User talk:Xiangzhuang-pg
(R)-2-Methyl-CBS-oxazaborolidine
[edit](R)-2-Methyl-CBS-oxazaborolidine[1] |
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IUPAC name(3aR)-1-Methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole |
Other name(R)-Methyl oxazaborolidine |
IdentifiersCAS number:112022-83-0 |
SMILESO2B(N1CCC[C@@H]1C2(c3ccccc3)c4ccccc4)C |
InChI1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15) |
Properties |
Molecular formula:C18H20BNO |
Hazards |
EU classification: File:Highly flammable(F).jpg File:Hamful(Xn).jpg R-phrases: R17 |
(R)-2-Methyl-CBS-oxazaborolidine is an oxazaborolidine reagent which mediates the enantioselective reduction of ketones previously developed by the laboratory of Itsuno, and thus this transformation may more properly be called the Itsuno-Corey oxazaborolidine reduction[2].
References
[edit]- ^ (R)-2-Methyl-CBS-oxazaborolidine at Viwit
- ^ Hirao, A.; Itsuno, S.; Nakahama, S.; Yamazaki, N. (1981), Journal of the Chemical Society, Chemical Communications 7: 315, doi:10.1039/C39810000315
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