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Pure water (H2O) is an example of a compound. The ball-and-stick model of the molecule shows the spatial association of two parts hydrogen (white) and one part(s) oxygen (red)

A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) composed of atoms from more than one element held together by chemical bonds. A molecule consisting of atoms of only one element is therefore not a compound.

There are four types of compounds, depending on how the constituent atoms are held together:

A chemical formula specifies the number of atoms of each element in a compound molecule, using the standard abbreviations for the chemical elements and numerical subscripts. For example, a water molecule has formula H2O indicating two hydrogen atoms bonded to one oxygen atom. Many chemical compounds have a unique CAS number identifier assigned by the Chemical Abstracts Service. Globally, more than 350,000 chemical compounds (including mixtures of chemicals) have been registered for production and use.[1]

A compound can be converted to a different chemical substance by interaction with a second substance via a chemical reaction. In this process, bonds between atoms may be broken in either or both of the interacting substances, and new bonds formed.

Definitions

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Any substance consisting of two or more different types of atoms (chemical elements) in a fixed stoichiometric proportion can be termed a chemical compound; the concept is most readily understood when considering pure chemical substances.[2]: 15  [3][4] It follows from their being composed of fixed proportions of two or more types of atoms that chemical compounds can be converted, via chemical reaction, into compounds or substances each having fewer atoms.[5] The ratio of each element in the compound is expressed in a ratio in its chemical formula.[6] A chemical formula is a way of expressing information about the proportions of atoms that constitute a particular chemical compound, using the standard abbreviations for the chemical elements, and subscripts to indicate the number of atoms involved. For example, water is composed of two hydrogen atoms bonded to one oxygen atom: the chemical formula is H2O. In the case of non-stoichiometric compounds, the proportions may be reproducible with regard to their preparation, and give fixed proportions of their component elements, but proportions that are not integral [e.g., for palladium hydride, PdHx (0.02 < x < 0.58)].[7]

Chemical compounds have a unique and defined chemical structure held together in a defined spatial arrangement by chemical bonds. Chemical compounds can be molecular compounds held together by covalent bonds, salts held together by ionic bonds, intermetallic compounds held together by metallic bonds, or the subset of chemical complexes that are held together by coordinate covalent bonds.[8] Pure chemical elements are generally not considered chemical compounds, failing the two or more atom requirement, though they often consist of molecules composed of multiple atoms (such as in the diatomic molecule H2, or the polyatomic molecule S8, etc.).[8] Many chemical compounds have a unique numerical identifier assigned by the Chemical Abstracts Service (CAS): its CAS number.

There is varying and sometimes inconsistent nomenclature differentiating substances, which include truly non-stoichiometric examples, from chemical compounds, which require the fixed ratios. Many solid chemical substances—for example many silicate minerals—are chemical substances, but do not have simple formulae reflecting chemically bonding of elements to one another in fixed ratios; even so, these crystalline substances are often called "non-stoichiometric compounds". It may be argued that they are related to, rather than being chemical compounds, insofar as the variability in their compositions is often due to either the presence of foreign elements trapped within the crystal structure of an otherwise known true chemical compound, or due to perturbations in structure relative to the known compound that arise because of an excess of deficit of the constituent elements at places in its structure; such non-stoichiometric substances form most of the crust and mantle of the Earth. Other compounds regarded as chemically identical may have varying amounts of heavy or light isotopes of the constituent elements, which changes the ratio of elements by mass slightly.

Types

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Molecules

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Main article: molecule

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds.[9][10][11][12][13] A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).

Ionic compounds

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Main article: Ionic compound

An ionic compound is a chemical compound composed of ions held together by electrostatic forces termed ionic bonding. The compound is neutral overall, but consists of positively charged ions called cations and negatively charged ions called anions. These can be simple ions such as the sodium (Na+) and chloride (Cl−) in sodium chloride, or polyatomic species such as the ammonium (NH+
4) and carbonate (CO2−
3) ions in ammonium carbonate. Individual ions within an ionic compound usually have multiple nearest neighbours, so are not considered to be part of molecules, but instead part of a continuous three-dimensional network, usually in a crystalline structure.

Ionic compounds containing basic ions hydroxide (OH−) or oxide (O2−) are classified as bases. Ionic compounds without these ions are also known as salts and can be formed by acid–base reactions. Ionic compounds can also be produced from their constituent ions by evaporation of their solvent, precipitation, freezing, a solid-state reaction, or the electron transfer reaction of reactive metals with reactive non-metals, such as halogen gases.

