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Nitrate chlorides

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Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3−) and chloride (Cl−) ions. Various compounds are known, including amino acid salts,[1] and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides, and would be termed chlorido nitrato complexes.

Formation

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Nitrate chloride compounds may be formed by mixing solutions of chloride and nitrate slats, the addition of nitric acid to a chloride salt solution, or the addition of hydrochloric acid to a nitrate solution. Most commonly water is used as a solvent, but other solvents such as methylene dichloride, methanol or ethanol can be used.

Minerals

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name formula ratio

NO3:Cl

mw system space group unit cell Å volume density optical references
Buttgenbachite Cu19(NO3)2(OH)32Cl4 · 2H2O 2:4 hexagonal P63/mmc a = 15.75 Å, c = 9.161 Å Z=1 1968 4.538 Blue

Uniaxial (+) nω = 1.738 nε = 1.752

birefringence: δ = 0.014

[2][3]
Lislkirchnerite Pb6Al(OH)8Cl2(NO3)5·2H2O 5:2 monoclinic P21/n a = 10.7834(6) Å, b = 9.0584(5) Å, c = 13.6178(9) Å

β = 102.28(2)°

1300 [4]
Sveite KAl7(NO3)4(OH)16Cl2 · 8H2O 4:2 Monoclinic a = 10.89 Å, b = 13.04 Å, c = 30.71 Å

β = 92.1°

4,358 white

Biaxial (+) nα = 1.501 nβ = 1.503 nγ = 1.535

2V: calculated = 30°

Max Birefringence = δ = 0.034

[5]
Pb8O3(OH)5(NO3)4Cl 4:1 Monoclinic a = 14.831(3) Å, b = 7.659(2) Å, c = 10.186(2) Å

β = 108.64(3)°

1096 colourless [6]

List

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name formula ratio

NO3:Cl

mw system space group unit cell Å volume density comment references
Chlorine nitrate O2NOCl orthorhombic P212121 a = 3.856 b = 6.755 c = 12.07 Z=46 314.5 2.058 at −166 °C (related compound) [7]
anilinium chloride nitrate (C6H8N)2ClNO3 1:1 triclinic P1 a = 8.418 b = 9.648 c = 10.036 α = 62.993° β = 86.798° γ = 72.999° [8]
o-Phenylenediaminium chloride nitrate orthorhombic Pnma a = 7.3695 b = 8.2367 c = 14.2398 Z=4 864.36 1.596 [9]
l-lysinium(2+) chloride nitrate L-Lys2+·Cl−·NO3- 1:1 monoclinic P21 a 8.8022 b 7.0096 c 20.2169 β 95.226° [10]
L-Lysine L-lysinium dichloride nitrate 2C6H15N2O2+·H+·NO3-·2Cl- 1:2 428.32 orthorhombic P212121 a 4.9846 b 20.604 c 20.663 Z=4 2122.1 1.341 colourless [11]
L-cysteinium sodium nitrate chloride 1:1 monoclinic P21 a=18.5, b=5.22, c=7.22 β=103.83° 678 transparent from 328 to 1400nm; SHG 0.51 ×KDP [12]
Bis(L-ornithinium) chloride nitrate sulfate 2C5H14N2O22+·Cl-·NO3-·SO42- 461.88 monoclinic C2 a 13.872 b 9.578 c 9.178 β 125.35° Z=2 994.6 1.542 [13]
(μ4-octahydroxycucurbit(5)uril)-(μ2-nitrato)-aqua-di-potassium chloride nonahydrate {[K(H2O)](NO3⊂C30H28N20O20)[K(η2-NO3)]}Cl(H3O)22+·7H2O monoclinic P21/c a 13.8265 b 14.2642 c 25.143 β 92.711° Z=4 4953.2 1.806 colourless [14]
Thecotrichite Ca3(CH3COO)3Cl(NO3)2 • 6H2O 2:1 monoclinic P21/c a 23.5933 b 13.8459 c 6.8010 β 95.195° Z=4 2212.57 anthropogenic, formed on ceramics in damp wooden cupboards;

