Gold(III) acetate

Gold(III) acetate
Names
	Other names Auric acetate;
Identifiers
CAS Number	15804-32-7;
3D model (JSmol)	Interactive image;
ChemSpider	11278961;
PubChem CID	15952561;
CompTox Dashboard (EPA)	DTXSID70580364 ;
	InChI InChI=1S/3C2H4O2.Au/c31-2(3)4;/h31H3,(H,3,4);/q;;;+3/p-3 Key: OTCKNHQTLOBDDD-UHFFFAOYSA-K;
	SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Au+3];
Properties
Chemical formula	Au(CH3COO)3
Molar mass	374.10 g/mol
Appearance	Yellow solid
Melting point	170 °C (338 °F; 443 K) (decomposes)
Solubility in water	Slightly soluble
Solubility	Slightly soluble in alkaline solutions
Hazards
NFPA 704 (fire diamond)	0 1 0
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Gold(III) acetate, also known as auric acetate, is a chemical compound of gold and acetic acid. It is a yellow solid that decomposes at 170 °C to gold metal. This decomposition of gold(III) acetate has been studied as a pathway to produce gold nanoparticles as catalysts.^[3]

Production and reactions

Gold(III) acetate can be produced by the reaction of gold(III) hydroxide and glacial acetic acid:^[4]

Au(OH)₃ + 3CH₃COOH → Au(CH₃COO)₃ + 3H₂O

It reacts with 2-(p-tolyl)pyridine (tpy) in presence of trifluoroacetic acid to form Au(CF₃COO)₂(tpy).^[5]

Gold(III) sulfide has been claimed as the product when gold(III) acetate is sonicated with cyclo-octasulfur in decalin.^[6]

References

^ Hiroaki Sakurai; Kenji Koga; Yasuo Iizuka; Masato Kiuchi (2013). "Colorless alkaline solution of chloride-free gold acetate for impregnation: An innovative method for preparing highly active Au nanoparticles catalyst". Applied Catalysis A: General. 462: 236–246. doi:10.1016/j.apcata.2013.05.016.
^ S. Bakrania; G. Rathore; Margaret Wooldridge (2008). "An investigation of the thermal decomposition of gold acetate". Journal of Thermal Analysis and Calorimetry. 95 (1): 117–122. doi:10.1007/s10973-008-9173-1. S2CID 22343912.
^ H.-S. Oh; J.H. Yang; C.K. Costello; Y.M. Wang; S.R. Bare; H.H. Kung; M.C. Kung (2002). "Selective Catalytic Oxidation of CO: Effect of Chloride on Supported Au Catalysts". Journal of Catalysis. 210 (2): 375–386. doi:10.1006/jcat.2002.3710.
^ Metal Finishing. the University of Michigan: Metals and Plastics Publications. 1940. p. 104. Retrieved 11 May 2023.
^ Langseth, E.; Görbitz, C.H.; Heyn, R.H.; Tilset, M. (2012). "Versatile methods for preparation of new cyclometalated gold(III) complexes". Organometallics. 31 (18): 6567–6571. doi:10.1021/om300537a. hdl:10852/40504.
^ Kristl, M.; Drofenik, M. (2003). "Preparation of Au₂S₃ and nanocrystalline gold by sonochemical method". Inorganic Chemistry Communications. 6 (12): 1419–1422. doi:10.1016/j.inoche.2003.08.027.

[alk-1] Hiroaki Sakurai; Kenji Koga; Yasuo Iizuka; Masato Kiuchi (2013). "Colorless alkaline solution of chloride-free gold acetate for impregnation: An innovative method for preparing highly active Au nanoparticles catalyst". Applied Catalysis A: General. 462: 236–246. doi:10.1016/j.apcata.2013.05.016.

[2] S. Bakrania; G. Rathore; Margaret Wooldridge (2008). "An investigation of the thermal decomposition of gold acetate". Journal of Thermal Analysis and Calorimetry. 95 (1): 117–122. doi:10.1007/s10973-008-9173-1. S2CID 22343912.

[3] H.-S. Oh; J.H. Yang; C.K. Costello; Y.M. Wang; S.R. Bare; H.H. Kung; M.C. Kung (2002). "Selective Catalytic Oxidation of CO: Effect of Chloride on Supported Au Catalysts". Journal of Catalysis. 210 (2): 375–386. doi:10.1006/jcat.2002.3710.

[4] Metal Finishing. the University of Michigan: Metals and Plastics Publications. 1940. p. 104. Retrieved 11 May 2023.

[5] Langseth, E.; Görbitz, C.H.; Heyn, R.H.; Tilset, M. (2012). "Versatile methods for preparation of new cyclometalated gold(III) complexes". Organometallics. 31 (18): 6567–6571. doi:10.1021/om300537a. hdl:10852/40504.

[Sonics-6] Kristl, M.; Drofenik, M. (2003). "Preparation of Au₂S₃ and nanocrystalline gold by sonochemical method". Inorganic Chemistry Communications. 6 (12): 1419–1422. doi:10.1016/j.inoche.2003.08.027.

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