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Wyatt Ferguson
Chemi-ionization is the formation of an ion through the reaction of a gas phase atom or molecule with an atom or molecule in an excited state.[1][2]
Reactions
[edit]Chemi-ionization can be represented by
where G is the excited state species (indicated by the superscripted asterisk), and M is the species that is ionized by the loss of an electron to form the radical cation (indicated by the superscripted "plus-dot").
See also
[edit]References
[edit]- ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "chemi-ionization". doi:10.1351/goldbook.C01044 C01044
- ^ Klucharev, A. N. (1993), "Chemi-ionization processes", Physics-Uspekhi, 36 (6): 486, Bibcode:1993PhyU...36..486K, doi:10.1070/PU1993v036n06ABEH002162
- ^ Vinckier, C.; Gardner, Michael P.; Bayes, Kyle D. (1977). "A study of chemi-ionization in the reaction of oxygen atoms with acetylene". The Journal of Physical Chemistry. 81 (23): 2137–2143. doi:10.1021/j100538a001. ISSN 0022-3654.
- ^ Mihajlov, A. A.; Srećković, V. A.; Ignjatović, Lj. M.; Klyucharev, A. N. (2012). "The Chemi-Ionization Processes in Slow Collisions of Rydberg Atoms with Ground State Atoms: Mechanism and Applications". Journal of Cluster Science. 23 (1): 47–75. doi:10.1007/s10876-011-0438-7. ISSN 1040-7278.
- ^ Müller, M. W.; Merz, A.; Ruf, M. -W.; Hotop, H.; Meyer, W.; Movre, M. (1991). "Experimental and theoretical studies of the Bi-excited collision systems He*(23 S) + He*(23 S, 21 S) at thermal and subthermal kinetic energies". Zeitschrift für Physik D Atoms, Molecules and Clusters. 21 (2): 89–112. doi:10.1007/BF01425589. ISSN 0178-7683.