refractive index: nx = 1.491 nz = 1.494 stable to 110°C

[15]
di-μ-hydroxido-bis[triaqua(nitrato-κ2O,O′)scandium(III)] dichloride [Sc2(NO3)2(OH)2(H2O)6]Cl2 1:1 426.95 triclinic P1 a=6.7221 b=7.6279 c=8.5181 α=100.904° β=110.125° γ=102.329° Z=1 383.87 1.847 colourless @100K [16]
[Fe(Cl)4](Fe(NO3)2(OPPh2py)2 [17]
[Fe(NO3)2(Cl)(OPPh2py)]· CH2Cl2 monoclinic P21/n a 9.138 b 15.69 c 16.68 β 94.50° [17]
hexamethylphosphoric triamide Fe(NO3)2(Cl)(HMPA)1.5 [18]
hexamethylphosphoric triamide Fe(NO3)2(Cl)(HMPA)2 [18]
hexamethylphosphoric triamide Fe(NO3)(Cl)2(HMPA)2 monoclinic P21/c a 15.994 b 10.172 c 16.571 β 104.7° [18]
pypn=N,N′-bis(2-pyridylmethyl)-1,3-propanediamine

(N,N'-bis((pyridin-2-yl)methyl)propane-1,3-diamine)-dichloro-iron(iii) nitrate

[Fe(pypn)Cl2](NO3) monoclinic P21/c a 11.848 b 12.474 c 12.301 β 94.56° Cl in cis position [19]
pentaamminenitrocobalt(III) chloride nitrate [Co(NH3)5NO2](NO3)Cl orthorhombic Pnam a 14.814 b 9.623 c 7.309 @290K; photosalient (jumps under UV) [20][21][22]
trans-Dichloro-bis(ethylenediamine)-cobalt(III) nitrate [Co en2Cl2]NO3 monoclinic P21/n a = 6.348 b = 9.304 c = 9.853 β = 101.79° 569.6 1.82 green [23][24]
cis-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate [Co(en)2(NH3)Cl](NO3)2 [25]
trans-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate [Co(en)2(NH3)Cl](NO3)2 [25]
5-nitrosalicyliddineaminato tetraamino cobalt dichloride nitrate orange [26]
cis-Chlorobis(ethylenediamine)dodecylaminecobalt(III) nitrate cis-[Co(en)2(C12H25NH2)Cl](NO3)2 [27]
bis(1,4,7-triazacyclononane) nickel(ii) nitrate chloride monohydrate [Ni([9]aneN3)2](NO3)Cl·H2O orthorhombic Pna21 a 17.584 b 8.860 c 12.141 [28]
Bis[chlorobis(1,10-phenanthroline-N,N')(thiourea-S)nickel(II)] chloride nitrate diethanol solvate [NiCl(C12H8N2)2(CH4N2S)]2(NO3)Cl·­2C2H6O orthorhombic Fdd2 a 22.813 b 29.024 c 17.113 Z=8 11331 1.467 blue [29]
Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-nickel(ii)) clathrate chloride trinitrate undecahydrate {[C14H17N2Ni(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl2(NO3)6·22H2O triclinic P1 a 16.671 b 16.678 c 20.442 α 112.772° β 101.844° γ 90.102° [30]
bis(bis(1,4,7-triazacyclonon-1-yl)pentane)-di-nickel(ii) trichloride nitrate pentadecahydrate [Ni2(EM5)2]Cl3NO3·15H2O orthorhombic Pbcn a 28.030 b 17.469 c 12.289 [31]
bis(bis(1,4,7-triazacyclonon-1-yl)hexane)-di-nickel(ii) dichloride dinitrate hexahydrate [Ni2(EM6)2]Cl3(NO3)2·6H2O triclinic P1 a 9.529 b 9.566 c 14.684 α 81.08° β 78.84° γ 88.82° [31]
dapsc = 2,6-diacetylpyridine-bis(semicarbazone)) [Ni(dapsc)(H2O)2]Cl(NO3)·H2O triclinic P1 a=6.9130 b=12.3410 α=114.8010 β=93.946 γ=103.7760 Z=2 933.10 1.735 green [32]
hexakis(1H-imidazole)-nickel(ii) chloride nitrate tetrahydrate [Ni(Im)6][(NO3)Cl(H2O)4] hexagonal P63m a 9.003 c 21.034 [33]
bis(M-2-chloro)-(nitrato-o)-(2,2 '-bipyridine-N.N ')-copper(II) Cu(2,2 '-BP)Cl NO3 triclinic P1 a = 7.515 b = 9.253 c = 10.283 α=112.181° β= 102.155° γ= 105.617° Z=2 597.4 1.769 green; dimer [34]
bis(M-2-chloro)-(nitrato-o)-(2,2 '-4,4'-dimethylbipyridine-N.N ')-copper(II) Cu(2, 2'-dmBP)ClNO3 dimer [34]
Chloro(1,10-phenanthroline-2-carboxamide oxime)copper(II) Nitrate [35]
bis(μ2-2,4,4,6,6-pentakis(2-pyridyloxy)cyclo-2,4,6-triphosphazene 2-oxide)-dichloro-nitrato-cobalt(ii)-di-copper chloride [{(N3P3(OC5H4N)5(O)CuCl)2Co(NO3)}Cl] orthorhombic Fddd a =22.639 b =28.202 c =45.260 [36]
Copper(II)–sparteine nitrate chloride CuII{(−)Sp}(NO3)Cl orthorhombic P212121 a 16.370 b 13.334 c 7.6803 [37]
Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-copper(ii)) clathrate dichloride dinitrate hexadecahydrate {[C14H17N2Cu(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl4(NO3)4·32H2O triclinic P1 a 16.607 b 17.093 c 20.509 α 66.003° β 77.568° γ 89.155° [30]
copper(II)-di-2-pyridylamine complex chloride nitrate

