Thallium azide

Thallium azide
Names
	IUPAC name Thallium(I) azide
	Other names thallium azide
Identifiers
CAS Number	13847-66-0 ;
3D model (JSmol)	Interactive image;
ChemSpider	15368504 ;
PubChem CID	22764821;
CompTox Dashboard (EPA)	DTXSID00628243 ;
	InChI InChI=1S/N3.Tl/c1-3-2;/q-1;+1 Key: GMUSFHMEMWCQIE-UHFFFAOYSA-N ; InChI=1/N3.Tl/c1-3-2;/q-1;+1 Key: GMUSFHMEMWCQIE-UHFFFAOYAP;
	SMILES [Tl+].[N-]=[N+]=[N-];
Properties
Chemical formula	TlN3
Molar mass	246.40 g·mol−1
Appearance	yellow-brown crystals
Solubility in water	insoluble
Structure
Crystal structure	Tetragonal, tI16
Space group	I4/mcm, No. 140
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	very toxic
	GHS labelling:
Pictograms
Signal word	Danger
NFPA 704 (fire diamond)	4 0 3
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Thallium azide, TlN₃, is a yellow-brown crystalline solid poorly soluble in water. Although it is not nearly as sensitive to shock or friction as lead azide, it can easily be detonated by a flame or spark. It can be stored safely dry in a closed non-metallic container.

Preparation and structure

Thallium azide can be prepared treating an aqueous solution of thallium(I) sulfate with sodium azide. Thallium azide will precipitate; the yield can be maximized by cooling.

TlN₃, KN₃, RbN₃, and CsN₃ adopt the same structures. The azide is bound to eight cations in an eclipsed orientation. The cations are bound to eight terminal N centers.^[2]

Coordination sphere of azide in KN₃, RbN₃, CsN₃ and TlN₃.

Safety

All thallium compounds are poisonous and should be handled with care; avoid breathing any dust or fumes.

References

^ Mauer F.A.; Hubbard C.R.; Hahn T.A. (1973). "Thermal expansion and low temperature phase transition of thallous azide". J. Chem. Phys. 59 (7): 3770–3776. Bibcode:1973JChPh..59.3770M. doi:10.1063/1.1680549.
^ Ulrich Müller "Verfeinerung der Kristallstrukturen von KN₃, RbN₃, CsN₃ und TIN₃" Zeitschrift für anorganische und allgemeine Chemie 1972, Volume 392, 159–166. doi:10.1002/zaac.19723920207

[1] Mauer F.A.; Hubbard C.R.; Hahn T.A. (1973). "Thermal expansion and low temperature phase transition of thallous azide". J. Chem. Phys. 59 (7): 3770–3776. Bibcode:1973JChPh..59.3770M. doi:10.1063/1.1680549.

[2] Ulrich Müller "Verfeinerung der Kristallstrukturen von KN₃, RbN₃, CsN₃ und TIN₃" Zeitschrift für anorganische und allgemeine Chemie 1972, Volume 392, 159–166. doi:10.1002/zaac.19723920207

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