User:Mittens10/New sandbox
Cuprate superconductors are high-temperature superconductors made of layers of copper oxides (CuO2) alternating with layer of charge reservoirs (CR), which are oxides of other metals.
Structure
[edit]
The structure of superconducting cuprates are often closely related to perovskite structure. Cuprates are layered materials, consisting of superconducting planes of copper oxide, separated by layers containing ions such as lanthanum, barium, strontium, which act as a charge reservoir, doping electrons or holes into the copper-oxide planes. Thus the structure is described as a superlattice of superconducting CuO2 layers separated by spacer layers. Superconductivity takes place within the copper-oxide (CuO2) sheets with only weak coupling between adjacent CuO2 planes, making the properties close to that of a two-dimensional material. This structure causes a large anisotropy in normal conducting and superconducting properties, with a much higher conductivity parallel to the CuO2 plane than in the perpendicular direction, since electrical currents flow within the CuO2 sheets.
Generally, critical temperatures depend on the chemical compositions, cations substitutions and oxygen content. Chemical formulae of superconducting materials generally contain fractional numbers to describe the doping required for superconductivity. There are several families of cuprate superconductors which can be categorized by the elements they contain and the number of adjacent copper-oxide layers in each superconducting block. For example, YBCO and BSCCO can alternatively be referred to as Y123 and Bi2201/Bi2212/Bi2223 depending on the number of layers in each superconducting block (n). The superconducting transition temperature has been found to peak at an optimal doping value (p=0.16) and an optimal number of layers in each superconducting block, typically n=3.
The undoped "parent" or "mother" compounds are Mott insulators with long-range antiferromagnetic order at sufficiently low temperatures. Single band models are generally considered to be enough to describe the electronic properties.
Cuprate superconductors usually feature copper oxides in both the oxidation states 3+ and 2+. For example, YBa2Cu3O7 is described as Y3+(Ba2+)2(Cu3+)(Cu2+)2(O2−)7. All superconducting cuprates are layered materials having a complex structure described as a superlattice of superconducting CuO2 layers separated by spacer layers, where the misfit strain between different layers and dopants in the spacers induce a complex heterogeneity that in the superstripes scenario is intrinsic for high-temperature superconductivity.