(μ2-Chloro)-(nitrato-O)-(bis(2-pyridyl)amine-N,N')-copper(ii) hemihydrate

[Cu(dipyam)Cl(NO3)].0.5H2O monoclinic P21/a a 7.382 b 21.494 c 8.032 β 94.26 [38]
tipa=tri(4-imidazolylphenyl)amine

(μ3-tris(4-(Imidazol-1-yl)phenyl)amine)-chloro-zinc nitrate dimethylformamide solvate

[Zn(tipa)Cl]⋅NO3⋅2 DMF orthorhombic Pnna a=28.470 b=27.784 c=9.255 7321 1.044 [39]
Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 2:1 1029.39 hexagonal P63/mcm a = 9.5732 c = 15.820 Z=2 1255.6 2.723 UV cut off 231 nm; uniaxial; birefringence 0.14 @ 546 nm [40]
KRb2(NO3)2Cl 2:1 369.51 orthorhombic pbam a=12.1863 b=12.4072 c=5.8203 Z=4 880.02 2.789 transparent; birefringence = 0.084 at 1064 nm [41]
[Ru(NH3)5Cl](NO3)2 tetragonal I4 a = 7.5811 b = 7.5811 c = 10.535 605.5 1.896 yellow [42]
[RuNO(NH3)3(H2O)Cl](NO3)2 monoclinic Cc a = 13.7924 b = 6.9114 c = 12.3577 β = 111.863° Z = 4 1093.27 2.185 [43]
bis((μ2-chloro)-(nitrato)-(η5-pentamethylcyclopentadienyl)-rhodium(iii)) [Cp*Rh(η1-NO3)(μ-Cl)]2 monoclinic P21/n a 8.3874 b 10.4549 c 14.8585 β 104.385° [44]
chloro-(cyclohexylisocyano)-(η5-pentamethylcyclopentadienyl)-(triphenylphosphine)-rhodium nitrite nitrate dihydrate {[Cp*RhCl(PPh3)(CNC6H11)]2(NO2)(NO3)}·2H2O triclinic P1 a 10.319 b 10.5582 c 17.371 α 97.011° β 94.35° γ 112.154° [44]
[Rh(NH3)5Cl](NO3)2 tetragonal I4 a = 7.5858 b = 7.5858 c = 10.41357 Z=2 599.24 1.926 yellow [42]
bis(μ2-4'-(4-pyridyl)-2,2':6',2''-terpyridine)-bis(η5-pentamethylcyclopentadienyl)-tetra-chloro-di-rhodium-nickel dinitrate methanol solvate dihydrate {Cp*2Rh2[Ni(pyterpy)2]Cl4}(NO3)2 monoclinic C2/c a 53.4454 b 8.8419 c 33.7700 β 112.029° [45]
cis-dichlorobis(ethylenediamine)rhodium(III) nitrate [Rh(en)2Cl2]NO3 triclinic P1 a=8.619 b=6.528 c=11.687 α=I02.18 β=90.98 γ=112.46 Z=2 590.5 2.00 yellow [46]
trans-dichlorobis(ethylenediamine)rhodium(III) nitrate [Rh(en)2Cl2]NO3 monoclinic P21/n a = 6.441 b=9.281 c=10.010 β=102.42 Z=2 584.4 2.02 orange [46]
L=3,6,9,16,19,22-hexaazatricyclo[22.2.2.211,14]triacon-11,13,24,26(1),2 7,29-hexaene

