Jump to content

Selenidostannate

Add links
From Wikipedia, the free encyclopedia

Selenidostannates are chemical compounds which contain anionic units of selenium connected to tin. They can be considered as stannates where selenium substitutes for oxygen. Similar compounds include the selenogermanates and thiostannates. They are in the category of chalcogenidotetrelates or more broadly chalcogenometallates.

Formation

[edit]

Some selenidostannates can be made by treating tin diselenide (SnSe2) with an alkali selenide dissolved in water.[1] Other possible solvents include  choline chloride with 1,8-diaminooctane,[2]

Properties

[edit]

Most selenidostannates are semiconductors. Their resistance drops on exposure to light. Also selenidostannates are often coloured, most often orange, red or yellow.

Many are unstable in humid air, as the water reacts with the selenidostannate to form hydrogen selenide (H2Se).

Use

[edit]

Selenidostannates are primarily of research interest. They are under investigation as photoelectric materials.

List

[edit]
name chem mw crystal system space group unit cell Å volume density comment references
tris(μ2-1,2-Diaminoethane)-1,2-diaminoethane-di-lithium triselenido-tin(iv) Li4Sn2Se6 · 8en monoclinic C2/c a=22.660 b=9.449 c=20.336 β=101.24° [3]
diammonium [NH4]2Sn4Se9 orthorhombic Pnma a =13.2274 b=12.4270 c=12.6102 supertetrahedra Sn4Se10 arranged in layers [4]
bis(dimethylammonium) heptakis(μ-selenido)-tri-tin dimethylamine solvate [NH2(CH3)2]2Sn3Se7·0.5NH(CH3)2 monoclinic C2/c a=23.5939 b=13.6409 c=15.0372, β=102.177° chains of Sn3Se8 [4]
tetrakis(ethylammonium) tetradecakis(μ-selenido)-hexa-tin [NH3C2H5]2Sn3Se7 orthorhombic Cmca a=13.5561 b=24.0194 c=27.0184 [4]
bis(Ethylenediammonium) ethylenediamine bis((μ2-selenido)-diseleno-tin(iv)) [enH2]2[Sn2Se6] · en triclinic P1 a =8.636 b =11.044 c =6.613, α =104.48° β =110.76° γ =79.43° twin edge-bridged SnSe4 tetrahedra [5]
tetrakis(2-Aminoethylammonium) bis(μ2-selenido)-tetraselenido-di-tin(iv) 1,2-diaminoethane [enH]4[SnIV2Se6] · en triclinic P1 a=11.212 b=11.631 c=13.097, α=79.40° β=76.82° γ=64.82° [6]
catena(Ethylenediammonium hemiethylenediamine (μ3-selenido)-hexakis(μ2-selenido)-tri-tin(iv)) [enH2][Sn3Se7]·0.5en orthorhombic Fdd2 a=23.597 b=27.563 c=13.877 [4][5]
catena-(tetrakis(μ2-Seleno)-ethylenediamine-di-tin(iv)) [2 SnSe2·en] orthorhombic Pca21 a 1=3.724 b =11.866 c =13.647 [5]
[(C2H5)3NH]2Sn3Se7 P212121 2.12 eV [4]
[(C2H5)3NH]2Sn3Se7·0.25H2O monoclinic P21/n 2.1 eV [4]
(Et4N)2Sn3Se7 monoclinic P21/m a=10.140 b=13.858 c=12.071, β=100.649° [7]
[NEt4]4[Sn4Se10] cubic P43n a = 22.170 10897 [8]
bis(tetrapropylammonium) nonaselenidotetrastannate(IV) ([C3H7]4N)2[Sn4Se9] monoclinic P21/n a = 15.328, b = 19.058, c = 15.398, β = 97.947°, Z = 4 4454.7 orange [9]
(C7N4OH16)2Sn3Se7·H2 orthorhombic Pbca [4]
(NH3(CH2)8NH3)Sn3Se7 triclinic P1 [4]
Octane-1,8-diammonium (μ3-selena)-hexakis(μ2-selena)-tri-tin (NH3(CH2)8NH3)Sn3Se7 triclinic P1 a=8.4419 b=11.6441 c=13.1857 α=66.636° β=77.989° γ=83.919° [10]
Decane-1,10-diammonium (μ3-selena)-hexakis(μ2-selena)-tri-tin (NH3(CH2)10NH3)Sn3Se7 monoclinic C2/c a=23.726 b=13.910 c=15.954 β=111.915° [10]
(NH3(CH2)10NH3)Sn3Se7 monoclinic C2/c [4]
tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ3-selenido)-octadecakis(μ2-selenido)-nona-tin monoclinic P21/c a =18.652 b=20.353 c=20.196 β=105.244° [11]
tetrakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) dodecakis(μ2-selenido)-diselenido-hexa-tin [Mmpmim]4Sn6Se14 monoclinic P21/c a=14.270 b=15.549 c=14.377 β=92.749° [11]
bis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) (μ3-selenido)-hexakis(μ2-selenido)-tri-tin [Mmpmim]2Sn3Se7 trigonal P3221 a=13.9470 b=13.9470 c=27.8553 [11]
octakis(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) tetrakis(μ3-selenido)-docosakis(μ2-selenido)-diselenido-dodeca-tin [Mmpmim]8Sn12Se26 monoclinic P21/c a=24.538 b=13.961 c=19.434 β=94.539° [11]
tetra(1,2-dimethyl-3-butyl-1H-imidazol-3-ium) bis(μ3-selenido)-dodecakis(μ2-selenido)-hexa-tin [Mmbmim]4Sn6Se14 trigonal P3221 a=13.9381 c=27.774 [11]
[prmmim]2[Sn3Se7] P3221 [4]
Bmmim=1-butyl-2,3-dimethylimidazolium [bmmim]2[Sn3Se7] P3221 band gap 2.2 eV [4]
Bzmim = 1-benzyl-3-methylimidazolium

bis(1-benzyl-3-methylimidazolium) heptakis(μ-selenido)-tri-tin

[Bzmim]2[Sn3Se7] orthorhombic Pbca a=14.297 b=13.8808 c=16.8855 β=99.817° [12]
Emim = 1-ethyl-3-methylimidazolium

pentakis(1-ethyl-3-methylimidazolium) bis(heptakis(μ-selenido)-tri-tin) chloride unknown solvate

[Emim]5[Sn3Se7]2Cl hexagonal P63/mmc a=13.8331 c=18.4649 [12]
[DBNH]2[Sn3Se7]·PEG monoclinic C2/c band gap 2.13 eV [4]
[DBNH]3[NH4][Sn6Se14] trigonal R3 band gap 2.02 eV [4]
(H+-DBN)2[Sn3Se7] Cmc21 band gap 2.02 eV [4]
(CH3)3N(CH2)2OH]2[Sn3Se7] orthorhombic Pbca band gap 2.35 eV [4]
catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate] (CH3)3N(CH2)2OH]2[Sn3Se7]∙H2O monoclinic P21/n a=9.8365 b=13.5796 c=20.7384 β=92.727° Z=4 2893.0 2.606 orange; [4][13]
catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin] (CH3)3N(CH2)2CH3]2[Sn3Se7] orthorhombic Pbca a =17.534 b =13.7273 c =24.1221 Z=8 5806.2 2.547 orange [14]
bis(N,N,N-trimethylbutanaminium) poly[heptaselenidotristannate(IV)] (Bu(CH3)3N)2[Sn3Se7] monoclinic C2/c a = 23.950, b = 13.760, c = 20.011, β = 114.565°, Z = 8 5998 orange [4][15]
AEPP = N-aminoethylpiperazine [AEPPH2]2[Sn5Se12] triclinic P1 a = 10.6351, b = 10.6850, c = 10.7771, α = 61.344°, β = 62.442°, γ = 67.468 [16]
phen=1,10-Phenanthroline (CH3NH3)4(Sn2Se6)·6phen triclinic P1 a 10.594 b 12.225 c 14.945 α 83.589° β 83.133° γ 86.604° [17]
Im=imidazolium

catena-(pentakis(3-n-butyl-1-methylimidazolium) dodecakis(μ-selenido)-nona-tin tetrafluoroborate)

