Iodocyclopropane
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| Names | |
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| Preferred IUPAC name
Iodocyclopropane | |
| Other names
Cyclopropyl iodide, cyclopropyliodide
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| EC Number |
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PubChem CID
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| Properties | |
| C3H5I | |
| Molar mass | 167.977 g·mol−1 |
| Appearance | Liquid |
| Density | g/cm3 |
| Hazards | |
| GHS labelling: | |
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| H315, H319, H335 | |
| Related compounds | |
Related compounds
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Fluorocyclopropane Bromocyclopropane Chlorocyclopropane |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Iodocyclopropane is a organoiodine compound with the chemical formula C3H5I.[1][2] The compound is a member of haloalkane family.
Chemical properties
[edit]The compound reacts with benzoxazole to produce 2-cyclopropylbenzoxazole in presence of palladium catalyst.[3]
Uses
[edit]Iodocyclopropanes are used as synthetic intermediates to synthesize many alkyl, aryl, and acyl substituted cyclopropanes via organometallic reactions.[4]
See also
[edit]References
[edit]- ^ "Iodocyclopropane". Manchester Organics. Retrieved 31 May 2023.
- ^ "Iodocyclopropane". Sigma Aldrich. Retrieved 31 May 2023.
- ^ Wu, Xiaojin; Lei, Chuanhu; Yue, Guizhou; Zhou, Jianrong Steve (10 August 2015). "Palladium-Catalyzed Direct Cyclopropylation of Heterocycles". Angewandte Chemie International Edition. 54 (33): 9601–9605. doi:10.1002/anie.201504735. hdl:10356/89367. PMID 26179255.
- ^ Martin, Stephen F.; Dwyer, Michael P. (19 March 1998). "Iodocyclopropanes as versatile intermediates for the synthesis of substituted cyclopropanes". Tetrahedron Letters. 39 (12): 1521–1524. doi:10.1016/S0040-4039(98)00072-0. ISSN 0040-4039. Retrieved 31 May 2023.