Iodine sulfate
| Names | |
|---|---|
| Other names
Iodine(III) sulfate
| |
| Identifiers | |
3D model (JSmol)
|
|
| |
| |
| Properties | |
| I2(SO4)3 | |
| Appearance | Light yellow crystals |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Iodine sulfate is an inorganic compound with the formula I2(SO4)3.[1] It appears as light yellow crystals and reacts with water.
Synthesis
[edit]Reaction of diiodosyl sulfate and sulfur trioxide:[2][3][4]
- (IO)2SO4 + 2 SO3 → I2(SO4)3
Iodine sulfate is also produced when elemental I2 , I2O5 and SO3 react.[5]
Physical properties
[edit]Iodine sulfate forms light yellow hygroscopic crystals.[2][3][6]
Chemical properties
[edit]Iodine sulfate is soluble in organic liquids[3] and stable in anhydrous and strongly acidic solvents.[6] In a humid environment, it darkens due to decomposition that releases molecular iodine.[2]
References
[edit]- ^ Kasumov; Koz'min; Zefirov (1997). "Chemistry of inorganic sulfonates and sulfates of polyvalent iodine". Russian Chemical Reviews. 66 (10): 843–857. doi:10.1070/RC1997v066n10ABEH000282.
- ^ a b c Fichter; Kappeler (1915). "Neue Beobachtungen an Jodisalzen". ZAAC. 91: 134–144. doi:10.1002/ZAAC.19150910109.
- ^ a b c Argument, Cyril (1944). "The iodous sulphates". Durham theses. Durham University. pp. 22–23:
According to the equation: (IO)2SO4 + 2SO3 = I2(SO4)3 ... the yellow crystals could be isolated. They showed properties typical of a neutral iodine salt, being specially sensitive to moisture. [Fichter et al.] showed that the compound was mainly neutral iodine sulphate I2(SO4)3 ... the neutral salts have a much lighter yellow colour[,] a greater solubility in organic liquids and a greater sensitivity to water.
- ^ Selte, Kari; Kjekshus, Arne (1971). "Iodine Oxides. Part IV. Solid Compounds Formed in the Systems H2O—SO3—I2On (n=3, 4, and 5)". Acta Chem. Scand. 25 (2): 751–752. doi:10.3891/acta.chem.scand.25-0751.
- ^ Lehmann, Hans-Albert; Hesselbarth, Heinz (1959). "Zur Chemie des Schwefeltrioxyds. XI. Zur Kenntnis der SO3-Verbindungen des J2O5 und J2O4". ZAAC. 299 (1-2): 51–57. doi:10.1002/zaac.19592990107.
- ^ a b Kraszkiewicz, Lukasz; Skulski, Lech (2008). "Facile Syntheses of Symmetrical Diaryliodonium Salts from Various Arenes, with Sodium Metaperiodate as the Coupling Reagent in Acidic Media". Synthesis. 15: 2373–2380. doi:10.1055/s-2008-1067169.
- Zefirov; Sorokin; Zhdankin; Koz'min (1986). "Sul'faty trekhvalentnogo ioda - novye reagenty dlya funktsionalizatsii olefinov v tsiklicheskie sul'faty" [Sulfates of trivalent iodine - new reagents for functionalization of defins to cyclic sulfates]. Zhurnal Organicheskoj Khimii (in Russian). 22 (2): 450-452. ISSN 0514-7492.
- Adriano; Maulide (2021). "Recent discoveries on the structure of iodine(III) reagents and their use in cross-nucleophile coupling". Chemical Science (12): 853–864. doi:10.1039/D0SC03266B. PMC 8178994.
- Robinson; Woodward (2003). "Direct formation of cyclic sulfates utilising hypervalent iodine species and sulfur trioxide adducts". Tetrahedron Letters. 44 (8): 1655–1657. doi:10.1016/S0040-4039(03)00039-X. ISSN 0040-4039.