(C4C1C1Im)5[Sn9Se20][BF4] monoclinic P21/n a=13.878 b=20.365 c=31.026 β =91.326° Z=4 8766 2.652 orange [18]
DMMP=2,6-dimethylmorpholine (DMMPH)4[Sn2Se6] monoclinic P21/n a=6.158 b=22.381 c=14.642 β=93.57° Z=2 2014.1 1.926 yellow [18]
catena-(bis(1-ethyl-3-methylimidazolium) bis(2,6-dimethylmorpholin-4-ium) tetradecakis(μ-selenido)-hexa-tin) (C2C1Im)2(DMMPH)2[Sn6Se14] monoclinic P21/n a=20.616 b=13.857 c=19.629 β=107.40° Z=4 5351 2.821 orange [18]
catena-[tetrakis(3-n-Butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(μ3-selenido)-undecakis(μ2-selenido)-selenido-hexa-tin(iv)] [BMMIm]4[Sn6Se14] monoclinic P21/c a 24.2744 b 13.8901 c 19.1763 β 94.083° Z=4 6449.3 2.503 orange [19]
catena-(hexadecakis(1-butyl-2,3-dimethylimidazolium) octakis(μ3-selenido)-octatetracontakis(μ2-selenido)-tetracosa-tin) [BMMIm]16[Sn24Se56] trigonal P32 a=27.8622 c=28.0566 Z=3 18862.4 2.568 red [19]
catena-(tris(3-Butyl-1,2-dimethylimidazolium) 2,6-dimethylmorpholin-4-ium (μ3-selenido)-dodecakis(μ2-selenido)-selenido-hexa-tin) [BMMIm]3[DMMPH][Sn6Se14] triclinic P1 a 11.1358 b 12.6745 c 23.362, α 89.690° β 88.473° γ 72.098° Z=2 3136.6 2.534 orange or yellow (low temp) [19]
1-butyl-3-methyl-inidazolinium [BMIm]4[Sn9Se20] monoclinic Cc a=19.901 b=26.494 c=14.447 β=105.34 Z=4 7361 2.892 red [20]
catena-[bis(2-hydroxy-N,N,N-trimethylethan-1-aminium) heptakis(μ-selenido)-tri-tin monohydrate] [HOCH2CH2N(CH3)3]2Sn3Se7·H2O monoclinic P21/n a 9.8365 b 13.5796 c 20.7384 β 92.727° orange (high temp) or yellow [21]
catena-[bis(N,N,N-trimethylpropan-1-aminium) heptakis(μ-selenido)-tri-tin] [CH3CH2CH2N(CH3)3]2Sn3Se7 orthorhombic Pbca a 17.403 b 13.7025 c 23.9113 2.852 yellow [21]
tetrakis(piperidinium) bis(μ-selenido)-tetraselenido-di-tin {[Sn2Se6]·4(C5NH12)} monoclinic P21/n a 10.3277 b 10.2808 c 15.7823 β 96.725° 2.0110 red [22]
catena-[bis(3,6,7,8-tetrahydro-2H-pyrrolo[1,2-a]pyrimidin-5-ium) tetrakis(μ-selenido)-hexa-tin] {[Sn3Se7]·2(HDBN)} DBN = 1,5-diazabicyclo[4.3.0]non-5-ene orthorhombic Cmc21 a 13.4435 b 24.4817 c 14.4494 red [22]
[dabcoH]2[(CH3)2NH2]2[Sn2Se6] monoclinic C2/m a=20.172 b=11.674 c=6.476 β=103.15 Z=2 1485.2 2.303 yellow [23]
(N2H4)3(N2H5)4Sn2Se6 triclinic P1 a = 6.6475, b = 9.5474, c = 9.883, α = 94.110°, β = 99.429°, γ = 104.141°, Z = 1 [24]
bis(1-Aminoethylammonium) bis(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane-potassium) bis(μ2-seleno)-tetraseleno-di-tin(iv) (enH)2(2,2,2-crypt-K)2Sn2Se6 monoclinic P21/n a=8.442 b=25.877 c=14.821 β=104.19°
(MeSn)4Se6 triclinic P1 a = 9.147, b =10.495 c =10.508, α = 85.60, β = 89.83 γ =65.71° Z=2 916 adamantane structure [25]
Na4SnS4 tetragonal I41acd [26]
Na4SnS4 tetragonal P421c a=7.84679 c=6.95798, Z=2 428.42 yellow [26]
Na4SnSe4·14H2O [26]
Na4SnSe4·16H2O monoclinic P21/m a = 8.673, b = 16.563, c = 8.647, β = 92.10°, Z = 2 tetrahedra; Sn-Se bond length 2.504−2.527 Å [27][1]
Na4Sn2S6·5H2O [28]
Na4Sn2Se6·13H2O triclinic P1 a = 7.106, b = 10.330, c = 19.009, α = 78.60, β = 85.66, γ = 72.85° Z = 2 (at −130°C) orange-red; tetrahedral edge-shared pairs [27][29]
Na4Ge2Se6 · 16 H2O monoclinic P21/c a = 9.894, b = 11.781, c = 12.225, β = 92.90°, Z = 2 [30]
Na4Sn3Se8 trigonal bipyramid + tetrahedron [27]
Na6Sn4Se11 · 22 H2O monoclinic C2/c a 15.325 b 11.634 c 26.739 β 95.81° yellow-orange [31]
Na6Sn2Se7·16H2O red [29]
catena-(tris(1-Amino-2-ammonioethane) octakis(μ3-selenido)-hexakis(μ2-selenido)-sodium-hexa-tin sesquikis(dimethylamine) sesquihydrate) (enH)3Na[Sn3Se7]2·1.5Me2NH·1.5H2O R32 a=13.8647 c=18.962 Na+ ion conductor [32]
bis((μ4-Selenido)-(μ3-selenido)-bis(μ2-ethylene-1,2-diamine))-tetra-sodium-tin [Na4(en)4][SnSe4] orthorhombic P41212 a=13.090 b=13.090 c=14.548 [33]
Li2MgNaSe4 orthorhombic Pmn21 a = 8.40 b = 7.18 c = 6.73 Z=2 405.9 3.867 yellow; moisture absorbing [34]
SnPSe3 monoclinic Pn a=6.8161 b=7.7264 c=9.6437 β=91.073° [35]
K4SnSe4 orthorhombic Pnma a=14.714 b=10.323 c=8.248 Z=4 yellow [36]
2D-K2Sn2Se5 orthorhombic Pbca a=13.0246 b=12.186 c=14.135 Z=8 [37]
K4Sn2Se6 tetrahedral edge-shared pairs [27]
K4Sn3Se8 orthorhombic Ccca a 8.214 b 27.795 c 8.2136 [38]
K0.5[Sn3Se7] hexagonal P6522 a=13.8325 c 43.295 Z=12 7174.1 2.579 red [18]
K6Sn4Se11 . 8H2O monoclinic C2/c a =28.004 b =9 c =15.192, β 113.8° [7]
K6[SnIII2Se6] [6]
K4Sn4Se10·4.5H2O trigonal R3 a=15.32 c=21.019 [39]
tetrakis(Tetramethylammonium) (hexakis(μ2-seleno)-di-tin(iv)-potassium) K(N(CH3)4)3Sn2Se6 triclinic P1 a 9.587 b 10.005 c 15.996 α 95.15° β 92.81° γ 106.96° [40]
(μ2-Ethylene-1,2-diamine-N,N')-bis(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium (μ2-ethylene-1,2-diamine-N,N')-(ethylene-1,2-diamine-N)-bis(1,4,7,10,13,16-hexaoxacyclo-octadecane)-di-potassium hexakis(μ2-selenido)-(tetraselenoxy)-tetra-tin(iv) [18-crown-6-K]4[Sn4Se10]·5en monoclinic P21/n a=22.003 b=18.966 c=24.392 β=97.548° [41]
dipotassium(+) bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)potassium(+)] hexaselenodistannate(4-) tetrakis(ethylenediamine) solvate (18-crown-6) K2[K(C12H24O6)]2[Sn2Se6].4C2H8N2 monoclinic P21/n a=15.634 b=8.479 c=23.404 β=108.60° [42]
bis((4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium) tris(tetraselenido)-tin(iv) [K-(2,2,2-crypt)]2Sn(Se4)3 triclinic P1 a=10.7088 b=12.9986 c=21.7865 α=86.299° β=81.598° γ=87.258° [43]
Ca(en)4Ca(en)3[Sn2Se6] triclinic P1 a = 10.2708, b = 12.2739, c = 16.3103, α = 93.576°, β = 90.609°, γ = 109.269°, Z = 1 1936.09 [44]
[VII(dien)2]2[Sn2Se6] monoclinic P21/n a 9.7686 b 15.094 c 12.517 β 91.007° band gap 2.11 eV [45]
catena-(tetraethylenepentaminedi-ium octakis(μ-selenido)-bis(tetraethylenepentamine)-tetraselenolato-tetra-tin(iv)-di-vanadium(iii)) [H2tepa]0.5[VIII(tepa)(μ-Sn2Se6)] orthorhombic Abm2 a=7.808 b=41.97 c=16.982 Z=8 5565 2.496 [46]
tepa = tetraethylenepentamine

bis(Hydroxy-tetraethylenepentamine-chromium) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) monohydrate

[Cr(tepa)(OH)]2Sn2Se6·H2O orthorhombic Pbcn a=16.767 b=14.552 c=14.859 2.08 eV [47]
peha = pentaethylenehexamide

bis(Pentaethylenehexamine-chromium) dichloride 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate)

[Cr(peha)]2(Sn2Se6)Cl2 monoclinic P21/n a=9.636 b=14.361 c=15.357 β=106.50° 2.19 eV [47]
en = ethylenediamine, pip = piperazine

pentakis(tris(ethylenediamine)-chromium(iii)) bis(tetrakis(selenyl)-tin(iv)) heptakis(chloride) piperazine solvate

[Cr(en)3]2.5[SnSe4]·Cl3.5·(pip)0.5·1.5H2O trigonal R3c a=15.4035 c =61.487 band gap 2.23 eV;SnSe4 tetrahedron [2]
catena-[(μ3-Selenido)-(μ2-selenido)-bis(1,2-diaminoethane)-selenido-manganese-tin] SnSe3Mn(en)2 monoclinic P21/n a =9.4565 b =11.2896 c =12.7937 β =103.765° Z=4 2.657 red [48]
catena-[(μ3-Selenido)-bis(μ2-selenido)-(1,2-diaminoethane)-manganese-tin] SnSe3Mn(en) orthorhombic Pbca a=13.9290 b=7.5261 c=19.2572 Z=8 2018.7 3.097 red [48]
catena-[bis(μ3-Selenido)-bis(μ2-selenido)-bis(1,2-diaminoethane)-di-manganese-tin] MnSnSe4Mn(en)2 orthorhombic Pnma a=13.1101 b=14.8267 c=7.9466 Z=4 1544.66 2.858 yellow [48]
pentaehtylenehexaamine [Mn(peha)][Sn3Se7] monoclinic P21/n [4]
[Mn(dien)2]Sn3Se7·0.5H2O monoclinic P21/n band gap 1.89 eV [4]
[Mn(en)2.5(en-Me)0.5][Sn3Se7] monoclinic P21/c [4]
catena-[tris(ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin] [Mn(en)3][Sn3Se7] monoclinic P21/n a=12.2277 b=13.1904 c=15.9272 β=100.174° red [4][49]
catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese heptakis(μ-selenido)-tri-tin monohydrate] [Mn(dien)2][Sn3Se7]∙H2O monoclinic P21/n a=12.3987 b=13.3150 c=16.6672 β=96.378° red; band gap 2.04 eV [4][49]
[Mn(dien)2]Sn3Se7·0.5H2O monoclinic P21/n a 12.322 b 13.300 c 16.706 β 96.331° [50]
bis(bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) bis(μ-selenido)-tetrakis(selenido)-di-tin [Mn(dien)2]2Sn2Se6 monoclinic P21/n a 12.677 b 9.585 c 15.595 β 102.49(3)° [50]
[Mn(dien)2]MnSnSe4 orthorhombic C2221 a=9.002 b=17.761 c=12.967 band gap 2.25 eV [51]
catena-[tris(ethane-1,2-diamine)-manganese(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] [Mn(en)3]Sn3Se6(Se2) monoclinic P21/n a 11.974 b 14.046 c 15.893, β 99.78° [52]
catena-((bis(diethylenetriamine)-manganese(ii)) bis(μ-selenido)-manganese) [Mn(en)3][Sn(Se4)3] triclinic P1 a 10.222 b 12.175 c 12.394, α 89.37° β 74.97° γ 75.66° [52]
en = ethylenediamine, hda = N-(2-hydroxyethyl)ethylenediamine)

bis(bis(ethylenediamine)-(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii)) bis(μ-selenido)-tetrakis(selenido)-di-tin

[Mn(en)2(hda)]2[Sn2Se6] monoclinic P21/n a 9.1189 b 12.3968 c 17.515 β 97.010° [53]
catena-[bis(N-(2-hydroxyethyl)ethylenediamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin] [Mn(hda)2][SnMnSe4] monoclinic C2/c a 9.4497 b 17.6025 c 13.1121 β 103.617° [53]
dien = diethylenetriamine

catena-[bis(diethylenetriamine)-manganese(ii) bis(μ-selenido)-manganese bis(μ-selenido)-tin]

