User:Benjah-bmm27/PPh3Cl2
Identifiers
[edit]CAS: 2526-64-9
Google test
[edit]"triphenylphosphine dichloride": 1080 (but plenty of complexes like [PdCl2(PPh3)2] included)
"dichlorotriphenylphosphorane": 511 (implies molecular structure - does not apply well to [ClPPh3]+ Cl−)
"dichlorotriphenylphosphine": 388 (again, complexes like [PdCl2(PPh3)2] included)
Info stored locally
[edit]Wikipedia > Article factory > PPh3Cl2
Online info
[edit]Entry at e-EROS Encyclopedia of Reagents for Organic Synthesis
Sigma-Aldrich product page: 378755 Dichlorotriphenylphosphorane
ChemACX: here
Tetrahedron Letters 48 (2007) 223-226 - Reactivity of chlorinating agents/PPh3 for the chlorination of alcohols and carboxylic acids: a comparative study
Acta Cryst. (1987). C43, 2309-2311 for structure of [Ph3PCl]+ [MoCl6]− — only example of the chlorotriphenylphosphonium cation I could find on IUCr (but many others are known, according to SciFinder).
Properties
[edit]mol wt 333.19
Relevant existing articles
[edit]- Phosphorane
- Triphenylphosphine
- Phosphorus trichloride
- Phosphorus pentachloride
- Phosphorus halides
- Halogenation