Talk:Methyllithium

Chemicals Mid‑importance

	This article is within the scope of WikiProject Chemicals, a daughter project of WikiProject Chemistry, which aims to improve Wikipedia's coverage of chemicals. To participate, help improve this article or visit the project page for details on the project.ChemicalsWikipedia:WikiProject ChemicalsTemplate:WikiProject Chemicalschemicals articles
Mid	This article has been rated as Mid-importance on the project's importance scale.

Occupational Safety and Health Low‑importance

	This article is within the scope of WikiProject Occupational Safety and Health, a collaborative effort to improve the coverage of articles related to occupational safety and health on Wikipedia. If you would like to participate, please visit the project page, where you can join the discussion and see a list of open tasks.Occupational Safety and HealthWikipedia:WikiProject Occupational Safety and HealthTemplate:WikiProject Occupational Safety and HealthOccupational Safety and Health articles
Low	This article has been rated as Low-importance on the project's importance scale.

BROWN TL, ROGERS MT (1957). "THE PREPARATION AND PROPERTIES OF CRYSTALLINE LITHIUM ALKYLS". JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 79 (8): 1859–1861.--Stone 16:30, 16 March 2007 (UTC)[reply]

WEISS E, LUCKEN EAC (1964). "DIE KRISTALLSTRUKTUR UND ELEKTRONENSTRUKTUR DES METHYLLITHIUMS". JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2 (3): 197–205. --Stone 16:32, 16 March 2007 (UTC)[reply]

SETZER WN, SCHLEYER PV (1985). "X-RAY STRUCTURAL-ANALYSES OF ORGANO-LITHIUM COMPOUNDS". ADVANCES IN ORGANOMETALLIC CHEMISTRY. 24: 353–451. {{cite journal}}: Text "issue" ignored (help)

K. Ziegler, K. Nagel, M. Patheiger (1955). "Metallorganische Verbindungen. XX. Lithium- und Magnesium-Methylen". Zeitschrift für anorganische und allgemeine Chemie. 282 (1–6): 345–351. doi:10.1002/zaac.19552820136.{{cite journal}}: CS1 maint: multiple names: authors list (link) --16:53, 16 March 2007 (UTC)

MeLi Name

I noted that this page is a redirect from "Methyllithium" - the redirect should be in the opposite direction - the correct name is not "Methyl lithium" (two words) but "Methyllithium" (one word). See, for example, n-Butyllithium, tert-Butyllithium, Phenylmagnesium bromide, Methylmagnesium chloride, etc. ChemistHans 18:52, 20 August 2007 (UTC)[reply]

I tried, unsuccessfully, to move this page to methyllithium. Perhaps an admin can help.

Ben 19:24, 20 August 2007 (UTC)[reply]

Done. --Ed (Edgar181) 20:01, 21 August 2007 (UTC)[reply]

Reactivity

I made some minor edits in the reactivity section, but there are still some problems. "Dangerous" is mentioned several times. I am not clear what this refers to - MeLi is considerably less reactive than commonly used reagents like n-BuLi. There is occasionally trouble with pressure build-up from methane buildup - perhaps this is what is meant. The statement "THF, usually a chemically inert solvent, is attacked by MeLi" is not correct - MeLi attacks THF only very slowly - experiments run for days at room temperature show little sign of THF decomposition. Of course, one would not store a THF solution of MeLi for months at room temperature, but otherwise there is no problem. Unless I hear some objections I will make some more changes. ChemistHans 20:56, 21 August 2007 (UTC)[reply]