[Mn(dien)2][SnMnSe4] orthorhombic C2221 a 9.0169 b 17.740 c 12.9543 [53]
heptakis(μ2-selenido)-(tetraethylenepentamine)-manganese(ii)-tri-tin(iv) Mn(tepa)·Sn3Se7 orthorhombic P212121 a=12.533 b=13.709 c=13.989 [54]
tetrakis(μ2-selenido)-bis(seleno)-bis(tetraethylenepentamine)-di-manganese(ii)-di-tin(iv) [Mn(tepa)]2(μ2-Sn2Se6) tetragonal I41/a a=26.483 b=26.483 c=10.1423 [54]
hexakis(μ2-selenido)-tetrakis(1,10-phenanthroline)-di-manganese-di-tin dihydrate {[Mn(phen)2]2(μ2-Sn2Se6)}·H2O monoclinic P21/n a 11.061 b 10.061 c 25.21 β 90.081° [17]
catena-((μ3-selenido)-bis(μ2-selenido)-(1,10-phenanthroline)-manganese-tin) [Mn(phen)]2(μ4-Sn2Se6) triclinic P1 a 9.721 b 10.257 c 10.346, α 118.24° β 112.53° γ 95.75° [17]
hexakis(μ-2-aminoethan-1-olato)-octakis(μ-selenido)-hepta-manganese-di-tin Mn7(ea)6(SnSe4)2 orthorhombic Pccn a=14.886 b=19.354 c=12.4314 Z=4 3581.5 2.993 orange [55]
catena-(pentakis(μ2-selenido)-bis(1,10-phenanthroline)-manganese-di-tin) [Mn(phen)2](Sn2Se5) monoclinic C2/c a 16.639 b 12.961 c 14.088β 117.91° [17]
catena-[tris(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) bis(tris(ethane-1,2-diamine)-manganese) icosakis(μ-selenido)-selenido-nona-tin chloride] (Bmmim)3[Mn(en)3]2[Sn9Se21]Cl monoclinic P21/c a=19.4488 b=19.5108 c=26.6148 β=109.587° red [49]
catena-[hexakis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) bis((N-(2-(amino)ethyl)ethane-1,2-diamine)-manganese) tetratriacontakis(selenido)-selenido-pentadeca-tin] (Bmmim)6[Mn(dien)2]2Sn15Se35 monoclinic P21/n a=13.4256 b=29.904 c=19.5845 β=106.643° red [49]
catena-[hemikis(tris(ethane-1,2-diamine)-manganese) hemikis((N-methylethane-1,2-diamine)-bis(ethane-1,2-diamine)-mangnaese) heptakis(μ-selenido)-tri-tin] [Mn(en)2.5(en-Me)0.5][Sn3Se7] monoclinic P21/c a=12.1058 b=13.2204 c=18.2504 β=120.839° Z=4 2507.9 3.049 orange [56]
catena-(bis(4-Aminobutan-1-aminium) tetrakis(μ2-selenido)-manganese-tin) (1,4-dabH)2MnSnSe4 orthorhombic Fdd2 a =23.287 b=25.410 c=6.6053 [57]
tetrakis(2,2'-bipyridine)-hexakis(μ-selenido)-di-tin-di-manganese {Mn(2,2′-bipy)2}2(μ2-Sn2Se6) monoclinic P 21/n a=8.756 b=20.960 c=12.484 β=95.66° [58]
hexakis(μ2-Selenido)-bis(1,4,8,11-tetraazacyclotetradecane)-di-manganese(ii)-di-tin {Mn(cyclam)}2(μ-Sn2Se6.15) monoclinic P21/n a=9.949 b=16.783 c=11.649 β=105.208° [59]
hexakis(μ2-Selenido)-bis(2,2';6',2''-terpyridine)-di-manganese(ii)-di-tin {Mn(terpy)}2(μ-Sn2Se6) triclinic P1 a=9.430 b=10.872 c=11.090 α=117.86° β=102.83° γ=103.22° [59]
tris(μ2-Selenido)-(2,2';6',2''-terpyridine)-manganese(ii)-tin {Mn(terpy)}2(μ-Sn2Se6) triclinic P1 a=9.923 b=10.027 c=10.959 α=107.29° β=97.57° γ=115.10° [59]
(NMe4)2[MnSn4Se10] tetragonal I4 a=9.865 c =15.317 red [60]
Li4MnSn2Se7 monoclinic Cc a=18.126 b=7.221 c=10.470 β=93.43° Z=4 1403.2 4.132 orange [61]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene [DBNH]2[MnSnSe4] tetragonal P42/ncm a=13.0305 c =6.6220 [62]
[Fe(tatda)]Sn3Se7 monoclinic P21/n 1.93 eV [4]
catena-((bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-iron) [Fe(dien)2]FeSnSe4 orthorhombic C2221 a =8.974 b =17.755 c =12.967 band gap 2.21 eV [51]
bis(bis(diethylenetriamine)-iron(ii)) bis(μ-selenido)-tetraselenido-di-tin [Fe(dien)2]2Sn2Se6 monoclinic P21/n a=12.563 b=9.655 c=15.566 β=102.76° band gap 2.60 eV [51]
bis(bis(diethylenetriamine)-iron(ii)) ethane-1,2-diammonium bis(2-ammonioethyl)amine bis(bis(μ-selenido)-tetraselenido-di-tin) [H2en][H2dien][Fe(dien)2]2(Sn2Se6)2 triclinic P1 a=8.727 b=12.794 c=14.918, α=66.09° β=84.06° γ=75.33° band gap 2.58 eV [51]
catena-[tris(ethane-1,2-diamine)-iron(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] [Fe(en)3]Sn3Se6(Se2) monoclinic P21/c a =11.950 b =14.083 c =17.995 β =120.25° [52]
tris(ethane-1,2-diamine)-iron(ii) tris[tetraselanato]-tin [Fe(en)3][Sn(Se4)3] triclinic P1 a 10.223 b 12.106 c 12.263, α 89.40° β 89.40° γ 75.45° [52]
tatda = 3,6,9,12-tetraazatetradecane-1,14-diamine

catena-[(3,6,9,12-tetraazatetradecane-1,14-diamine)-iron heptakis(μ-selenido)-tri-tin]

[Fe(tatda)]Sn3Se7 monoclinic P21/n a 12.1067 b 13.3225 c 17.0827 β 96.978° [50]
hexakis(μ2-selenido)-tetrakis(1,10-phenanthroline)-di-iron-di-tin [Fe(phen)2]2(μ2-Sn2Se6) monoclinic C2/c a 26.192 b 11.248 c 17.843 β 98.816° [17]
catena-(bis(tris(1,10-phenanthroline)-iron) bis(μ3-selenido)-dodecakis(μ2-selenido)-hexa-tin hydrate) [Fe(phen)3](Sn3Se7)·1.25H2O trigonal R3c a=13.9483 c 75.476 band gap 1.97 eV [17]
bipy = bipyridine

catena-[nonakis(μ-selenido)-tetra-tin tris(2,2'-bipyridine)-iron dihydrate]

[Fe(bipy)3]Sn4Se9·2H2O trigonal R3c a=26.902 c 30.673 [63]
[Fe(bipy)3]2[Sn3Se7]2·bipy·2H2O monoclinic P21/c a 27.055 b 13.391 c 24.756, β 103.88° [63]
heptakis(μ-selenido)-(tetra-ethylenepentamine)-iron-tri-tin Sn3Se7Fe(tepa) orthorhombic P212121 a 12.4958 b 13.7745 c 14.0233 3.112 black [22]
bis[tris(ethane-1,2-diamine)-iron] 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [Fe(en)3]2Sn2Se6 orthorhombic Pbca a =15.5062(9)Å b=11.8662 c=19.0966 2.146 red [22]
{CpFe(CO)2}3{CpFe(CO)}Sn3Se4 triclinic P1 a 12.2066 b 12.584 c 13.0007, α 90.632° β 90.068° γ 120.836° [64]
(NMe4)2[FeSn4Se10] tetragonal I4 a=9.878 c=15.345 [60]
[Co(en)3]2Sn2Se6 orthorhombic Pbca a=15.640 b=11.564 c=18.742 [46]
[Co(dien)2]2Sn2Se6 monoclinic P21/n a=10.2224 b=14.5788 c=12.3921 β=91.237° 1846.4 yellow; black with water, ultrasound turns yellow [65][46][66]
[Co(en)(trien)]2Sn2Se6 monoclinic P21/n a 7.929 b 15.855 c 14.262 β 93.436° [67]
bis(tris(2,2'-bipyridine)-cobalt(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate [Co(2,2′-bipy)3]2[Sn3Se7]2·(2,2′-bipy)·H2O monoclinic P21/c a=27.032 b=13.392 c=24.763 β=103.85° [58]
catena-[tris(ethylenediamine)-nickel hemikis(heptakis(μ-selenato)-selenato-tri-tin) hemikis(hexakis(μ-selenato)-selenato-tri-tin)] [Ni(en)3][Sn3Se6.5(Se2)0.5] orthorhombic Pca21 a =14.88 b =1.8872Å c =13.859 1.95 eV;chains of [Sn3Se7]n2n– and [Sn3Se6(Se)2]n2n– [2]
tris(ethylenediamine)-nickel(ii) tetrakis(μ-selanyl)-selanyl-di-tin [Ni(en)3][Sn2Se5] monoclinic P21/n a=8.7998 b=10.0736 c=22.655 β=90.763° [68]
[Ni(en)3]2[Sn2Se6] orthorhombic a=15.288 b=11.937 c=19.239 3511.0 [46]
catena-[tris(ethylenediamine)-nickel heptakis(μ-selenato)-tri-tin] [Ni(en)3][Sn3Se7] monoclinic P21/n a=12.32 b=13.19 c=15.73 β=101.07° band gap 2.01 eV [2]
catena-[tris(1,2-diaminoethane)-nickel(ii) pentakis(μ-selenido)-bis(selenido)-tri-tin(iv)] [Ni(en)3]Sn3Se7.5 orthorhombic Pca21 a 14.869 b 11.888 c 13.860 [52]
tris(ethane-1,2-diamine)-nickel tris[tetraselanato]-tin [Ni(en)3][Sn(Se4)3] triclinic P1 a 10.104 b 12.048 c 12.107, α 89.52° β 75.44° γ 75.78° [52]
phen = 1,10-phenanthroline

tris(1,10-phenanthroline)-nickel(ii) heptakis(μ-selenato)-tri-tin(iv) sesquihydrate

[Ni(phen)3]Sn3Se7·1.5H2O trigonal R3 a=13.971 c=38.281 [69]
[(Ni0.4Zn0.6)(en)6]Sn2Se6 [65]
catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) hemikis((μ2-triethylenetetramine)-bis(triethylenetetramine)-di-nickel) tris(μ3-selenido)-heptadecakis(μ2-selenido)-selenido-nona-tin) 2D-(Bmmim)8[Ni2(teta)2(μ-teta)]Sn18Se42 monoclinic P21/n a =18.9764 b= 25.1081 c =20.5731 β =100.870° [70]
teta = triethylenetetramine

(ethylenediamine)-(triethylenetetramine)-nickel(ii) (triethylenetetramine)-(N-(2-hydroxyethyl)ethylenediamine)-nickel(ii) hexakis(μ-selenido)-tetrakis(selenido)-tetra-tin

[Ni(teta)(en)][Ni(teta)(hda)][Sn4Se10] monoclinic P21/n a 12.3191 b 17.7104 c 22.643 β 95.278° [70]
tepa=tetraethylenepentamine

catena-(tetrakis(1-n-Butyl-2,3-dimethylimidazolium) bis(chloro-(tetraethylenepentamine)-nickel) pentakis(μ3-selenido)-tricosakis(μ2-selenido)-(tetraethylenepentamine)-nickel-dodeca-tin)

2D-(Bmmim)4[Ni(tepa)Cl]2[Ni(tepa)Sn12Se28] monoclinic Pn a=21.2230 b=13.4993 c=23.8715 β =112.461° [70]
Bmmim=1-butyl-2,3-dimethylimidazolium 2D-(Bmmim)3[Ni(en)3]2[Sn9Se21]Cl monoclinic P21/c a 19.488 b 19.626 c 26.793 β 109.930° [53]
catena-(bis(1-n-Butyl-2,3-dimethylimidazolium) bis(tris(propane-1,2-diamine)-nickel) bis(bis(μ3-selenido)-heptakis(μ2-selenido)-tetra-tin)) 3D-(Bmmim)2[Ni(1,2-pda)3]Sn8Se18 trigonal R3c a=27.7913 c 47.4281 [70]
catena-[bis(N-(2-(amino)ethyl)ethane-1,2-diamine)-nickel sesquikis(3-butyl-1,2-dimethyl-1H-imidazol-3-ium) hemikis(2-amino-N-(2-aminoethyl)ethylammonium) octadecakis(μ-selenido)-octa-tin] 2D-(Bmmim)2[Ni(teta)(en)][Sn3Se7]2 monoclinic P21/c a=31.088 b=10.5393 c=19.9712 β=99.966° [71]
catena-[(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-(ethane-1,2-diamine)-nickel bis(1-butyl-2,3-dimethyl-1H-imidazol-3-ium) tridecakis(μ-selenido)-selenido-hexa-tin] 3D-(Bmmim)1.5(dienH)0.5Ni(dien)2[Sn4Se9]2 monoclinic P21/c a=24.3753 b=13.3778 c=17.7885 β=93.949° [71]
[Ni(tren)(en)]SnSe3∙H2O 638.64 monoclinic P21/n a=12.8150 b=10.0094