Ionic compounds typically have high melting and boiling points, and are hard and brittle. As solids they are almost always electrically insulating, but when melted or dissolved they become highly conductive, because the ions are mobilized.

Intermetallic compounds

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Main article: Intermetallic compound

An intermetallic compound is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties.[14][15][16] They can be classified as stoichiometric or nonstoichiometic intermetallic compounds.[14]

Complexes

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Main article: Coordination complex

A coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents.[17][18][19] Many metal-containing compounds, especially those of transition metals, are coordination complexes.[20] A coordination complex whose centre is a metal atom is called a metal complex of d block element.

Bonding and forces

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Compounds are held together through a variety of different types of bonding and forces. The differences in the types of bonds in compounds differ based on the types of elements present in the compound.

London dispersion forces are the weakest force of all intermolecular forces. They are temporary attractive forces that form when the electrons in two adjacent atoms are positioned so that they create a temporary dipole. Additionally, London dispersion forces are responsible for condensing non polar substances to liquids, and to further freeze to a solid state dependent on how low the temperature of the environment is.[21]

A covalent bond, also known as a molecular bond, involves the sharing of electrons between two atoms. Primarily, this type of bond occurs between elements that fall close to each other on the periodic table of elements, yet it is observed between some metals and nonmetals. This is due to the mechanism of this type of bond. Elements that fall close to each other on the periodic table tend to have similar electronegativities, which means they have a similar affinity for electrons. Since neither element has a stronger affinity to donate or gain electrons, it causes the elements to share electrons so both elements have a more stable octet.

Ionic bonding occurs when valence electrons are completely transferred between elements. Opposite to covalent bonding, this chemical bond creates two oppositely charged ions. The metals in ionic bonding usually lose their valence electrons, becoming a positively charged cation. The nonmetal will gain the electrons from the metal, making the nonmetal a negatively charged anion. As outlined, ionic bonds occur between an electron donor, usually a metal, and an electron acceptor, which tends to be a nonmetal.[22]

Hydrogen bonding occurs when a hydrogen atom bonded to an electronegative atom forms an electrostatic connection with another electronegative atom through interacting dipoles or charges.[23][24][25][26]

Reactions

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Main article: Chemical reaction

A compound can be converted to a different chemical composition by interaction with a second chemical compound via a chemical reaction. In this process, bonds between atoms are broken in both of the interacting compounds, and then bonds are reformed so that new associations are made between atoms. Schematically, this reaction could be described as AB + CD → AD + CB, where A, B, C, and D are each unique atoms; and AB, AD, CD, and CB are each unique compounds.

The Hill System

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The Hill System or also known as the Hill Notation is a form of writing chemical formulas idea by Edwin A. Hill. It is used to set the order of the Carbon atom as first and Hydrogen atom as the second of a chemical formula. Ex. C12H22O11 If the following chemicals are not present, the chemical formula should be written in alphabetic order. Ex. AgCNO[27]

