User:Tetracube/Tetrafluorophosphonium
| Names | |
|---|---|
| IUPAC name
tetrafluoridophosphorus(1+), tetrafluorophosphanium
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| Other names
tetrafluorophosphonium(V)
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| Identifiers | |
3D model (JSmol)
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| ChEBI | |
PubChem CID
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| Properties | |
| PF+ 4 | |
| Molar mass | 106.967374 g/mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetrafluorophosphonium is a polyatomic ion with chemical formula PF+
4. It is the phosphorus analogue of the tetrafluoroammonium ion and the fluorine analogue of phosphine.[1] It has tetrahedral molecular geometry.
Synthesis
[edit]Phosphorus pentafluoride forms an adduct with antimony pentafluoride characterised by Raman spectroscopy as [PF+
4][Sb
3F−
16].[2]
References
[edit]- ^ Wiberg, Egon; Wiberg, Nils; Holleman, Arnold Frederick (2001). Inorganic chemistry. Academic Press. p. 726. ISBN 0123526515.
- ^ Chen, G. S. H.; Passmore, J. (1979). "Preparation and characterization of tetrafluorophosphonium(V) hexadecafluorotriantimonate(V), [PF
4][Sb
3F
16], the adduct arsenic pentafluoride–trifluorophosphine (1/1), and the redox reactions of trifluorophosphine with arsenic, antimony, and bismuth pentafluoride". Journal of the Chemical Society Dalton Transactions (8): 1251–1256. doi:10.1039/DT9790001251.