c=15.6626 β=???? Z=4

1885.8 band gap [72]
bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin dihydrate [Ni(tren)(en)]2[Sn2S6]·2H2O monoclinic P21/n a 12.7041 b 9.8000 c 15.3989 β 108.843° 3.23 eV [73]
bis((tris(2-aminoethyl)amine)-(ethane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin hexahydrate [Ni(tren)(en)]2[Sn2S6]·6H2O monoclinic P21/c a 12.5580 b 9.7089 c 16.0359 β 91.827° 3.16 eV [73]
bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin trihydrate [Ni(tren)(1,2-dach)]2[Sn2S6]·3H2O triclinic P1 a 9.8121 b 10.0080 c 12.422, α 86.38° β 79.65° γ 65.71° 3.43 eV [73]
bis((tris(2-aminoethyl)amine)-(cyclohexane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate [Ni(tren)(1,2-dach)]2[Sn2S6]·4H2O monoclinic P21/c a 10.7119 b 19.0797 c 11.1005 β 104.803° 3.29 eV [73]
bis((tris(2-aminoethyl)amine)-(propane-1,2-diamine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin tetrahydrate [Ni(tren)(1,2-dap)]2[Sn2S6]·4H2O monoclinic C2/c a 14.3925 b 15.1550 c 18.9307 β 99.108° 3.32 eV [73]
bis((tris(2-aminoethyl)amine)-(2-(aminomethyl)pyridine)-nickel(ii)) bis(μ-sulfido)-tetrathiolato-di-tin decahydrate [Ni(tren)(2amp)]2[Sn2S6]·10H2O monoclinic P21/n a 12.1933 b 13.4025 c 14.8920 β 103.090° 3.28 eV [73]
L1 = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane [Ni(L1)][Ni(L1)Sn2S6]n·2H2O monoclinic P21/c a 11.6481 b 14.4268 c 10.8450 β 95.449° brown [74]
L2 = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane [Ni(L2)]2[Sn2S6]·4H2O triclinic P1 a 9.1562 b 10.3705 c 12.2897 α 66.761° β 85.350° γ 81.308° [74]
(μ2-triethylenetetramine)-bis(triethylenetetramine)-di-nickel(ii) tetrachloride dihydrate [Ni2(trien)2(μ-trien)]Cl4·2H2O orthorhombic Pbca a 13.737 b 13.089 c 18.193 [67]
bis(tris(2,2'-bipyridine)-nickel(ii)) heptakis(μ-selenido)-tri-tin(iv) hexakis(μ-selenido)-selenido-tri-tin(iv) 2,2'-bipyridine monohydrate [Ni(2,2′-bipy)3]2[Sn3Se7]2·(2,2′-bipy)·H2O monoclinic P 21/c a=26.999 b=13.383 c=24.714 β=103.89° [58]
Cu2SnSe4 F3m thermoelectric [75]
(1,4-dabH2)Cu2SnSe4 orthorhombic P42/n a=14.956 b=14.956 c=12.017 [57]
Na6Cu8Sn3Se13 cubic Fm3c a =18.4754 [76]
[Cu2SnSe5][Mn(Hen)2(en)] monoclinic P21/c a 9.640 b 21.04 c 10.611 β 100.72° 1.49 eV [77]
[(Mn1.67Zn0.33)(en)6]Sn2Se6 [65]
K2Cu2Sn2Se6 monoclinic C2/c Z=8 black; band gap 1.04 eV [78]
Copper zinc tin selenide Cu2ZnSnSe4 black; photovoltaic 11.6% efficient [29]
catena-[tris(ethane-1,2-diamine)-zinc(ii) (μ-diselenido)-hexakis(μ-selenido)-tri-tin] [Zn(en)3]Sn3Se6(Se2) monoclinic P21/n a 11.949 b 14.060 c 15.794 β 100.39° [52]
tris(ethane-1,2-diamine)-zinc(ii) tris[tetraselanato]-tin [Zn(en)3][Sn(Se4)3] triclinic P1 a 10.156 b 12.096 c 12.109, α 89.64° β 75.49° γ 75.87° [52]
Zn2(en)2(μ4-SnSe4) tetragonal I41/a a =7.8032 c =31.528 [53]
tetrakis(μ-selenido)-bis(selenido)-bis(N,N-bis(2-aminoethyl)ethane-1,2-diamine)-di-tin(iv)-di-zinc(ii) {Zn(tren)}2(μ-Sn2Se6) monoclinic C2/c a 12.414 b 9.846 c 23.970° β 102.395° 2861.5 band gap 2.38 eV [79]
tetrakis(μ-selenido)-bis(selenido)-bis(bis(2-(2-aminoethyl)aminoethyl)amine)-di-tin(iv)-di-zinc(ii) {Zn(tepa)}2(μ-Sn2Se6) tetragonal I41/a a=26.6205 c =10.0533 7124.3 band gap 2.31 eV [79]
catena-[bis(dimethylammonium) octakis(μ-selenido)-tri-tin(iv)-zinc(ii)] [(Me)2NH2]2ZnSn3Se8 monoclinic C2 a=10.961 b=11.056 c=9.683 β=105.17° [80]
(Me4N)2Zn[Sn4Se10] [81]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene [DBNH]2[ZnSnSe4] tetragonal P42/ncm a=13.033 c 6.548 band gap 2.42 eV [62]
K2ZnSn3Se8 monoclinic P21 a 7.639 b 12.400 c 18.384 β 98.13° band gap 2.10 eV [82]
Cu2ZnSnSe4 [75]
[NH4]2Ga4Se8Sn4 monoclinic P21/c a 7.582 b 12.501 c 18.377 β 96.43° [83]
catena-(1-ethylpyridinium hexakis(μ-selenido)-gallium-di-tin hydrate) H3CCH2NC5H5GaSn2Se6 ∙ 0.25H2O tetragonal I41/a a=26.401 c =10.464 orange [84]
x~0.25 Na2−xGa2−xSn1+xSe6 monoclinic C2 a=13.308 b=7.594 c=13.842 β=118.730° 1226.7 [85]
K3Ga6Sn6Se12 cubic Pa3 a=13.5555 Z=12 2490.8 4.347 colourless [86]
KGaSnSe4 cubic Pa3 a=13.5555 Z=12 2490.8 4.347 orange [86]
[(TEPA)Mn]2+4[Sn4Ga4Zn2Se20]8− tetragonal P4b2 a=17.4951 c 13.5849 [87]
(Et4N)2[Sn6Se10Br6] monoclinic P21/n a = 14.0826 b = 14.1904 c = 24.277 β = 92.809° Z = 4 4845.6 [88]
Rb2Sn2Se5 monoclinic C2/c a=11.555 b=8.478 c=12.030 β=108.60 Z=4 1117 4.78 black; oxygen sensitive [89]
Rb4Sn4Se10·1.5H2O R3 a 15.539 c 21.373 [39]
Rb2Cu2Sn2Se6 monoclinic C2/c Z=8 black; band gap 1.04 eV [78]
RbGaSnSe4 cubic Pa3 a=13.7200 2582.63 4.550 orange [86]
Rb2Sn4Se9-H2O orthorhombic Pnma a=13.298 b=12.418 c=12.563 [90]
Rb2MnSn3Se8 monoclinic P21 a 7.7864 b 12.6343 c 18.4878 β 95.810° [91]
Rb2MnSnSe4 monoclinic P21/n a=8.6015 b=10.956 c=10.675 β=90° [92]
Rb4Cu8Sn3S12 cubic Fm3c a=18.0851 [93]
(H3O)RbCu6Sn2S8 tetragonal I4/m a=14.8834 c=7.6466 [93]
SrZnSnSe4 orthorhombic Fdd2 a 21.6984 b 21.873 c 13.1140 [94]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-yttrium] [Y2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.4190 b=13.6062 c=20.6569 Z=8 2.467 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-yttrium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Y2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.24 c=10.940 2.025 yellow [95]
Ru(bpy)3[Sn4Se9] 1755.02 trigonal R3c a=27.240 c=31.01 Z=18 19927 2.632 dark red [96]
β-Ag8SnSe6 Pmn21 [4]
[NH4]3AgSn3Se8 tetragonal P4/nbm a=8.2155 c=13.413 thermochromic: gold-darkred-gold [4][80]
[NH4]4Ag12Sn7Se22 monoclinic C2/c a=52.634 b=6.8175 c=13.5176 β=99.955 Z=4 4959.1 5.270 black; band gap 1.21 eV [4][97]
[(Me)2NH2]0.75[Ag1.25SnSe3] tetragonal P421m a=13.998 c=8.685 Z=8 1701.9 4.403 dark red; band gap 1.85 eV [4][98]
[CH3NH3]2[H3O]Ag5Sn4Se12·C2H5OH tetragonal P421m a=13.6350 c 9.1491 Z=8 band gap 1.80 eV [4][80]
catena-[bis(methylammonium) dimethylammonium dodecakis(μ-selenido)-penta-silver-tetra-tin] [NH3CH3]0.5[NH2(CH3)2]0.25Ag1.25SnSe3 tetragonal P421m b =13.7193 c 9.0964 4.019 [99]
[bmmim]7[AgSn12Se28] triclinic P1 band gap 2.2 eV [4]
heptakis(1,2-dimethyl-3-propyl-1H-imidazol-3-ium) bis(μ3-selenido)-hexacosakis(μ2-selenido)-dodeca-tin-silver [Mmpmim]7Ag5Sn4Se12∙3H2O triclinic P1 a 10.8983 b 13.5554 c 23.091 α 88.904° β 86.700° γ 68.230° [11]
catena-[N1-(2-azaniumylethyl)ethane-1,2-bis(aminium) dodeca-selenium-tetra-tin-penta-silver trihydrate] [H3dien][Ag5Sn4Se12]∙3H2O P421 a =14.2623 b =14.2623 c =9.3022 [100]
K2Ag2SnSe4 P2/c band gap 1.8 eV [4]
K2Ag2Sn2Se6 P4/mmc [4]
K3AgSn3Se8 P4/nbm band gap 1.8 eV [4]
[Mn(NH3)6][Ag4Mn4Sn3Se13] orthorhombic F43c a 19.1263Å b 19.1263Å c 19.1263 [101]
catena-(2-aminoethylammonium bis(μ4-sulfido)-bis(μ3-sulfido)-tin-di-copper-silver) [enH][Cu2AgSnS4] orthorhombic Pnma a=19.726 b=7.8544 c=6.5083 Z=4 1008.35 3.577 red [102]
[Zn(NH3)6][Ag4Zn4Sn3Se13] orthorhombic F43c a=18.9679 b=18.9679 c=18.9679 [101]
(1,4-dabH2)Cu1.72Ag0.28SnSe4 tetragonal P42/n a=14.990 c=12.059 band gap 2.43 eV [103]
Rb3AgSn3Se8 P4/nbm band gap 1.8 eV [4]
Li6.4Cd4.8Sn4Se16 orthorhombic Pna21 a=14.400 b=8.399 c=6.787 band gap 1.95 eV [104]
tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ3-diselenido)-undecakis(μ2-selenido)-tri-cadmium-tetra-tin [DBNH]4[Cd3Sn4Se11(Se2)2] monoclinic C2/c a=22.236 b=12.623 c=21.756 β=109.91° [105]
Cd(tren)SnSe3 triclinic P1 a=7.752 b=8.128 c=12.467, α=97.299° β=103.639° γ=107.325° Z=2 712.1 2.865 [106]
K2CdSnSe4 625.16 tetragonal I42m a=8.084 c=6.920 452.24 photocatalyst [107]
Cu2CdSnSe4 [75]
catena-(1-ethylpyridinium hexakis(μ-selenido)-indium-di-tin hydrate) CH3CH2NC5H5InSn2Se6 ∙ 0.25H2O tetragonal I41/a a=26.946 c =10.283 orange [84]
[NH4]2[In2Sn2Se8] tetragonal I4/mcm a=b 8.3731 c 6.719
catena-[tris(1,10-phenanthroline)-cobalt octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate] Co(phen)3In2Sn2Se8 ∙ C6H11NH2 ∙ 4H2O monoclinic P21/n a=15.610 b=24.238 c=15.828 β=107.04° Z=4 5726 2.169 orange [108]
tris(1,10-phenanthroline)-nickel octakis(μ-selenido)-di-indium-di-tin cyclohexylamine solvate tetrahydrate Ni(phen)3In2Sn2Se8 ∙ C6H11NH2 monoclinic P21/n a=15.574 b=24.083 c=15.804 β=107.11° Z=4 5665 2.192 orange [108]
RbInSnSe4 cubic Pa3 a=13.9728 Z=12 2728.04 4.637 red; air sensitive [109]
RbInSnSe4 monoclinic P21/c a= 7.8104 b= 12.6533 c= 18.7062