See also

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References

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  1. ^ Wang, Zhanyun; Walker, Glen W.; Muir, Derek C. G.; Nagatani-Yoshida, Kakuko (2020-01-22). "Toward a Global Understanding of Chemical Pollution: A First Comprehensive Analysis of National and Regional Chemical Inventories". Environmental Science & Technology. 54 (5): 2575–2584. Bibcode:2020EnST...54.2575W. doi:10.1021/acs.est.9b06379. PMID 31968937.
  2. ^ Whitten, Kenneth W.; Davis, Raymond E.; Peck, M. Larry (2000), General Chemistry (6th ed.), Fort Worth, TX: Saunders College Publishing/Harcourt College Publishers, ISBN 978-0-03-072373-5
  3. ^ Brown, Theodore L.; LeMay, H. Eugene; Bursten, Bruce E.; Murphy, Catherine J.; Woodward, Patrick (2013), Chemistry: The Central Science (3rd ed.), Frenchs Forest, NSW: Pearson/Prentice Hall, pp. 5–6, ISBN 9781442559462, archived from the original on 2021-05-31, retrieved 2020-12-08
  4. ^ Hill, John W.; Petrucci, Ralph H.; McCreary, Terry W.; Perry, Scott S. (2005), General Chemistry (4th ed.), Upper Saddle River, NJ: Pearson/Prentice Hall, p. 6, ISBN 978-0-13-140283-6, archived from the original on 2009-03-22
  5. ^ Wilbraham, Antony; Matta, Michael; Staley, Dennis; Waterman, Edward (2002), Chemistry (1st ed.), Upper Saddle River, NJ: Pearson/Prentice Hall, p. 36, ISBN 978-0-13-251210-7
  6. ^ "Chemical compound". ScienceDaily. Archived from the original on 2017-09-13. Retrieved 2017-09-13.
  7. ^ Manchester, F. D.; San-Martin, A.; Pitre, J. M. (1994). "The H-Pd (hydrogen-palladium) System". Journal of Phase Equilibria. 15: 62–83. doi:10.1007/BF02667685. S2CID 95343702. Phase diagram for Palladium-Hydrogen System
  8. ^ a b Atkins, Peter; Jones, Loretta (2004). Chemical Principles: The Quest for Insight. W.H. Freeman. ISBN 978-0-7167-5701-6.
  9. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Molecule". doi:10.1351/goldbook.M04002
  10. ^ Ebbin, Darrell D. (1990). General Chemistry (3rd ed.). Boston: Houghton Mifflin Co. ISBN 978-0-395-43302-7.
  11. ^ Brown, T.L.; Kenneth C. Kemp; Theodore L. Brown; Harold Eugene LeMay; Bruce Edward Bursten (2003). Chemistry – the Central Science (9th ed.). New Jersey: Prentice Hall. ISBN 978-0-13-066997-1.
  12. ^ Chang, Raymond (1998). Chemistry (6th ed.). New York: McGraw Hill. ISBN 978-0-07-115221-1.
  13. ^ Zumdahl, Steven S. (1997). Chemistry (4th ed.). Boston: Houghton Mifflin. ISBN 978-0-669-41794-4.
  14. ^ a b Askeland, Donald R.; Wright, Wendelin J. (January 2015). "11-2 Intermetallic Compounds". The science and engineering of materials (Seventh ed.). Boston, MA. pp. 387–389. ISBN 978-1-305-07676-1. OCLC 903959750. Archived from the original on 2021-05-31. Retrieved 2020-11-10.{{cite book}}: CS1 maint: location missing publisher (link)
  15. ^ Panel On Intermetallic Alloy Development, Commission On Engineering And Technical Systems (1997). Intermetallic alloy development : a program evaluation. National Academies Press. p. 10. ISBN 0-309-52438-5. OCLC 906692179. Archived from the original on 2021-05-31. Retrieved 2020-11-10.
  16. ^ Soboyejo, W. O. (2003). "1.4.3 Intermetallics". Mechanical properties of engineered materials. Marcel Dekker. ISBN 0-8247-8900-8. OCLC 300921090. Archived from the original on 2021-05-31. Retrieved 2020-11-10.
  17. ^ Lawrance, Geoffrey A. (2010). Introduction to Coordination Chemistry. Wiley. doi:10.1002/9780470687123. ISBN 9780470687123.
  18. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "complex". doi:10.1351/goldbook.C01203
  19. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "coordination entity". doi:10.1351/goldbook.C01330
  20. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  21. ^ "London Dispersion Forces". www.chem.purdue.edu. Archived from the original on 2017-01-13. Retrieved 2017-09-13.
  22. ^ "Ionic and Covalent Bonds". Chemistry LibreTexts. 2013-10-02. Archived from the original on 2017-09-13. Retrieved 2017-09-13.
  23. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "hydrogen bond". doi:10.1351/goldbook.H02899
  24. ^ "Hydrogen Bonds". chemistry.elmhurst.edu. Archived from the original on 2016-11-19. Retrieved 2017-10-28.
  25. ^ "Hydrogen Bonding". www.chem.purdue.edu. Archived from the original on 2011-08-08. Retrieved 2017-10-28.
  26. ^ "intermolecular bonding – hydrogen bonds". www.chemguide.co.uk. Archived from the original on 2016-12-19. Retrieved 2017-10-28.
  27. ^ Hill, Edwin A. (1900-08). "ON A SYSTEM OF INDEXING CHEMICAL LITERATURE; ADOPTED BY THE CLASSIFICATION DIVISION OF THE U. S. PATENT OFFICE.1". Journal of the American Chemical Society. 22 (8): 478–494. doi:10.1021/ja02046a005. ISSN 0002-7863. {{cite journal}}: Check date values in: |date= (help)

Further reading

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Look up chemical compound in Wiktionary, the free dictionary.
Wikimedia Commons has media related to Chemical compounds.
  • Robert Siegfried (2002), From elements to atoms: a history of chemical composition, American Philosophical Society, ISBN 978-0-87169-924-4
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