User:Graeme Bartlett/borate tellurate

Borate tellurates are chemical mixed anion compounds that contain any kind of borate and tellurate ions. They are distinct from borotellurates where borate and tellurate are linked via oxygen; and telluroborates in which tellurium atoms replace oxygen in borates. There are also analogous borate selenates,and borate sulfates with selenium or sulfur atoms instead of tellurium.

List

chem	mw	crystal system	space group	unit cell	volume	density	comments	references
Gd₃S₃BO₃	626.74	triclinic	P1	a=3.9725 b=7.5945 c=11.182 α=91.402 β=91.093 γ=90.206 Z=2	337.30	6.173	pale yellow; band gap 2.65 eV	^[1]
Bi₃TeBO₉		Hexagonal	P6₃	a=8.7337 c =5.8903			transparent from 0.35 to 7.10 μm; SHG 1.6×KDP	^[2]
Bi₃(TeO₆)(BO₃)	909.35	hexagonal	P6₃	a=8.745, c=5.891, Z=2	390.20	7.740	pale yellow; decompose 825 °C	^[3]

References

^ Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01). "Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)". New Journal of Chemistry. 40 (8): 6720–6727. doi:10.1039/C6NJ00549G. ISSN 1369-9261.
^ Dong, Weimin; Sun, Yingjie; Wang, Biao; Zhu, Mengqi; Li, Jing; Xu, Xinguang; Wang, Jiyang (2022-06-13). "Bi 3 TeBO 9 : A Promising Mid-Infrared Nonlinear Optical Crystal with a Large Laser Damage Threshold". Inorganic Chemistry. 61 (23): 8870–8878. doi:10.1021/acs.inorgchem.2c00924. ISSN 0020-1669.
^ Daub, Michael; Krummer, Michael; Hoffmann, Anke; Bayarjargal, Lkhamsuren; Hillebrecht, Harald (2017-01-26). "Synthesis, Crystal Structure, and Properties of Bi 3 TeBO 9 or Bi 3 (TeO 6 )(BO 3 ): A Non-Centrosymmetric Borate-Tellurate(VI) of Bismuth". Chemistry - A European Journal. 23 (6): 1331–1337. doi:10.1002/chem.201602480.

Category:Borates Category:Tellurates Category:Mixed anion compounds

[1] Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01). "Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)". New Journal of Chemistry. 40 (8): 6720–6727. doi:10.1039/C6NJ00549G. ISSN 1369-9261.

[2] Dong, Weimin; Sun, Yingjie; Wang, Biao; Zhu, Mengqi; Li, Jing; Xu, Xinguang; Wang, Jiyang (2022-06-13). "Bi 3 TeBO 9 : A Promising Mid-Infrared Nonlinear Optical Crystal with a Large Laser Damage Threshold". Inorganic Chemistry. 61 (23): 8870–8878. doi:10.1021/acs.inorgchem.2c00924. ISSN 0020-1669.

[3] Daub, Michael; Krummer, Michael; Hoffmann, Anke; Bayarjargal, Lkhamsuren; Hillebrecht, Harald (2017-01-26). "Synthesis, Crystal Structure, and Properties of Bi 3 TeBO 9 or Bi 3 (TeO 6 )(BO 3 ): A Non-Centrosymmetric Borate-Tellurate(VI) of Bismuth". Chemistry - A European Journal. 23 (6): 1331–1337. doi:10.1002/chem.201602480.

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