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wikipedia page https://en.wikipedia.org/wiki/History_of_the_internal_combustion_engine says:
"Also in 1794 Robert Street patented an internal combustion engine, which was also the first to use the liquid fuel"
wikipedia page https://en.wikipedia.org/wiki/Barsanti-Matteucci_engine says:
"Luigi de Cristoforis, described in a paper published in the acts of the Lombard Royal Institute of Science, Literature and Art, a pneumatic machine (later built and shown to work) that ran on naphtha and an air mixture, and which constituted the first liquid fuel engine."