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Dipropalin

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Dipropalin
Names
Preferred IUPAC name
4-Methyl-2,6-dinitro-N,N-dipropylaniline
Other names
  • L-35355
  • 2,6-Dinitro-N,N-dipropyl-p-toluidine
  • 4-Methyl-2,6-dinitro-N,N-dipropylbenzenamine
  • 地乐灵 (Geleling)
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/C13H19N3O4/c1-4-6-14(7-5-2)13-11(15(17)18)8-10(3)9-12(13)16(19)20/h8-9H,4-7H2,1-3H3
    Key: UDVZOMAEGATTSE-UHFFFAOYSA-N
  • CCCN(CCC)C1=C(C=C(C=C1[N+](=O)[O-])C)[N+](=O)[O-]
Properties
C13H19N3O4
Molar mass 281.312 g·mol−1
Appearance Yellow crystals[1]
Melting point 42 °C (108 °F; 315 K) [citation needed]
Boiling point 118 °C (244 °F; 391 K)
0.3 g/L[citation needed]
Hazards
Lethal dose or concentration (LD, LC):
Over 3600 mg/kg (rat, oral)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dipropalin is a preëmergent dinitroaniline herbicide. It is currenctly not commercially used in western countries,[1] but may be available in China[2][unreliable source?] and used in India.[3] It has low acute toxicity.[1] It is used on turf.[1] Tests in the 1960s in the USA evaluated its performance as a trifluralin analog, where it scored the highest pre-emergent effectiveness amongst methyl-group analogs, though losing to several trifluoromethyls, such as trifluralin itself. Dipropalin's methyl group does see increased post-emergent activity, but no trifluralin analog was effective in this regard.[4]

References

[edit]
  1. ^ a b c d e Lewis, Kathleen A.; Tzilivakis, John; Warner, Douglas J.; Green, Andrew (2016-05-18). "An international database for pesticide risk assessments and management". Human and Ecological Risk Assessment: An International Journal. 22 (4): 1050–1064. Bibcode:2016HERA...22.1050L. doi:10.1080/10807039.2015.1133242. hdl:2299/17565. ISSN 1080-7039.
  2. ^ "地乐灵详细信息_百度知道". zhidao.baidu.com.
  3. ^ Kukkambakam Chandra Mohan, T. Chandraiah, M. Nagaraju, & N. Y. Sreedhar. (2015). Elucidation of electrochemical reduction behavior of dinitro group containing pesticides Chlornidine, Dipropalin and Prodiamine residues in soil, water and agricultural formulations. Journal of Indian Chemical Society, Vol. 92(Apr 2015), 467–471. https://doi.org/10.5281/zenodo.5595667
  4. ^ Gentner, W. A. (1966). "Herbicidal Properties of Trifluralin Analogs". Weeds. 14 (2): 176–178. doi:10.2307/4040959. JSTOR 4040959.
[edit]
  • Dipropalin in the Pesticide Properties DataBase (PPDB)