Phosphorus tricyanide
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| Other names
Tricyanophosphine
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3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| P(CN)3 | |
| Appearance | white crystals |
| Boiling point | 190 °C (374 °F; 463 K) sublimes[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Phosphorus tricyanide is an inorganic compound with the chemical formula P(CN)3. It can be produced by the reaction of phosphorus trichloride and trimethyl(iso)cyanosilane.[2] The reaction of phosphorus tribromide and silver cyanide in diethyl ether produce phosphorus tricyanide too.[1] Its thermal decomposition can produce graphite phase C3N3P.[3] Phosphorus tricyanide reacts with Re(CO)5FBF3 to form {P[CN-Re(CO)5]3}(BF4)3.[4]
References
[edit]- ^ a b Noeth, Heinrich; Vetter, Hans Joachim. Dialkylaminophosphoranes. II. Preparation and reaction of dimethylaminohalophosphoranes, (Me2N)3-nPXn. Chemische Berichte, 1963. 96: 1109-1118. ISSN 0009-2940.
- ^ T. A. Bither, W. H. Knoth, R. V. Lindsey, W. H. Sharkey (August 1958). "Trialkyl- and Triaryl(iso)cyanosilanes 1". Journal of the American Chemical Society. 80 (16): 4151–4153. doi:10.1021/ja01549a010. ISSN 0002-7863. Archived from the original on 2022-06-25. Retrieved 2022-06-15.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ Brian L. Chaloux, Brendan L. Yonke, Andrew P. Purdy, James P. Yesinowski, Evan R. Glaser, Albert Epshteyn (2015-07-14). "P(CN) 3 Precursor for Carbon Phosphonitride Extended Solids". Chemistry of Materials. 27 (13): 4507–4510. doi:10.1021/acs.chemmater.5b01561. ISSN 0897-4756. Archived from the original on 2022-06-15. Retrieved 2022-06-15.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ Wolfgang Sacher, Alfred Schmidpeter, Wolfgang Beck (April 2015). "Organometallic Lewis Acids, Part LIX [1] Pentacarbonylrhenium Complexes with Phosphorus Tricyanide and Dicyanophosphide: Organometallic Lewis Acids, Part LIX". Zeitschrift für anorganische und allgemeine Chemie. 641 (5): 762–764. doi:10.1002/zaac.201500068. Archived from the original on 2022-06-15. Retrieved 2022-06-15.
{{cite journal}}: CS1 maint: multiple names: authors list (link)