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Nitrate nitrite

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A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO−2) and nitrate (NO−3) anions. They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.[citation needed]

Production

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Mercury(II) nitrate and potassium nitrate in water solution produce the salt tripotassium tetranitratomercurate(II) nitrate K3[Hg(NO2)4]NO3.[1]

Properties

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On heating, nitrate nitrites lose NO2 and NO and yield metal oxides.

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Other compounds having an element in two different anion states include the sulfate sulfites, the phosphate phosphites, arsenate arsenites and the selenate selenites.

List

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name formula ratio

NO3:NO2

mw system space group unit cell Å volume density properties references
[Cr(NH3)5(NO2)] ·(NO3)2 [2]
trans-dinitrotetraamminecobalt(III) nitrate monohydrate [Co(NO2)2(NH3)4]NO3•H2O 1:2 orthorhombic P212121 a=10.02, b=6.02, c=16.84, Z=4 1.84 [3]
cis-dinitrotetraamminecobalt(III) nitrate [Co(NO2)2(NH3)4]NO3 1:2 orthorhombic P212121 a=12.19, b=7.18, c=10.92, Z=4 1.95 [4]
[cis-β-Co(trien)(NO2)2]NO3 1:2 monoclinic P21/n a = 7.604, b = 13.019, c = 14.472, β = 98.13°, Z = 4 1418.26 1.682 racemate [5]
[cis-α-Co(tren)(NO2)2]NO3•13H2O 1:2 P21/c [6]
trans-Co[(en2)(NO2)2]NO3 1:2 [7]
trans-[Co(2,3,2-tet)(NO2)2]NO3 1:2 373.21 P21/n a=8.490, b=8.884, c=18.580 and β=95.08°;, Z=4 1395.89 1.776 [8]
trans-[Co(2,3,2-tet)(NO2)2]NO3 373.21 Pn a=6.493, b=11.731, c=9.325 β=100.13°; M.W.=373.21, Z=2)= 699.21 1.773 [8]
cis-[Co(Hao)2(NO2)2]NO3 (Hao = 3-amino-3-methyl-2-butanone oxime) monoclinic P21/n a= 8.1 60, b= 17.250, c= 13.745, β= 104.77° [9]
[Co(pic)2(NO2)2]NO3.½H2O pic=2-picolylamine [10]
cis-[Co(phen)2(NO2)2]NO3 · 2 H2O phen=1,10-phenanthroline [11]
Sparteine copper(II) nitrate nitrite Cu(C15H26N2)(NO3)(NO2) 1:1 green [12]
trans-diammine-cis-dinitratonitronitrosyl ruthenium(II) RuNO(NH3)2(NO3)2(NO2)
bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate [Pd(NO2)(NH3)3]2[Pd(NH3)4](NO3)4 4:1 829.20 tetragonal I42m a=7.637 c=21.610 Z=2 2.18 bright yellow [13]
bis(1,10-Phenanthroline)-(nitroso-O)-(nitrato-O,O')-cadmium(ii) Cd(phen)2(NO3)(NO2) monoclinic P21/c a 6.872 b 9.690 c 20.852 β 93.59° [14]
catena-((μ2-Nitroso-O,O')-aqua-(nitrato-O,O')-(1,10-phenanthroline)-cadmium(ii)) [Cd(phen)(NO3)(NO2)(H2O)]n monoclinic Cc a 11.703Å b 15.242 c 13.451 β 106.321° [14]
[NO2(NH3)2Pt(C5H4NO)2Pt(NH3)2NO2](NO3)2.H2O yellow [15]
K3[Hg(NO2)4]NO3 1:4 orthorhombic Pnma a=12.12 b=10.58 c=9.28 Z=4 3.14 pale yellow [1]
Pb2(NO2)(NO3)(SeO3) 1:1 orthorhombic Pmn21 a=5.529, b=10.357, c=6.811, Z=2 390 colourless [16]
K2Pb(NO2)3(NO3) 1:3 503.4 orthorhombic Pbca a = 6.766, b = 11.999, c = 26.61, Z = 8 2160 3.095 yellow orange [17]
[Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O 1:4 orthorhombic Pbca a = 8.9414, b = 14.5330, c = 24.9383, Z = 8 3240.6

