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User:Qwertyzap/sandbox

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Qwertyzap/sandbox
Names
IUPAC name
2-Methoxy-1,3,5-trinitrobenzen
Other names
2,4,6-Trinitroanisol; picric acid, methyl ester; trisol; trinol; trinitroanisole
Identifiers
Properties
C7H5N3O7
Molar mass 243.13 g/mol
Appearance yellow, "leaf-like" crystals
Density 1.408 g/cm3
Melting point 68.4 °C
Boiling point explodes
insoluble in water, soluble in diethyl ether and hot ethanol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
explosive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Tracking categories (test):

Trinitroanisole is an chemical compound that exists as pale yellow crystals with a melting point of 68.4°C. It is an explosive with a detonation velocity of 7200 meters per second. [1] [2]

Synthesis

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Trinitroanisole can be prepared by the reaction of 2,4-dinitrochlorobenzene with methanol in the presence of sodium hydroxide followed by the nitration of the resulting product. Alternatively, it can be prepared directly by the reaction of picryl chloride with methanol in the presence of sodium hydroxide. [1] [2]

Use

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Historically, trinitroanisole was used as a military explosive, however, due to its tendency to form picric acid and dangerous picrate salts, its use has been largely abandoned. [3]

Notes

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  1. ^ a b Wikimedia Foundation."Trinitroanisole", "German Wikipedia", accessed July 21, 2011.
  2. ^ a b Wasag-Chemie, Essen. "Explosives". 1961, p. 164
  3. ^ Wikimedia Foundation. "Tri-nitroanisole", "Japanese Wikipedia", accessed July 21, 2011.