β= 96.297

1837.52 4.589 orange [109]
Cs2Sn2Se5 . H2O orthorhombic Ama2 a =12.05 b =12.405 c =9.426 [7]
Cs2Sn2Se5 
Cs2Sn2Se6 triclinic P1 a =7.129 b =7.285 c =7.965, α =95.8° β =115.38° γ =108.46° [90]
Cs2Sn3Se7 monoclinic C2/c a = 23.214, b = 13.679, c =14,657, β= 111.92°, Z = 8, 4317 red; SnSe5 trigonal bipyramids connected in sheets [4][27]
Cs4Sn2Se6 yellow; tetrahedral edge-shared pairs [27]
Cs4Sn4Se10·3.2H2O triclinic P1 a=7.235 b=9.468 c=11.235 α=68.77° β=83.25° γ=84.53° [39]
Cs2Sn4Se9-H2O orthorhombic Pnma a =13.514 b =12.54 c =12.679 [90]
(4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-potassium tris(μ3-selenido)-tris(μ2-selenido)-bis(1,2-ethylenediamine-N)-(4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane)-di-cesium-potassium-di-tin(iv) [K-(2,2,2-crypt)]2Cs2Sn2Se6·2en triclinic P1 a=10.0019 b=13.8929 c=24.478 α=100.204° β=95.701° γ=90.147° [43]
Cs[Cr(en)2SnSe4] 739.67 monoclinic P21/n a=7.6800 b=13.1483 c=15.7069 β=91.176° Z=4 1585.7 3.098 black [110]
Cs2MnSnSe4 orthorhombic Fddd a=6.4075 b=14.416 c=24.820 [92]
Cs2MgSn3Se8 orthorhombic P212121 a 7.9055 b 12.7661 c 18.474 [111]
Cs2MnSn3Se8 orthorhombic P212121 a 7.8798 b 12.7040 c 18.4556 [91]
Mn4Cs10Se17Sn4 ∙ 15.5H2O triclinic P1 a 13.717 b 15.502 c 18.481 α 77.02° β 74.35° γ 69.71° Z=2 3512 3.418 red [56]
Zn4Cs10Se17Sn4 ∙ 17H2O triclinic P1 a 13.537 b 15.256 c 18.41, α 76.98° β 73.78° γ 69.57° Z=2 3386 3.577 yellow [56]
Cs2ZnSn3Se8 orthorhombic P212121 a 7.8146 b 12.6534 c 18.3747 [111]
CsGaSnSe4 orthorhombic Pmcn a 7.6785Å b 12.655Å c 18.278 [85]
Cd4Cs10Se17Sn4 ∙ 17H2O triclinic P1 a 17.8678 b 17.7949 c 23.5518 α 98.682° β 105.75° γ 90.307° Z=4 7116 3.617 yellow [56]
Cs2CdSn3Se8 orthorhombic P212121 a 7.9335 b 12.7336 c 18.5387 [111]
CsInSnSe4 cubic Pa3 a=14.1932 Z=12 2959.2 4.755 red; air sensitive [109]
Ba2SnSe4 709.21 monoclinic P21/c a 8.582 b 9.255 c 12.460 β 114.28° Z=4 902.2 5.221 orange [112]
α-Ba2SnSe5 orthorhombic P212121 dark brown [113]
β-Ba2SnSe5 monoclinic P21/c a = 9.3949 b = 8.8656 c = 12.5745 β = 113.299° Z = 4 961.9 high temperature; red [113]
m-Ba2SnSe5 monoclinic P121/c1 a = 21.17189 b = 9.0915 c = 24.7141 β = 125.621° [114]
Ba6Sn6Se13 orthorhombic P212121 a 9.2998 b 12.384 c 26.896 Z=4 3097.8 5.495 black; 1.52 eV [115]
Li2Ba7Sn4Se16 cubic I43d a=15.1628 Z=4 3486.1 5.170 ? red [116]
Na2Ba7Sn4Se16 cubic I43d a=14.807 Z=4 3246 4.082 red [116]
BaZnSnSe4 orthorhombic Fdd2 a 22.2402 b 22.7047 c 13.1972 6664.0 5.081 red; band gap 1.95 eV [117]
BaGa2SnSe6 trigonal R3 a = 10.145 c = 9.249 Z = 3 824.4 5.253 red

NLO 5.2 × AgGaS2 at 2.09 μm birefringence 0.1649 at 1.064 μm

[118]
Ba4Ga4SnSe12 band gap 2.14 [119]
BaAg2SnSe4 orthorhombic I222 a=7.10 b=7.47 c=8.30 band gap 0.2 eV [4][120]
BaCdSnSe4 684.27 orthorhombic Fdd2 a 22.38 b 22.71 c 13.588 Z=32 6907 5.265 orange [112]
catena-(hexakis(μ2-selenido)-(N-(2-(amino)ethyl)-N'-(2-((2-(amino)ethyl)amino)ethyl)ethane-1,2-diaminato)-di-tin-lanthanum hemihydrate) (H3O)[La(tepa)(μ-1κ2:2κ2-Sn2Se6)] monoclinic C2/c a=13.845 b=9.805 c=22.010 β=105.949° [121]
tetrakis(μ-selenido)-bis(3,6,9,12-tetraazatetradecane-1,14-diamine)-nitrato-chloro-di-lanthanum(iii)-tin {La(peha)(Cl)}{La(peha)(NO3)}(μ-1κ2:2κ2-SnSe4)] triclinic P1 a 8.411 b 14.760 c 16.244 α 92.57° β 91.95° γ 102.18° Z=2 1967.3 2.15 light yellow [122]
2,2'-(ethane-1,2-diyldiimino)diethanaminium tetrakis(μ-selenido)-tetrakis(triethylenetetramine )-diselenido-di-tin-di-lanthanum(iii) bis(μ-selenido)-tetraselenido-di-tin monohydrate [H2trien][{La(trien)2}2(μ-1κ:2κ-Sn2Se6)][Sn2Se6]·H2O monoclinic P21/c a=14.903 b=16.763 c=16.552 β=101.231° Z=2 4056 2.01 orange [122]
[{La(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ triclinic P1 a 10.253 b 13.061 c 15.847 α 80.62° β 73.59° γ 88.60° Z=1 2007.9 2.514 red [123]
[La2(en)8(μ-Se2)]Sn2Se monoclinic P21/n a 10.079 b 14.843 c 14.918 β 90.599° Z=2 2231.7 2.422 yellow [123]
La3AgSnSe7 P63 [4]
catena-(hexakis(μ2-Selenido)-(tetraethylenepentamine)-cerium-di-tin monohydrate) (H3O)[Ce(tepa)(μ-1κ2:2κ2-Sn2Se6)] monoclinic C2/c a=13.852 b=9.802 c=22.035 β=105.98° [124]
tetrakis(μ2-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-cerium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ2-selenido)-tetraselenido-di-tin [Htrien]2[{Ce(trien)(tren)}2(μ-1κ:2κ-Sn2Se6)] triclinic P1 a 9.832 b 10.584 c 18.091, α 90.097° β 92.448° γ 94.500° [124]
[{Ce(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ triclinic P1 a 10.2333 b 13.0790 c 15.7663, α 80.422° β 73.738° γ 88.376° Z=1 1997.1 2.532 orange [125]
[{Ce(en)4}2(μ-Se2)]Sn2Se6 monoclinic P21/n a 10.094 b 16.616 c 13.397 β 101.878° Z=2 2198.9 2.462 light yellow [125]
BaCeSn2Se6 orthorhombic Pmc21 a=4.1908 b=20.749 c=12.406 [126]
tetrakis(μ2-Selenido)-bis(triethylenetetramine)-bis(tris(2-aminoethyl)amine)-diselenido-di-neodymium-di-tin bis((2-((2-aminoethyl)amino)ethyl)(2-aminoethyl)ammonium) bis(μ2-selenido)-tetraselenido-di-tin [Htrien]2[{Pr(trien)(tren)}2(μ-1κ:2κ-Sn2Se6)] triclinic P1 a 9.842 b 10.578 c 18.080, α 90.065° β 92.532° γ 94.511° [124]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-praseodymium] [Pr2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.450 b=13.617 c=21.005 Z=8 2.622 orange [95]
[{Pr(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a 10.197 b 11.7622 c 15.497 β 98.967° Z=2 1835.9 2.510 yellow [125]
catena-(bis(μ2-hydroxo)-tetrakis(μ2-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-neodymium-di-tin) [{Nd(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)] orthorhombic Pbca a=12.485 b=13.601 c=20.917 [121]
[{Nd(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a 10.176 b 11.772 c 15.470 β 99.128° Z=2 1829.8 2.531 yellow [125]
[{Nd(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ triclinic P1 a 10.184 b 12.979 c 15.751, α 80.448° β 73.991° γ 88.552° Z=1 1973.1 2.576 red [125]
ethane-1,2-diaminium tris(N-(2-(amino)ethyl)ethane-1,2-diamine)-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [Hen][Sm(dien)3]Sn2Se6 triclinic P1 a=10.044 b=12.803 c=15.811 α=66.32° β=72.86° γ=68.35° [127]
bis(bis(N,N-bis(2-(amino)ethyl)ethane-1,2-diamine)-chloro-samarium) hemikis(N,N-bis(2-aminoethyl)ethane-1,2-diamine) bis(μ-selenido)-tetrakis(selenido)-di-tin [Sm(trien)(tren)(Cl)]2Sn2Se6·0.5en triclinic P1 a=10.348 b=10.575 c=14.043 α=77.26° β=87.78° γ=61.410° [127]
bis(N,N'-bis(2-(amino)ethyl)ethane-1,2-diamine)-bis(ethane-1,2-diamine)-bis(μ-hydroxy)di-samarium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [{Sm(en)(trien)}2(μ-OH)2]Sn2Se6 triclinic P1 a=10.044 b=12.803 c=15.811, α=66.32° β=72.86° γ=68.35° [127]
catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-samarium-tin hemihydrate] [{Sm(tepa)(μ-OH)}2 (μ-1κ:2κ-Sn2Se6)]n·nH2O monoclinic C2/c a=22.944 b=11.946 c=18.907 β=125.53° Z=4 4217 2.27 yellow [122]
[Hdien][Sm(dien)2(μ-SnSe4)] monoclinic P2/c a 10.185 b 9.471 c 13.808 β 102.256° [128]
Eu8(Sn4Se14)(Se3)2 orthorhombic P21212 a = 11.990 b = 16.425 c = 8.543 [129]
catena-[bis(μ-selenido)-(μ-hydroxo)-(3,6,9-triazaundecan-1,11-diamine)-selenido-europium-tin hemihydrate] [{Eu(tepa)(μ-OH)}2 (μ-1κ:2κ-Sn2Se6)]n·nH2O monoclinic C2/c a=22.904 b=11.981 c=18.894 β=125.52° Z=4 4220 2.28 yellow [122]
[Hdien][Eu(dien)2(μ-SnSe4)] monoclinic P2/c a 10.185 b 9.453 c 13.791 β 102.165° [128]
[Eu2(dien)4(μ-OH)2]Sn2Se6 monoclinic P21/n a 12.027 b 11.802 c 13.827 β 99.179° [128]
[{Eu(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a = 10.136 b = 11.771 c = 15.423 β = 99.322° Z = 2 1815.8 [130]
catena-(bis(μ2-hydroxo)-tetrakis(μ2-selenido)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-diselenido-di-gadolinium-di-tin monohydrate) [{Gd(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]·H2O monoclinic C2/c a=22.82 b=11.975 c=18.918 β=125.975° [121]
[{Gd(en)3}2(μ-OH)2]Sn2Se6 monoclinic P21/n a 9.993 b 11.842 c 15.313° β 99.979° Z=2 1784.6 2.643 yellow [125]
[Hdien][Gd(dien)2(μ-SnSe4)] monoclinic P21/c a 10.300 b 9.426 c 13.875 β 101.678° Z=2 1319.3 2.271 red [125]
[Gd(dap)4]2[Sn2Se6]Cl2 monoclinic P21/c a=10.2385 b=14.1276 c=18.068 β =102.745° [131]
[{Tb(en)3}2(μ-OH)2]Sn2Se6 1423.62 monoclinic P21/n a=10.120 b=11.781 c=15.403 β=99.534° Z=2 1811.1 2.611 [132]
bis(tetrakis(propane-1,2-diamine)-terbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate [Tb(dap)4]2[Sn2Se6]Cl2·H2O monoclinic P21/c a=10.240 b=14.116 c=18.030 β=102.808° [131]
catena-[bis(μ2-selenido)-(μ2-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-dysprosium-tin] [Dy2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.4132 b=13.5901 c=20.6722 Z=8 2.759 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-dysprosium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Dy2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.2390 c=11.0380 2.229 yellow [95]
[Dy2(en)6(μ2-OH)2][Sn2Se6] [133]
bis(tetrakis(propane-1,2-diamine)-dysprosium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate [Dy(dap)4]2[Sn2Se6]Cl2·H2O monoclinic P21/c a=10.214 b=14.118 c=18.000 β=102.798° [131]
bis(tetrakis(Propane-1,2-diamine)-holmium chloride) 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) [Ho(dap)4]2[Sn2Se6]Cl2 monoclinic P21/c a=10.1839 b=14.1303 c=18.0100 β=102.571° Z=4 2529.5 yellow [134]
bis(μ2-Hydroxo)-tetrakis(diethylenetriamine)-di-holmium 1,3,2,4-diselenadistannetane-2,2,4,4-tetrakis(selenolate) {[Ho(dien)2]2(μ2-OH)2}[Sn2Se6] monoclinic P21/n a=12.0096 b=11.7181 c=13.7717 β=99.138° Z=2 1913.5 2.586 yellow [134]
bis(bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-bis(μ-hydroxo)-di-holmium) tricyclo[3.3.1.13,7]tetrastannaselenane-1,3,5,7-tetrakis(selenolate) tetrahydrate [Ho2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.076 c 10.948 8629.6 2.281 yellow; supertetrahedron [134]
catena-[bis(μ2-selenido)-(μ2-hydroxo)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-erbium-tin] [Er2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.418 b=13.605 c=20.636 Z=8 2.778 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-erbium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Er2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.1622 c=11.0089 2.261 yellow [95]
[Er2(en)6(μ2-OH)2][Sn2S6] monoclinic P21/n a 9.951 b 11.860 c 15.278 β 100.239° [133]
bis(tetrakis(propane-1,2-diamine)-erbium) dichloride bis(μ-selenido)-tetrakis(selenido)-di-tin monohydrate [Er(dap)4]2[Sn2Se6]Cl2·H2O monoclinic P21/c a=10.204 b=14.176 c=18.041 β=102.530° [131]
catena-[(μ-hydroxo)-bis(μ-selenido)-(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-selenido-tin-thulium [Tm2(tepa)2(μ-OH)2Sn2Se6] orthorhombic Pbca a=12.399 b=13.518 c=20.504 Z=8 2.820 orange [95]
bis(bis(μ2-hydroxo)-bis(N-(2-aminoethyl)-N'-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine)-dichloro-di-thulium) hexakis(μ2-selenido)-tetrakis(selenido)-tetra-tin tetrahydrate [Tm2(tepa)2(μ2-OH)2Cl2]2[Sn4Se10]·4H2O tetragonal I41/a a=28.2080 c=11.0142 2.258 yellow [95]
[Hen]4[Tm(en)4]2[Ag6Sn6S20]·3en monoclinic C2/m a 14.517 b 24.380 c 13.422 β 94.46° [135]
catena-((μ2-Hydroxo)-bis(μ2-selenido)-selenide-(tetraethylenepentamine)-tin-ytterbium hemihydrate) [{Yb(tepa)(μ-OH)}2(μ-1κ:2κ-Sn2Se6)]·H2O monoclinic C2/c a=21.255 b=12.835 c=17.633 β=125.41° [124]
bis(μ2-Hydroxo)-tetrakis(diethylenetriamine)-di-ytterbium bis(μ2-selenido)-tetraselenido-di-tin [{Yb(dien)2}2(μ-OH)2]Sn2Se6 monoclinic P21/n a=12.026 b=11.666 c=13.819 β=98.971° Z=4 [124]
DBU=1,8-diazabicyclo[5.4.0]undec-7-ene

