Radium sulfate

Radium sulfate
Identifiers
CAS Number	7446-16-4 ;
3D model (JSmol)	Interactive image;
ChemSpider	10745681;
PubChem CID	6365199;
	InChI InChI=1S/H2O4S.Ra/c1-5(2,3)4;/h(H2,1,2,3,4);/p-2 Key: XOROGAYSRYIXBN-UHFFFAOYSA-L;
	SMILES [O-]S(=O)(=O)[O-].[Ra];
Properties
Chemical formula	O4RaS
Molar mass	322 g·mol−1
Appearance	White solid
Solubility product (Ksp)	3.66×10−11
Related compounds
Other cations	strontium sulfate, barium sulfate, lead(II) sulfate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Radium sulfate (or radium sulphate) is an inorganic compound with the formula RaSO₄ and an average molecular mass of 322.088 g/mol.^[3] This white salt is the least soluble of all known sulfate salts.^[4] It was formerly used in radiotherapy and smoke detectors, but this has been phased out in favor of less hazardous alternatives.

Properties

Radium sulfate crystallizes in a solid in the same structure as barium sulfate. It forms crystals in the orthorhombic crystal system, with a unit cell of dimensions a = 9.13 b=5.54 and c = 7.31 Å. The unit cell volume is 369.7 Å³.^[5] Distance from the radium ion to oxygen is 2.96 Å and the sulfur to oxygen bond length in the sulfate ion is 1.485 Å. In this compound the ionic radius of the radium ion is 1.66 Å, and it is in ten coordination.^[6]

Radium sulfate can form solid solutions with the sulfates of strontium, barium or lead.^[6]

References

^ Chambers, Michael. "ChemIDplus - 7446-16-4 - MXQFUMUIEZBICJ-UHFFFAOYSA-L - Sulfuric acid, radium salt (1:1) - Similar structures search, synonyms, formulas, resource links, and other chemical information". chem.nlm.nih.gov.
^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
^ "Radium sulfate | O4RaS | ChemSpider".
^ Kirby, H. W.; Salutsky, Murrell L. (1964). The Radiochemistry of Radium (PDF). National Academies Press. p. 12.
^ Matyskin, Artem V.; Ylmen, Rikard; Lagerkvist, Petra; Ramebäck, Henrik; Ekberg, Christian (2017). "Crystal structure of radium sulfate: An X-ray powder diffraction and density functional theory study". Journal of Solid State Chemistry. 253: 15–20. Bibcode:2017JSSCh.253...15M. doi:10.1016/j.jssc.2017.05.024.{{cite journal}}: CS1 maint: multiple names: authors list (link)
^ ^a ^b Hedström, Hanna; Persson, Ingmar; Skarnemark, Gunnar; Ekberg, Christian (2013-05-22). "Characterization of Radium Sulphate". Journal of Nuclear Chemistry. 2013: 1–4. doi:10.1155/2013/940701.

[1] Chambers, Michael. "ChemIDplus - 7446-16-4 - MXQFUMUIEZBICJ-UHFFFAOYSA-L - Sulfuric acid, radium salt (1:1) - Similar structures search, synonyms, formulas, resource links, and other chemical information". chem.nlm.nih.gov.

[crc-2] John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.

[3] "Radium sulfate | O4RaS | ChemSpider".

[4] Kirby, H. W.; Salutsky, Murrell L. (1964). The Radiochemistry of Radium (PDF). National Academies Press. p. 12.

[5] Matyskin, Artem V.; Ylmen, Rikard; Lagerkvist, Petra; Ramebäck, Henrik; Ekberg, Christian (2017). "Crystal structure of radium sulfate: An X-ray powder diffraction and density functional theory study". Journal of Solid State Chemistry. 253: 15–20. Bibcode:2017JSSCh.253...15M. doi:10.1016/j.jssc.2017.05.024.{{cite journal}}: CS1 maint: multiple names: authors list (link)

[hed-6] Hedström, Hanna; Persson, Ingmar; Skarnemark, Gunnar; Ekberg, Christian (2013-05-22). "Characterization of Radium Sulphate". Journal of Nuclear Chemistry. 2013: 1–4. doi:10.1155/2013/940701.

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