Niobium(V) oxynitrate

Niobium(V) oxynitrate
Names
	Other names Niobyl nitrate; Niobium oxytrinitrate;
Identifiers
CAS Number	100456-47-1 ;
3D model (JSmol)	Interactive image;
EC Number	623-412-8;
	InChI InChI=1S/3NO3.Nb.O/c32-1(3)4;;/q3-1;+3; Key: XWRVJMHGWNZEAR-UHFFFAOYSA-N;
	SMILES [Nb](O[N+]([O-])=O)(O[N+]([O-])=O)(O[N+]([O-])=O)=O;
Properties
Chemical formula	NbO(NO3)3
Molar mass	294.92 g/mol
Appearance	White solid
Melting point	120 °C (248 °F; 393 K) (decomposes)
Solubility in water	Reacts
Solubility	Slightly soluble in diethyl ether, MeCN, and benzene
Structure
Crystal structure	Tetragonal
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H272, H315, H319, H335
Related compounds
Other anions	Niobium oxychloride
Other cations	Vanadyl nitrate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Niobium(V) oxynitrate is an inorganic compound with the proposed formula NbO(NO₃)₃. A single publication claims that niobium(V) oxynitrate is produced by the reaction of niobium pentachloride and dinitrogen pentoxide at 30 °C:^[1]

NbCl₅ + 4N₂O₅ → NbO(NO₃)₃ + 5NO₂Cl

Nitryl chloride is produced as a byproduct.

Attempts failed to produce niobium(V) oxynitrate by the reaction dinitrogen tetroxide and niobium pentachloride in acetonitrile in the formation of the acetonitrile niobium dioxide nitrate complex.^[2]

References

^ ^a ^b ^c ^d ^e B. O. Field; C. J. Hardy (1963). "Trinitratoniobium(V) Oxide, NbO(NO₃)₃". Proceedings of the Chemical Society: 11. doi:10.1039/PS9630000001.
^ K. W. Bagnall; D. Brown; P. J. Jones (1964). "Niobium(V) and tantalum(V) nitrates". Journal of the Chemical Society (451): 2396–2400. doi:10.1039/JR9640002396.

[nb-1] B. O. Field; C. J. Hardy (1963). "Trinitratoniobium(V) Oxide, NbO(NO₃)₃". Proceedings of the Chemical Society: 11. doi:10.1039/PS9630000001.

[com-2] K. W. Bagnall; D. Brown; P. J. Jones (1964). "Niobium(V) and tantalum(V) nitrates". Journal of the Chemical Society (451): 2396–2400. doi:10.1039/JR9640002396.

[1]

[2]