catena-(bis(2,3,4,6,7,8,9,10-Octahydropyrimido(1,2-a)azepin-1-ium) bis(μ3-selenido)-pentakis(μ2-selenido)-di-mercury)

[DBUH]2[Hg2Sn2Se6(Se2)] triclinic P1 a 10.390 b 12.244 c 13.977 α 86.58° β 79.51° γ 70.14° Z=2 1644.3 3.025 yellow [136]
catena-(bis(2,3,4,6,7,8,9,10-Octahydro-1H-pyrimido(1,2-a)azepin-5-ium) (μ3-diselenido)-(μ3-selenido)-pentakis(μ2-selenido)-di-mercury-di-tin) [DBUH]2[Hg2Sn2Se5(Se2)] monoclinic P21/c a=14.7289 b=18.6045 c=13.5200 β=111.571 3445.33 3.040 red [136]
(tetrakis(2,3,4,6,7,8-Hexahydro-1H-pyrrolo[1,2-a]pyrimidin-5-ium) bis(μ3-diselenido)-undecakis(μ2-selenido)-tri-mercury-tetra-tin [DBNH]4[Hg3Sn4Se11(Se2)2] monoclinic C2/c a 22.137 b 12.663 c 21.780° β 109.48° [105]
DBN=1,5-diazabicyclo[4.3.0]non-5-ene [DBNH]2[HgSnSe4] tetragonal P42/ncm a=12.8605 c 6.85560 band gap 2.46 eV [62]
Li4HgSn2Se7 monoclinic Cc a 18.286b 7.197 c 10.809 β 93.44° red [137]
Li2HgSnSe4 orthorhombic Pna21 a=14.458 b=8.378 c=6.8215 Z=4 826.3 5.217 red; SHG 6.0 × AgGaS2 [138]
Na2HgSn2Se6 tetragonal I4/mcm a=7.8571 c=20.214 [139]
Na2Hg3Sn2Se8 1516.81 tetragonal P4c2 a=9.3749 c=9.790 Z=2 860.5 5.854 red [138]
K2HgSnSe4 tetragonal I4/mcm a=8.0531Å c=6.9501 [140]
phen = 1,10-phenanthroline; eta = ethanolamine [Fe(phen)3]Hg2Sn2Se7·1.5eta·0.25H2O triclinic P1 a 13.0238 b 13.6275 c 14.4626 α 81.104° β 88.117° γ 82.840° [141]
teta = triethylenetetramine [Ni2(teta)2(μ-teta)]HgSn3Se9 orthorhombic Pmc21 a 22.731 b 13.2151 c 14.6495 [141]
SrHgSnSe4 orthorhombic Fdd2 a 21.9027 b 21.9059 c 13.5010 SHG 5 × AgGaS2 [142]
Cs2HgSn3Se8 orthorhombic P212121 a 7.9196 b 12.6657 c 18.5375 [111]
BaHgSnSe4 orthorhombic Fdd2 a 22.441 b 22.760 c 13.579 SHG 5 × AgGaS2 [142]
Tl4Sn2Se6 tetrahedral edge-shared pairs [27]
TlGaSnSe4 monoclinic P21/c a=7.501 b= 12.175 c= 18.203

β= 97.164 Z=8

1649.4 5.646 red [86]
TlGaSnSe4 cubic Pa3 a=13.4755 Z=12 2447.0 5.770 red [86]

