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OrganoMetallurgy/Drafts/Chloro tris(tert-butylimido)manganese
Identifiers
Properties
Appearance	Green crystals
Melting point	94–95 °C (201–203 °F; 367–368 K) with partial decomposition
Boiling point	sublimes at 70 °C under vacuum
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Chloro tris(tert-butylimido)manganese, Mn(N^tBu)₃CI, is a compound with manganese in the VIII oxidation state, which is extremely rare outside of compounds containing permanganate.

Structure

Tetrahedral geometry around the manganese, ^[1]

Synthesis

An acetonitrile solution of manganese(III) chloride reacts with trimethylsilane and tert-butylamine to form chloro tris(t-butylimido)manganese.^[2]

Reactions

The chloro ligand can be replaced by other groups.

some references to possibly use

^[3]

^[4]

References

^ Danopoulos, Andreas A.; Wilkinson, Geoffrey; Sweet, Tracy; Hursthouse, Michael B. (1993-01-01). "Synthesis and X-ray crystal structure of chloro tris(tert-butylimido)manganese". Journal of the Chemical Society, Chemical Communications (6). doi:10.1039/c39930000495. ISSN 0022-4936.
^ Danopoulos, Andreas A.; Wilkinson, Geoffrey; Sweet, Tracy K. N.; Hursthouse, Michael B. (1994-01-01). "Non-oxo chemistry of manganese in high oxidation states. Part 1. Mononuclear tert-butylimido compounds of manganese-(VII) and -(VI)". Journal of the Chemical Society, Dalton Transactions (7). doi:10.1039/dt9940001037. ISSN 1364-5447.
^ Lynam, Mary M.; Vites, JoséC. (1997-06-01). "Manganese 1994". Coordination Chemistry Reviews. 162: 275–304. doi:10.1016/s0010-8545(96)01331-8.
^ Danopoulos, Andreas A; Green, Jennifer C; Hursthouse, Michael B (1999-12-05). "Imido complexes of manganese". Journal of Organometallic Chemistry. 591 (1): 36–44. doi:10.1016/s0022-328x(99)00448-9.

[1] Danopoulos, Andreas A.; Wilkinson, Geoffrey; Sweet, Tracy; Hursthouse, Michael B. (1993-01-01). "Synthesis and X-ray crystal structure of chloro tris(tert-butylimido)manganese". Journal of the Chemical Society, Chemical Communications (6). doi:10.1039/c39930000495. ISSN 0022-4936.

[2] Danopoulos, Andreas A.; Wilkinson, Geoffrey; Sweet, Tracy K. N.; Hursthouse, Michael B. (1994-01-01). "Non-oxo chemistry of manganese in high oxidation states. Part 1. Mononuclear tert-butylimido compounds of manganese-(VII) and -(VI)". Journal of the Chemical Society, Dalton Transactions (7). doi:10.1039/dt9940001037. ISSN 1364-5447.

[3] Lynam, Mary M.; Vites, JoséC. (1997-06-01). "Manganese 1994". Coordination Chemistry Reviews. 162: 275–304. doi:10.1016/s0010-8545(96)01331-8.

[4] Danopoulos, Andreas A; Green, Jennifer C; Hursthouse, Michael B (1999-12-05). "Imido complexes of manganese". Journal of Organometallic Chemistry. 591 (1): 36–44. doi:10.1016/s0022-328x(99)00448-9.

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