User:Stewartadcock/sandbox
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Names | |||
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IUPAC name
Azane
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Other names
Hydrogen nitride
Trihydrogen nitride | |||
Identifiers | |||
3D model (JSmol)
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3DMet | |||
3587154 | |||
ChEBI | |||
ChEMBL | |||
ChemSpider | |||
EC Number |
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79 | |||
KEGG | |||
MeSH | Ammonia | ||
PubChem CID
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RTECS number |
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UNII | |||
UN number | 1005 | ||
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Properties | |||
NH3 | |||
Molar mass | 17.031 g/mol | ||
Appearance | Colourless gas | ||
Odor | strong pungent odor | ||
Melting point | −77.73 °C (−107.91 °F; 195.42 K) | ||
Boiling point | −33.34 °C (−28.01 °F; 239.81 K) | ||
47% (0 °C) 31% (25 °C) 28% (50 °C)[1] | |||
Solubility | soluble in chloroform, ether, ethanol, methanol | ||
Vapor pressure | 8573 h Pa | ||
Acidity (pKa) | 32.5 (−33 °C),[2] 10.5 (DMSO) | ||
Basicity (pKb) | 4.75 | ||
Refractive index (nD)
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1.3327 | ||
Viscosity | 0.276 cP (-40 °C) | ||
Structure | |||
Trigonal pyramid | |||
1.42 D | |||
Thermochemistry | |||
Std molar
entropy (S⦵298) |
193 J·mol−1·K−1[3] | ||
Std enthalpy of
formation (ΔfH⦵298) |
−46 kJ·mol−1[3] | ||
Hazards | |||
GHS labelling: | |||
[4] | |||
H221, H280, H314, H331, H400[4] | |||
P210, P261, P273, P280, P305+P351+P338, P310[4] | |||
NFPA 704 (fire diamond) | |||
Flash point | flammable gas (see text) | ||
Explosive limits | 15–28% | ||
Lethal dose or concentration (LD, LC): | |||
LD50 (median dose)
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0.015 mL/kg (human, oral) | ||
NIOSH (US health exposure limits): | |||
PEL (Permissible)
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50 ppm (25 ppm ACGIH- TLV; 35 ppm STEL) | ||
Related compounds | |||
Other cations
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Phosphine Arsine Stibine | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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- ^ Perry, Dale L.; Phillips, Sidney L. (1995). Handbook of inorganic compounds. CRC Press. p. 17. ISBN 0-8493-8671-3.
{{cite book}}
: CS1 maint: multiple names: authors list (link) - ^ Perrin, D. D., Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution; 2nd Ed., Pergamon Press: Oxford, 1982.
- ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN 0-618-94690-X.
- ^ a b c Sigma-Aldrich Co., Ammonia. Retrieved on 2013-07-20.