References

[edit]
  1. ^ a b Krebs, Bernt; Hürter, Hans-Ulrich (March 1980). "Selenostannate aus wäßriger Lösung: Darstellung und Struktur von Na4SnSe4 · 16 H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 462 (1): 143–151. doi:10.1002/zaac.19804620115. ISSN 0044-2313.
  2. ^ a b c d Cai, Ting; Zhu, Jian-Nan; Cheng, Fang-Fang; Li, Peng; Li, Wei; Zhao, Ming-Yu; Xiong, Wei-Wei (January 2019). "Growing crystalline selenidostannates in deep eutectic solvent". Inorganica Chimica Acta. 484: 214–218. doi:10.1016/j.ica.2018.09.046. S2CID 105120366.
  3. ^ Dehnen, Stefanie; Zimmermann, Christian; Anson, Christopher E. (January 2002). "Syntheses, Crystal Structures, and Energetics of a Complete Series of Lithium Salts of Binary or Ternary Hexachalcogenodistannates(IV), Li4Sn2E6 · 8en (E = S, Se, Te), Li4Sn2S1.36Se4.64 · 8en, Li4Sn2Se2Te4 · 8en, Li4Sn2Se2Te4 · 9en, and Li4Sn2S2Te4 · 10en". Zeitschrift für anorganische und allgemeine Chemie (in German). 628 (1): 279–288. doi:10.1002/1521-3749(200201)628:1<279::AID-ZAAC279>3.0.CO;2-L. ISSN 0044-2313.
  4. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj Wang, Kai-Yao; Liu, Hua-Wei; Zhang, Shu; Ding, Dong; Cheng, Lin; Wang, Cheng (2019-03-04). "Selenidostannates and a Silver Selenidostannate Synthesized in Deep Eutectic Solvents: Crystal Structures and Thermochromic Study". Inorganic Chemistry. 58 (5): 2942–2953. doi:10.1021/acs.inorgchem.8b02610. ISSN 0020-1669. PMID 30789725. S2CID 73484781.
  5. ^ a b c Sheldrick, W. S.; Braunbeck, H. G. (July 1993). "Darstellung und Kristallstruktur von Ethylendiammonium-Selenostannaten(IV) sowie von [2 SnSe2 · en]?". Zeitschrift für anorganische und allgemeine Chemie (in German). 619 (7): 1300–1306. doi:10.1002/zaac.19936190725. ISSN 0044-2313.
  6. ^ a b Dehnen, Stefanie; Zimmermann, Christian (2002). "Syntheses, Crystal Structures, and Reactivity of [enH]4[Sn2Se6]·en, [enH]4[Sn2Te6]·en and [enH]4[Sn2S6]: Known Anions within Novel Coordination Spheres obtained by Novel Synthesis Routes". Zeitschrift für Anorganische und Allgemeine Chemie. 628 (11): 2463–2469. doi:10.1002/1521-3749(200211)628:11<2463::AID-ZAAC2463>3.0.CO;2-Y.
  7. ^ a b c Loose, Anja; Sheldrick, William S. (1999). "Synthesis and Structure of [Sn4Se11]6-,1∞ [Sn2Se52-], and1∞ [Sn3Se72-] - Model Anions for the Solventothermal Reaction Pathway to Lamellar Selenidostannates(IV)". Zeitschrift für Anorganische und Allgemeine Chemie. 625 (2): 233–240. doi:10.1002/(SICI)1521-3749(199902)625:2<233::AID-ZAAC233>3.0.CO;2-M.
  8. ^ Park, Chang-Woo; Pell, Michael A.; Ibers, James A. (1996-01-01). "Electrochemical Synthesis of [NEt 4 ] 2 [enH] 2 [Ge 2 Se 6 ] and [NEt 4 ] 4 [Sn 4 Se 10 ]". Inorganic Chemistry. 35 (16): 4555–4558. doi:10.1021/ic9514859. ISSN 0020-1669.
  9. ^ Kim, Kang–Woo (2022-06-27). "Crystal structure of bis(tetrapropylammonium) nonaselenidotetrastannate(IV), (Pr 4 N) 2 [Sn 4 Se 9 ]". Zeitschrift für Kristallographie - New Crystal Structures. 237 (3): 409–411. doi:10.1515/ncrs-2022-0091. ISSN 1433-7266. S2CID 247599523.
  10. ^ a b Lu, Sheming; Ke, Yanxiong; Li, Jianmin; Zhou, Shuxi; Wu, Xintao; Du, Wenxin (December 2003). "Solvothermal Synthesis and Structure of Two 2D Tin–Selenides with Long Alkyldiamine NH 2 (CH 2 ) n NH 2 (n = 8, 10)". Structural Chemistry. 14 (6): 637–642. doi:10.1023/B:STUC.0000007574.13596.f6. ISSN 1040-0400. S2CID 93163632.
  11. ^ a b c d e f Li, Jian-Rong; Xiong, Wei-Wei; Xie, Zai-Lai; Du, Cheng-Feng; Zou, Guo-Dong; Huang, Xiao-Ying (2013). "From selenidostannates to silver-selenidostannate: structural variation of chalcogenidometallates synthesized in ionic liquids". Chem. Commun. 49 (2): 181–183. doi:10.1039/C2CC37051D. ISSN 1359-7345. PMID 23169004.
  12. ^ a b Wang, Zi; Du, Cheng-Feng; Cheng, Chu-Chu; Shen, Nan-Nan; Li, Jian-Rong; Huang, Xiao-Ying (December 2016). "Two new selenidostannates with a [Sn3Se7]n2n− layer from the imidazolium-based ionic liquids: The role of (Bzmim)+ and aggregated cation of [(Emim)3Cl]2+". Inorganic Chemistry Communications. 74: 58–61. doi:10.1016/j.inoche.2016.10.040.
  13. ^ Wang, Kai-Yao; Ding, Dong; Zhang, Shu; Wang, Yanlong; Liu, Wei; Wang, Shuao; Wang, Shuai-Hua; Liu, Dan; Wang, Cheng (2018), CCDC 1821847: Experimental Crystal Structure Determination, Cambridge Crystallographic Data Centre, doi:10.5517/ccdc.csd.cc1z4s85, retrieved 2022-07-05
  14. ^ Wang, Kai-Yao; Ding, Dong; Zhang, Shu; Wang, Yanlong; Liu, Wei; Wang, Shuao; Wang, Shuai-Hua; Liu, Dan; Wang, Cheng (2018), CCDC 1821848: Experimental Crystal Structure Determination, Cambridge Crystallographic Data Centre, doi:10.5517/ccdc.csd.cc1z4s96, retrieved 2022-07-05
  15. ^ Kim, Kang-Woo; Heo, Man-Young (2018-03-28). "Crystal structure of bis( N,N,N -trimethylbutanaminium) poly[heptaselenidotristannate(IV)], C 14 H 36 N 2 Se 7 Sn 3". Zeitschrift für Kristallographie - New Crystal Structures. 233 (2): 255–257. doi:10.1515/ncrs-2017-0255. ISSN 2197-4578. S2CID 103502515.
  16. ^ Han, Xiaohui; Meng, Junling; Xu, Jin; Liu, Xiaojuan; Liu, Dan; Wang, Cheng (January 2016). "Synthesis, crystal structure, and optical property of a one-dimensional selenidostannate: [AEPPH 2 ] 2 [Sn 5 Se 12 ] (AEPP = N -aminoethylpiperazine)". Inorganic Chemistry Communications. 63: 42–47. doi:10.1016/j.inoche.2015.11.009.
  17. ^ a b c d e f Liu, Guang-Ning; Guo, Guo-Cong; Zhang, Ming-Jian; Guo, Jin-Shuang; Zeng, Hui-Yi; Huang, Jin-Shun (2011-10-03). "Different Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline) m ] 2+ ( m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components". Inorganic Chemistry. 50 (19): 9660–9669. doi:10.1021/ic201413h. ISSN 0020-1669. PMID 21902192.
  18. ^ a b c d Santner, Silke; Sprenger, Jan A. P.; Finze, Maik; Dehnen, Stefanie (2018-03-07). "The Role of [BF 4 ] − and [B(CN) 4 ] − Anions in the Ionothermal Synthesis of Chalcogenidometalates". Chemistry: A European Journal. 24 (14): 3474–3480. doi:10.1002/chem.201705297. PMID 29266707.
  19. ^ a b c Lin, Yumei; Xie, Dewang; Massa, Werner; Mayrhofer, Leonhard; Lippert, Sina; Ewers, Benjamin; Chernikov, Alexey; Koch, Martin; Dehnen, Stefanie (2013-07-01). "Changes in the Structural Dimensionality of Selenidostannates in Ionic Liquids: Formation, Structures, Stability, and Photoconductivity". Chemistry: A European Journal. 19 (27): 8806–8813. doi:10.1002/chem.201300807. PMID 23677670.
  20. ^ Lin, Yumei; Dehnen, Stefanie (2011-09-05). "[BMIm] 4 [Sn 9 Se 20 ]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure". Inorganic Chemistry. 50 (17): 7913–7915. doi:10.1021/ic200697k. ISSN 0020-1669. PMID 21809815.
  21. ^ a b Wang, Kai-Yao; Ding, Dong; Zhang, Shu; Wang, Yanlong; Liu, Wei; Wang, Shuao; Wang, Shuai-Hua; Liu, Dan; Wang, Cheng (2018). "Preparation of thermochromic selenidostannates in deep eutectic solvents". Chemical Communications. 54 (38): 4806–4809. doi:10.1039/C8CC01614C. ISSN 1359-7345. PMID 29687106.
  22. ^ a b c d Hu, Dandan; Zhang, Yingying; Yang, Huajun; Lin, Jian; Wu, Tao (2017). "Structural transformation of selenidostannates from 1D to 0D and 2D via a stepwise amine-templated assembly strategy". Dalton Transactions. 46 (23): 7534–7539. doi:10.1039/C7DT01546A. ISSN 1477-9226. PMID 28573282.
  23. ^ Kim, Kang-Woo (2005-12-20). "DMF Solvothermal Synthesis and Structural Characterization of [dabcoH]2[(CH3)2NH2]2[Sn2Se6]". Journal of the Korean Chemical Society. 49 (6): 603–608. doi:10.5012/JKCS.2005.49.6.603.
  24. ^ Mitzi, David B. (2005-05-01). "Synthesis, Structure, and Thermal Properties of Soluble Hydrazinium Germanium(IV) and Tin(IV) Selenide Salts". Inorganic Chemistry. 44 (10): 3755–3761. doi:10.1021/ic048276l. ISSN 0020-1669. PMID 15877460.
  25. ^ Blecher, Axel; Dräger, Martin; Mathiasch, Bernd (1981-11-01). "(MeSn) 4 Se 6 , Geometrie und Schwingungsformen eines Adamantan-Gerüstes aus Zinn-Selen-Bindungen / (MeSn) 4 Se 6 , Geometry and Vibrational Modes of an Adamantane Framework Formed by Tin-Selenium Bonds". Zeitschrift für Naturforschung B. 36 (11): 1361–1367. doi:10.1515/znb-1981-1103. ISSN 1865-7117.
  26. ^ a b c Hartmann, Felix; Benkada, Assma; Indris, Sylvio; Poschmann, Michael; Lühmann, Henning; Duchstein, Patrick; Zahn, Dirk; Bensch, Wolfgang (2022-07-04). "Directed Dehydration as Synthetic Tool for Generation of a New Na 4 SnS 4 Polymorph: Crystal Structure, Na + Conductivity, and Influence of Sb-Substitution". Angewandte Chemie International Edition. 61 (36): e202202182. doi:10.1002/anie.202202182. ISSN 1433-7851. PMC 9546091. PMID 35648135. S2CID 249235734.
  27. ^ a b c d e f g Sheldrick, W. S.; Braunbeck, H.-G. (1990-12-01). "Darstellung und Kristallstruktur von Cs 2 Sn 3 Se 7 , ein Cäsium-selenostannat(IV) mit fünffach koordiniertem Zinn / Preparation and Crystal Structure of Cs 2 Sn 3 Se 7 , a Cesium Selenostannate(IV) with Pentacoordinated Tin". Zeitschrift für Naturforschung B. 45 (12): 1643–1646. doi:10.1515/znb-1990-1208. ISSN 1865-7117. S2CID 96371631.
  28. ^ Lühmann, Henning; Jeß, Inke; Näther, Christian; Bensch, Wolfgang (2020-02-28). "Crystal Structures and Selected Properties of Co II Containing Thiostannates prepared by a New Room Temperature Route". Zeitschrift für anorganische und allgemeine Chemie. 646 (4): 234–240. doi:10.1002/zaac.201900227. ISSN 0044-2313.
  29. ^ a b c Ritchie, Cameron; Chesman, Anthony Sidney Richard; Jasieniak, Jacek; Mulvaney, Paul (2019-03-26). "Aqueous Synthesis of Cu 2 ZnSnSe 4 Nanocrystals". Chemistry of Materials. 31 (6): 2138–2150. doi:10.1021/acs.chemmater.9b00100. ISSN 0897-4756. S2CID 107396726.
  30. ^ Krebs, Bernt; Müller, Herbert (January 1983). "Selenogermanate aus wäßriger Lösung: Darstellung und Struktur von Na4Ge2Se6 . 16 H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 496 (1): 47–57. doi:10.1002/zaac.19834960106. ISSN 0044-2313.
  31. ^ Loose, A.; Sheldrick, W. S. (2001). "Synthesis and Structure of the Bicyclic [Sn4Se11]6– Anion in Na6Sn4Se11 · 22 H2O". Zeitschrift für Anorganische und Allgemeine Chemie. 627 (9): 2051. doi:10.1002/1521-3749(200109)627:9<2051::AID-ZAAC2051>3.0.CO;2-6.