(μ2-3,6,9,16,19,22-Hexa-azatricyclo(22.2.2.211,14)triaconta-1(26),11,13,24,27,29-hexaene)-dichloro-di-palladium(ii) dinitrate monohydrate

[Pd2LCl2](NO3)2·H2O monoclinic P2/c a 21.744 b 9.243 c 16.259 β 93.580° [47]
en=Ethylenediamine py=pyridine [Pd(en)(py)Cl]NO3 monoclinic P21/c a = 7.990, b = 16.058, c = 9.846 β = 103.81° Z = 4 [48]
4-Methylpyridine, [Pd(en)(4-Me-py)Cl]NO3 [48]
4-hydroxy-pyridine [Pd(en)(4-OH-py)Cl]NO3 [48]
4-NH2-py=4-aminopyridine [Pd(en)(4-NH2-py)Cl]NO3 [48]
tetrakis(μ-tris((diphenylphosphino)methyl)amine)-tetrachloro-pentadeca-silver tris(nitrate) octahydrate [Ag15(N-triphos)4(Cl4)](NO3)3 3649.32 orthorhombic C2221 a 18.702 b 36.975 c 28.652 Z=6 19813 1.835 [49]
bis(tetrakis(Triphenylphosphine)-silver) chloro-diphenyl-bis(nitrato-O,O')-tin diphenyl-tris(nitrato-O,O')-tin [Ag(PPh3)4][SnPh2(NO3)2(Cl,NO3)] triclinic P1 a 22.43 b 14.13 c 13.96 α 90.59° β 69.82° γ 64.58° [50]
barium chloride nitrate Ba(NO3)Cl orthorhombic Pnma a 8.9108 b 5.2991 c 8.3414 UV cutoff 213 nm; birefringence 0.009 @ 1064 nm [51]
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine [La(H2LSS)(NO3)2Cl]·2CH2Cl2 tetragonal P43212 a = 18.1798 c = 16.4174 Z=4 5426.0 1.150 [52]
tris(μ2-N',N''-((5-Chloro-2-oxy-1,3-phenylene)dimethylylidene)bis(benzohydrazide))-bis(ethanol)-di-lanthanum dinitrate chloride acetone solvate dihydrate [La2(H2L1)3(C2H5OH)2]·(Cl)·(NO3)2·((CH3)2CO)2·(H2O)2 monoclinic C2/c a 21.1020 b 18.5070 c 23.1880 β 114.452° [53]
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine [Ce(H2LSS)(NO3)2Cl]·2CH2Cl2 tetragonal P43212 a = 18.216 c = 16.483 Z=4 5469.6 1.147 [52]
Chloro-nitrato-pentakis(tetrahydrofuran)-cerium(iii) pentachloro-(tetrahydrofuran)-cerium(iv) [CeCl(NO3)(THF)5]+[CeCl5(THF)]− monoclinic P2/c a 12.138 b 11.299 c 14.066 β 104.31° [54]
Praseodymium dichloride nitrate pentahydrate [PrCl2(H2O)6][PrCl2(NO3)2(H2O)4] monoclinic P2/c a = 12.288 b = 6.484 c = 12.660 β = 91.91° Z = 4 green [55]
L=N,N′‐bis (salicylidene)‐1,2‐cyclohexanediamine [Pr(H2L)2(NO3)2Cl]·2CH2Cl2 941.14 tetragonal P43212 a=18.0936 c=16.3490 Z=4 5352.3 1.168 [56]
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine [Nd(H2LSS)(NO3)2Cl]·2CH2Cl2 tetragonal P43212 a = 18.1041 c = 16.4374 Z=4 5387.5 1.164 [52]
Chloro-bis(nitrato-O,O')-bis(tetramethyl (t-butyl(hydroxy)methylene)-bis(phosphonate)-O,O')-neodymium(iii) NdCl(NO3)2{[(MeO)2PO]2C(OH)tBu}2 monoclinic P21/a a 17.0961 b 9.3040 c 24.4989 β 110.244° [57]
tri-sodium hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-triacontakis(μ-2-thiophenecarboxylato)-tetrakis(2-thiophenecarboxylato)-decakis(μ-glycinato)-diglycine-docosa-aqua-octatetraconta-europium(iii) nitrate hexachloride 2-thiophenecarboxylic acid pentahydrate Na3[Eu48O6(OH)84(tca)34(gly)12(H2O)22]·2Htca·6Cl·6H2O·NO3 15118.80 triclinic P1 a 20.720 b 23.227 c 24.562 α 88.66° β 71.76° γ 63.57° Z=1 9960 2.500 [58]
sodium tetradecakis(μ-3-hydroxy-2-(hydroxymethyl)-2-methylpropanoato)-hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-octadecakis(μ-2-thiophenecarboxylato)-octakis(2-thiophenecarboxylato)-tetracosa-aqua-octatetraconta-terbium(iii) nitrate octakis(chloride) Na[Tb48O6(OH)84(fca)26(dmp)14(H2O)24]·4Hfca·NO3·8Cl 15154.02 monoclinic P21/n a 24.0145 b 32.9221 c 25.6605 β 97.521° Z=2 20112.9 2.490 [58]
L=2-methyl-8-hydroxyquinoline