References

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  1. ^ a b Hall, D.; Holland, R.V. (January 1969). "The crystal structure of K3[Hg(NO2)4]NO3". Inorganica Chimica Acta. 3: 235–238. doi:10.1016/S0020-1693(00)92486-1.
  2. ^ Shepard, Whiting N.; Forster, Leslie S. (1971). "The2 E?4 A 2 transition in tetragonal Cr3+ complexes". Theoretica Chimica Acta. 20 (2): 135–142. doi:10.1007/BF00569260. ISSN 0040-5744. S2CID 95534463.
  3. ^ Oonishi, Isao; Muto, Fumio; Komiyama, Yoshimichi (October 1969). "The Molecular and Crystal Structure of trans -Dinitrotetramminecobalt(III) Nitrate Monohydrate". Bulletin of the Chemical Society of Japan. 42 (10): 2791–2796. doi:10.1246/bcsj.42.2791. ISSN 0009-2673.
  4. ^ Oonishi, Isao; Fujimaki, Hiroto; Muto, Fumio; Komiyama, Yoshimichi (March 1970). "The Crystal Structure of cis -Dinitrotetraamminecobalt (III) Nitrate". Bulletin of the Chemical Society of Japan. 43 (3): 733–739. doi:10.1246/bcsj.43.733. ISSN 0009-2673.
  5. ^ Bernal, Ivan; Cetrullo, James (October 1986). "The phenomenon of conglomerate crystallization. VII. Clavic dissymmetry in coordination compounds.V. An investigation of the crystallization behavior of [cis-β-Co(triethylenetetramine)(NO2)2]X (X = I, NO3) and the crystal structure of racemic [cis-β-Co(trien)(NO2)2]NO3". Inorganica Chimica Acta. 120 (2): 109–117. doi:10.1016/S0020-1693(00)86096-X.
  6. ^ Bernal, Ivan; Cetrullo, James; Myrczek, Jozef (October 1993). "The phenomenon of conglomerate crystallization Part XXXI. The crystallization behavior of [cis-Co(en)2(NO2)2Br and of : counter-ion effects on crystallization pathway of racemate solutions". Materials Chemistry and Physics. 35 (3–4): 290–300. doi:10.1016/0254-0584(93)90145-C.
  7. ^ Charpeutier, T.; Virlet, J. (October 1998). "Triple quantum MQMAS spectroscopy of (I=7/2) in Na3Co(NO2)6 and trans-Co[(en2)(NO2)2]NO3 interplay between the quadrupole coupling and anisotropic shielding tensors". Solid State Nuclear Magnetic Resonance. 12 (4): 227–242. doi:10.1016/S0926-2040(98)00051-4. PMID 9800268.
  8. ^ a b Bernal, Ivan; Somoza, Fernando; Chen, Ya-Chen; Massoud, Salah S. (April 1997). "The Phenomenon of Conglomerate Crystallization. Part 48. Two Polymorphs of Racemic Trans-[Co(2,3,2-Tet) (No2)2]No3(I and Ii)". Journal of Coordination Chemistry. 41 (3): 233–247. doi:10.1080/00958979708023574. ISSN 0095-8972.
  9. ^ Murray, Don E.; Schlemper, Elmer O.; Siripaisarnpipat, Sutatip; Murmann, R. Kent (1986). "A structural and isotopic NO 2 – exchange rate comparison of trans-[Co(ao–H–ao)(NO 2 ) 2 ] and cis-[Co(Hao) 2 (NO 2 ) 2 ]NO 3". J. Chem. Soc., Dalton Trans. (9): 1759–1765. doi:10.1039/DT9860001759. ISSN 0300-9246.
  10. ^ Sutton, Gj (1960). "Some Studies in Inorganic Complexes. VIII. Cobalt(II) and Cobalt(III) with 2-Picolylamine". Australian Journal of Chemistry. 13 (4): 473. doi:10.1071/CH9600473. ISSN 0004-9425.
  11. ^ Ghaschghaie, Natascha (2010). "HETEROLEPTISCHE COBALT(III)-CHELATKOMPLEXE MIT BIOLIGANDEN" (PDF).
  12. ^ Lee, Yong-Min; Kim, Yong-Kyu; Jung, Hee-Cheul; Kim, Young-Inn; Choi, Sung-Nak (2002-03-20). "Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes". Bulletin of the Korean Chemical Society. 23 (3): 404–412. doi:10.5012/BKCS.2002.23.3.404.
  13. ^ Boer, F. Peter; Carter, Virginia B.; Turley, June W. (April 1971). "Single-crystal x-ray and Raman studies of bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate". Inorganic Chemistry. 10 (4): 651–661. doi:10.1021/ic50098a001. ISSN 0020-1669.
  14. ^ a b Fan, Ruiqing; Zhang, Yanjiao; Yin, Yanbin; Su, Qing; Yang, Yulin; Hasi, Wuliji (June 2009). "Syntheses, structures, and luminescent properties of cadmium (II) complexes: 3D supramolecular [Cd(phen)(NO3)(NO2)(H2O)]n and Cd(phen)2(NO3)(NO2) constructed by π–π stacking interactions". Synthetic Metals. 159 (11): 1106–1111. doi:10.1016/j.synthmet.2009.04.007.
  15. ^ Hollis, L. Steven; Lippard, Stephen J. (May 1982). "Effect of axial ligands on the platinum-platinum bond in binuclear .alpha.-pyridonate-bridged platinum(III) complexes. Structures of [X(NH3)2Pt(C5H4NO)2Pt(NH3)2X](NO3)2.H2O, X = NO3, NO2". Inorganic Chemistry. 21 (5): 2116–2117. doi:10.1021/ic00135a087. ISSN 0020-1669.
  16. ^ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)". Monatshefte für Chemie. 118 (2): 211–216. doi:10.1007/BF00810054. S2CID 101945551.
  17. ^ Nardelli, Mario; Pelizzi, Giancarlo (January 1980). "Crystal structure of K2Pb(NO2)3(NO3)·H2O". Inorganica Chimica Acta. 38: 15–19. doi:10.1016/S0020-1693(00)91928-5.
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