academic Press. 1 January 1963. p. 84. ISBN 978-0-08-057854-5. Retrieved 24 May 2023.
- ^ So, S. P.; Chau, F. T. (June 1973). "Urey-Bradley Force Field of Perhalyl Fluorides". Zeitschrift für Physikalische Chemie. 85 (1–4): 69–75. doi:10.1524/zpch.1973.85.1-4.069. S2CID 101872763. Retrieved 24 May 2023.
- ^ Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. Retrieved 24 May 2023.
- ^ Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-67. ISBN 978-1-4822-0868-9. Retrieved 24 May 2023.
- ^ Simons, J. H. (2 December 2012). Fluorine Chemistry V5. Elsevier. p. 91. ISBN 978-0-323-14724-8. Retrieved 24 May 2023.