tetrakis(μ-2-methylquinolin-8-olato)-(μ-chloro)-ethanol-dinitrato-di-nickel(ii)-dysprosium(iii) acetonitrile solvate

[Ni2IIDyIII(EtOH)(L2)4(NO3)2Cl] ⋅ CH3CN triclinic P1 a 11.1201 b 14.1566 c 15.448 α 78.625° β 73.918° γ 81.055° [59]
(tetrakis(μ-(1-phenylethyl)ammoniomethylphosphonato)-chloro-nitrato-di-erbium R- or S-[Er2(pempH)4(NO3)Cl] orthorhombic P21212 a 15.986 b 32.069 c 9.1593 quadruple stranded helix [60]
[{trans-PtCl(NH3)2}{μ-(H2N(CH2)6NH2)}{trans-PdCl(NH3)2](NO3)Cl yellow [61]
[{trans-PtCl(NH3)2}2{trans-Pt(thiazole)2}{H2N(CH2)6NH2}2]Cl3(NO3) [62]
[PtPy2(NH=CH-OH)Cl3]NO3 orthorhombic P212121 a = 10.381 b = 11.776 c = 13.848 Z = 4 1692.9 [63]
alpha pyridone cis-[Pt(NH3)2(C5H4NOH)Cl](NO3) triclinic P1 a=10.706 b=12.552 c=4.151 α =95.57° β=92.32° γ=99.05° Z=2 547.4 2.558 white needles [64]
[PtIV(trans-1R,2R-diaminocyclohexane)trans-(acetate)2(9-ethylguanine)Cl]NO3 · H2O P21 a = 10.446 b = 22.906 c = 10.978 Z = 4 [65]
Chloro-(homopiperazine)-(diphenylsulfido)-platinum(ii) nitrate [PtII(homopiperazine)(diphenylsulfide)Cl]NO3 monoclinic P21/c a 17.666 b 8.812 c 12.619 β 101.02° [66]
mmap=1-methyl-4-(methylamino)piperidine [Pt(mmap)(CH3)2S)Cl](NO3) white [67]
dhq=decahydroquinoline [Pt(dhq)(CH3)2S)Cl](NO3) [67]
[La(NO3)2(H2O)6]2[PtCl6]·2H2O monoclinic P21/c a = 6.974 b = 16.545 c = 13.177 β = 93.97° Z=2 yellow [68]
[Pr(NO3)2(H2O)6]2[PtCl6]·2H2O monoclinic P21/c a = 6.955 b = 16.525, c = 13.18.5 β = 93.93° Z=2 yellow [68]
[Gd(NO3)(H2O)7][PtCl6]·4H2O monoclinic P21/n a = 8.3872 b = 21.3198 c = 11.4263 β = 95.670° Z=4 yellow [68]
[Dy(NO3)(H2O)7][PtCl6]·4H2O monoclinic P21/n a = 8.3840 b = 21.3950 c = 11.4310 β = 95.698° Z=4 yellow [68]
Ir[NO3]2Cl[NH3]5 tetragonal I4 a = 7.6061 c = 10.4039 601.89 2.410 yellow [42]
{Cp*2Ir2[Ni(pyterpy)2]Cl4}(NO3)2 [45]
Dichloro(ethylenediamine)gold(III) nitrate [Au(NH2CH2CH2NH2)Cl2]NO3 orthorhombic Pbca a = 10.338 b = 8.2105 c = 19.625 Z=8 [69]
(2,2'-Bipyridine)dichlorogold(III) nitrate [AuCl2(C10H8N2)]NO3 486.06 monoclinic C2/c a 6.9240 b 14.0460 c 13.0560 β 96.562° Z=4 1261.44 2.559 pale yellow [70]
Bis(methy1 L-cysteineato)mercury(II) hydrochloride hydronitrate monohydrate (C4H9NO2S)2ClHgNO3•H2O [71]
chloronitrato-2-{2′-[(1′-methyl)benzimidazolyl]}- 4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxidemercury(II) – mercury(II)chloride HgCl(NO3)(C15H19N4O2) · HgCl2 triclinic P1 a=9.922 b=10.822 c=11.460 α=107.518° β=102.046° γ=96.639° Z=2 1126.5 black [72]
caesium mercuric nitrate chloride CsHgNO3Cl2 1:2 466.41 hexagonal P63/mmc a=5.8817 c=11.3920 Z=2 341.30 4.538 birefringent Δn = 0.145@546 nm [73]
4-chloropyridinium (C5H5NCl)2[UO2Cl3(NO3)] 1:3 triclinic P1 a=6.819 b=10.781 c=14.252 α=72.890° β=80.394° γ=74.456° Z=2 960.3 2.308 [74]
4-bromopyridinium (C5H5NBr)2[UO2Cl3(NO3)] 1:3 756.41 monoclinic P21/m a =9.739 b =16.484 c =12.950 β =102.360° Z=4 2030.8 2.474 [74]
4-iodopyridinium (C5H5NI)3[UO2Cl3(NO3)](NO3) 2:3 559.20*2 monoclinic P21/c a =7.9797 b =25.043 c =14.730 β =103.019° Z=4 2868.0 2.590 [74]
pyr2phen = N,N′-bis-(pyridoxylideneiminato)2−phenylene

