Zirconium diphosphide
| Identifiers | |
|---|---|
3D model (JSmol)
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| |
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| Properties | |
| P2Zr | |
| Molar mass | 153.172 g·mol−1 |
| Appearance | grey crystals |
| insoluble | |
| Related compounds | |
Related compounds
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Zirconium monophosphide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Zirconium diphosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP2.[1]
Preparation
[edit]Zirconium diphosphide can be obtained from arc-melting of zirconium with red phosphorus:[2]
- 2 Zr + P4 → 2 ZrP2
Physical properties
[edit]Zirconium diphosphide forms grey crystals that is insoluble in water. Zirconium diphosphide is very toxic.[3] Has a lead(II) chloride crystal structure.[4][2][5] It dissolves in warm concentrated sulfuric acid. It decomposes into phosphorus and ZrP when heated in vacuum:[6]
- ZrP2 → ZrP + P
References
[edit]- ^ Chemical Thermodynamics of Zirconium. Elsevier. 6 December 2005. p. 477. ISBN 978-0-08-045753-6. Retrieved 7 March 2024.
- ^ a b Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3769. ISBN 978-0-412-30120-9. Retrieved 7 March 2024.
- ^ Grushko, Ya M. (28 May 1992). Handbook of Dangerous Properties of Inorganic And Organic Substances in Industrial Wastes. CRC Press. p. 750. ISBN 978-0-8493-9300-6. Retrieved 7 March 2024.
- ^ "Crystal structure of zirconium diphosphide, ZrP 2". Zeitschrift für Kristallographie - Crystalline Materials. 209 (4): 370. 1 April 1994. doi:10.1524/zkri.1994.209.4.370. Retrieved 7 March 2024.
- ^ "mp-1523: ZrP2 (orthorhombic, Pnma, 62)". Materials Project. Retrieved 7 March 2024.
- ^ "циркония дифосфид - свойства, реакции". chemister.ru. Retrieved 7 March 2024.