(N-(3-Hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-ylmethylidene)-N'-(5-(hydroxymethyl)-2-methyl-3-oxypyridin-4-ylmethylidene)-o-phenylenediamine-N,N',O,O')-chloro-dioxo-uranium nitrate dihydrate

[UO2(H2pyr2phen)Cl]NO3 triclinic P1 a 9.231 b 11.855 c 14.026 α 114.8° β 94.012° γ 97.95° [75]
K3[(UO2)(NO3)Cl3](NO3) monoclinic P21 a 7.8596 b 15.8675 c 10.6823 β 90.141° Z=4 1332.21 3.08 [76]
Cs2(UO2)(NO3)Cl3 1:3 704.21 monoclinic P21/n a=10.375 b=9.468 c=12.553 β= 110.280 Z=4 1156.7 4.04 lemon yellow [77]
bis(4-iodo-pyridinium) dinitrato-tetrachloro-plutonium(iv) (C5H5NI)2[Pu(IV)Cl4(NO3)2] triclinic P1 a =9.8096 b=10.1402 c=11.5033 73.416  82.364 87.100 Z=2 1086.8 2.811 orange [78]
bis(pyridinium) trinitrato-trichloro-plutonium(iv) (C5H6N)2[Pu(IV)Cl3(NO3)3] 694.60 monoclinic P21/c a 17.268 b 7.7622 c 15.112 β 97.598° Z=4 2007.8 2.298 dark red [78]
bis(4-chloro-pyridinium) dioxo-trichloro-nitrato-plutonium(vi) (C5H5NCl)2[Pu(VI)O2Cl3(NO3)] 671.46 triclinic P1 a 6.7493 b 10.8107 c 14.171 α 73.657° β 81.412° γ 75.206° Z=2 956.0 2.333 yellow [78]

References

[edit]
  1. ^ Fleck, Michel; Petrosyan, Aram M. (2014). Salts of amino acids: crystallization, structure and properties. Cham Heidelberg: Springer. pp. 495–506. ISBN 978-3-319-06298-3.
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