  32. ^ Du, Cheng-Feng; Li, Jian-Rong; Shen, Nan-Nan; Huang, Xiao-Ying (June 2016). "Ionothermal synthesis and electrochemical properties of a selenidostannate containing the mixed cations of Na+ and enH+". Journal of Solid State Chemistry. 238: 203–209. Bibcode:2016JSSCh.238..203D. doi:10.1016/j.jssc.2016.03.036.
  33. ^ Ruzin, Eugen; Zimmermann, Christian; Hillebrecht, Pierre; Dehnen, Stefanie (May 2007). "Syntheses and Structures of Solvated Tetrasodiumtetrachalcogenostannates [Na 4 ( en ) 4 ][SnE 4 ] ( en = 1,2-diaminoethane; E = Te, Se), and their Reactions Toward Further Ternary or Quaternary Chalcogenometallates [Mn( en ) 3 ] 2 [Sn 2 Te 6 ]·4H 2 O or [Na 10 (H 2 O) 34 ][Mn 4 ( μ 4 -Se)(SnSe 4 ) 4 ]". Zeitschrift für anorganische und allgemeine Chemie. 633 (5–6): 820–829. doi:10.1002/zaac.200700071. ISSN 0044-2313.
  34. ^ Gao, Hongbo; Zhang, Kewang; Abudurusuli, Ailijiang; Bai, Chen; Yang, Zhihua; Lai, Kangrong; Li, Junjie; Pan, Shilie (2021-10-18). "Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)". Materials. 14 (20): 6166. Bibcode:2021Mate...14.6166G. doi:10.3390/ma14206166. ISSN 1996-1944. PMC 8537313. PMID 34683761.
  35. ^ Shi, Zhi-Hui; Yang, Mei; Yao, Wen-Dong; Liu, Wenlong; Guo, Sheng-Ping (2021-09-20). "SnPQ 3 (Q = S, Se, S/Se): A Series of Lone-Pair Cationic Chalcogenophosphates Exhibiting Balanced NLO Activity Originating from SnQ 8 Units". Inorganic Chemistry. 60 (18): 14390–14398. doi:10.1021/acs.inorgchem.1c02178. ISSN 0020-1669. PMID 34464110. S2CID 237374017.
  36. ^ Klepp, Kurt O. (1992-03-01). "Na 4 SnSe 4 und K 4 SnSe 4 , zwei neue Selenostannate mit isolierten Anionen / Na 4 SnSe 4 and K 4 SnSe 4 , Two New Selenostannates with Discrete Anions". Zeitschrift für Naturforschung B. 47 (3): 411–417. doi:10.1515/znb-1992-0319. ISSN 1865-7117.
  37. ^ Peters, Bertram; Santner, Silke; Dehnen, Stefanie (2020-09-30). "Dimensional Reduction of a Selenido Stannate Salt in Ionic Liquids to form 2D-K 2 Sn 2 Se 5 , a Direct Heavy Analogue of an Oxo Silicate". Zeitschrift für anorganische und allgemeine Chemie. 646 (18): 1466–1469. doi:10.1002/zaac.202000162. ISSN 0044-2313. S2CID 225795333.
  38. ^ Yao, Hua–Gang; Zhang, Ren–Chun; Ji, Shou–Hua; Ji, Min; An, Yong–Lin; Ning, Gui–Ling (November 2010). "Mineralizer effect on the synthesis of two types of one-dimensional chains silver-selenogermanate and selenostannate". Inorganic Chemistry Communications. 13 (11): 1296–1298. doi:10.1016/j.inoche.2010.07.020.
  39. ^ a b c Loose, Anja; Sheldrick, William S (October 1999). "Solventothermal Synthesis and Structure of Lamellar Alkali Metal Selenidostannates(IV) A4Sn4Se10·xH2O with 20- (A=Cs; x=3.2) and 36-Membered Pores (A=K, Rb; x=4.5, 1.5)". Journal of Solid State Chemistry. 147 (1): 146–153. doi:10.1006/jssc.1999.8205.
  40. ^ Campbell, Janette; Devereux, Lesley A.; Gerken, Michael; Mercier, Hélène P. A.; Pirani, Ayaaz M.; Schrobilgen, Gary J. (1996-01-01). "Ditin(IV) Chalcogenide Anions: 77 Se, 119 Sn, and 125 Te Solution NMR Study of the Sn 2 Ch 6 4- and Sn 2 Ch 7 4- (Ch = Se, Te) Anions, X-ray Crystal Structures and Raman Spectra of K + (N(CH 3 ) 4 + ) 3 Sn 2 Se 6 4- , (enH + ) 2 (2,2,2-crypt-K + ) 2 Sn 2 Se 6 4- , and (K + ) 2 (2,2,2-crypt-K + ) 2 Sn 2 Te 6 4- , and X-ray Crystal Structures of K + (2,2,2-crypt-K + ) 2 HOSnTe 3 3- and K + (2,2,2-crypt-K + ) 2 HOSnTe 3 3- ·en". Inorganic Chemistry. 35 (10): 2945–2962. doi:10.1021/ic950917c. ISSN 0020-1669.
  41. ^ Pirani, Ayaaz M.; Mercier, Hélène P. A.; Dixon, David A.; Borrmann, Horst; Schrobilgen, Gary J. (2001-09-01). "Syntheses, Vibrational Spectra, and Theoretical Studies of the Adamantanoid Sn 4 Ch 10 4 - (Ch = Se, Te) Anions: X-ray Crystal Structures of [18-Crown-6-K] 4 [Sn 4 Se 10 ]·5en and [18-Crown-6-K] 4 [Sn 4 Te 10 ]·3en·2THF". Inorganic Chemistry. 40 (19): 4823–4829. doi:10.1021/ic010242f. ISSN 0020-1669. PMID 11531427.
  42. ^ Borrmann, H.; Pirani, A. M.; Schrobilgen, G. J. (1997-08-15). "(K + ) 2 (18-crown-6-K + ) 2 [Sn 2 Se 6 ] 4− .4en: an [Sn 2 Se 6 ] 4− Anion with a Short Sn". Acta Crystallographica Section C Crystal Structure Communications. 53 (8): 1004–1006. Bibcode:1997AcCrC..53.1004B. doi:10.1107/S0108270197004939. ISSN 0108-2701.
  43. ^ a b Wang, Jian-Qiang; Hoffmann, Stephan D.; Fässler, Thomas F. (December 2008). "Polytellurides and Polyselenides – Compounds Containing $_{\infty}^{1}\rm [Te_{6}-Te_{4}]^{4-}$ and [Sn(Se 4 ) 3 ] 2− Anions". Zeitschrift für anorganische und allgemeine Chemie. 634 (15): 2917–2921. doi:10.1002/zaac.200800329. ISSN 0044-2313.
  44. ^ Menezes, Prashanth W.; Fässler, Thomas F. (June 2012). "Synthesis and Crystal Structure of Ca(en)4Ca(en)3[Sn2Se6] and Ca(en)4Se4 in Superheated and Supercritical Ethylenediamine". Zeitschrift für anorganische und allgemeine Chemie (in German). 638 (7–8): 1109–1113. doi:10.1002/zaac.201200120.
  45. ^ Cao, Shumei; Chen, Yao; Liu, Xing; Zhou, Jian; Liu, Jiang-tao (November 2021). "The first selenidostannate directed by low-valent vanadium(II) complex: Photocurrent response and magnetic properties". Inorganic Chemistry Communications. 133: 108862. doi:10.1016/j.inoche.2021.108862.
  46. ^ a b c d Chen, Yao; Liu, Xing; Zhou, Jian; Zou, Hua-hong; Xiang, Bin (2021-02-15). "One-Dimensional Vanadium(III) Chalcogenidostannates Incorporating [V(tepa)] 3+ Complexes as Bridging Groups". Inorganic Chemistry. 60 (4): 2127–2132. doi:10.1021/acs.inorgchem.0c03484. ISSN 0020-1669. PMID 33503370. S2CID 231765552.
  47. ^ a b Lu, Jia-Lin; Tang, Chun-Ying; Wang, Fang; Shen, Ya-Li; Yuan, Ya-Xian; Jia, Ding-Xian (September 2014). "Ionothermal syntheses and optical property of chromium selenidostannates containing linear polyamine ligand". Inorganic Chemistry Communications. 47: 148–151. doi:10.1016/j.inoche.2014.07.037.
  48. ^ a b c Du, Cheng-Feng; Feng, Mei-Ling; Li, Jian-Rong; Zou, Guo-Dong; Du, Ke-Zhao; Huang, Xiao-Ying (2014). "Assembly and structural transformation of organic-decorated manganese selenidostannates". Dalton Trans. 43 (16): 6002–6005. doi:10.1039/C3DT53346H. ISSN 1477-9226. PMID 24619386.
  49. ^ a b c d Du, Cheng-Feng; Li, Jian-Rong; Feng, Mei-Ling; Zou, Guo-Dong; Shen, Nan-Nan; Huang, Xiao-Ying (2015). "Varied forms of lamellar [Sn 3 Se 7 ] n 2n− anion: the competitive and synergistic structure-directing effects of metal–amine complex and imidazolium cations". Dalton Transactions. 44 (16): 7364–7372. doi:10.1039/C5DT00620A. ISSN 1477-9226. PMID 25799365.
  50. ^ a b c Lu, Jialin; Shen, Yali; Wang, Fang; Tang, Chunying; Zhang, Yong; Jia, Dingxian (March 2015). "Solvothermal Syntheses and Characterizations of Selenidostannate Salts of Transition Metal Complex Cations: Conformational Flexibility of the Lamellar [Sn 3 Se 7 2- ] n Anion: Selenidostannate Salts of Transition Metal Complex Cations". Zeitschrift für anorganische und allgemeine Chemie. 641 (3–4): 561–567. doi:10.1002/zaac.201400289.
  51. ^ a b c d Sun, Peipei; Liu, Shuzhen; Han, Jingyu; Shen, Yali; Sun, Hui; Jia, Dingxian (August 2017). "Solvothermal syntheses, crystal structures, and optical and thermal properties of transition metal selenidostannates". Transition Metal Chemistry. 42 (5): 387–393. doi:10.1007/s11243-017-0141-0. ISSN 0340-4285. S2CID 99708088.
  52. ^ a b c d e f g h Han, Jingyu; Zhang, Limei; Li, Shufen; Zheng, Wei; Jia, Dingxian; Yuan, Yaxian (2019). "Alcohol-solvothermal syntheses, crystal structures and photocatalytic properties of tin selenides with polyselenide ligands". CrystEngComm. 21 (10): 1642–1652. doi:10.1039/C8CE02065E. ISSN 1466-8033. S2CID 104463228.
  53. ^ a b c d e Luo, Hai-Ying; Zhou, Jian (2018). "A series of new hybrid selenidostannates with metal complexes prepared in alkylol amines". Dalton Transactions. 47 (41): 14751–14759. doi:10.1039/C8DT03322F. ISSN 1477-9226. PMID 30289148.
  54. ^ a b Zhou, Jian; Bian, Guo-Qing; Dai, Jie; Zhang, Yong; Tang, Ai-bin; Zhu, Qin-Yu (2007-03-01). "Synthesis of a Selenidostannate(IV), [Mn(tepa)·Sn 3 Se 7 ] n , Demonstrating the Transformation from Achiral to Chiral and Dimeric to Polymeric Structure". Inorganic Chemistry. 46 (5): 1541–1543. doi:10.1021/ic062403r. ISSN 0020-1669. PMID 17269765.
  55. ^ Zhou, Jian; Xiao, Hong; Zou, Hua-Hong; Liu, Xing (2017). "A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior". Dalton Transactions. 46 (46): 16009–16013. doi:10.1039/C7DT03331A. ISSN 1477-9226. PMID 29120468.
  56. ^ a b c d Santner, Silke; Dehnen, Stefanie (2015-02-16). "[M 4 Sn 4 Se 17 ] 10– Cluster Anions (M = Mn, Zn, Cd) in a Cs + Environment and as Ternary Precursors for Ionothermal Treatment". Inorganic Chemistry. 54 (4): 1188–1190. doi:10.1021/ic5026087. ISSN 0020-1669. PMID 25622069.
  57. ^ a b Baiyin, Menghe; Naren, Jiruga; Gang, Gang; Wang, Xiaojing; Xu, Xiaoqing (September 2013). "Two new quaternary selenostannates synthesized under solvothermal conditions: Crystal structure and reflectance spectra of (1,4-dabH)2MnSnSe4 and (1,4-dabH2) Cu2SnSe4". Inorganic Chemistry Communications. 35: 135–139. doi:10.1016/j.inoche.2013.06.001.
  58. ^ a b c Li, Shufen; Wei, Zheng; Chen, Niannian; Gao, Yan; Jia, Dingxian (2019-12-17). "Hydrothermal syntheses, crystal structures, and optical properties of transition metal selenidostannates". Journal of Coordination Chemistry. 72 (22–24): 3562–3574. doi:10.1080/00958972.2019.1705286. ISSN 0095-8972. S2CID 212808596.
  59. ^ a b c Kromm, Anna; Sheldrick, William S. (June 2008). "Synthesis and Structures of Dimanganese(II) Complexes with Spirotricyclic [Mn(μ-Ge 2 Se 7 )Mn] and [Mn(μ-Sn 2 Se 6 )Mn] Cores". Zeitschrift für anorganische und allgemeine Chemie. 634 (6–7): 1005–1010. doi:10.1002/zaac.200700551. ISSN 0044-2313.
  60. ^ a b Haddadpour, Sima; Melullis, Maike; Staesche, Halgard; Mariappan, C. R.; Roling, Bernhard; Clérac, Rodolphe; Dehnen, Stefanie (2009-02-16). "Inorganic Frameworks from Selenidotetrelate Anions [T 2 Se 6 ] 4− (T = Ge, Sn): Synthesis, Structures, and Ionic Conductivity of [K 2 (H 2 O) 3 ][MnGe 4 Se 10 ] and (NMe 4 ) 2 [MSn 4 Se 10 ] (M = Mn, Fe)". Inorganic Chemistry. 48 (4): 1689–1698. doi:10.1021/ic802170f. ISSN 0020-1669. PMID 19159241.
  61. ^ Kaib, Thomas; Haddadpour, Sima; Andersen, Hanne Flåten; Mayrhofer, Leonhard; Järvi, Tommi T.; Moseler, Michael; Möller, Kai-Christian; Dehnen, Stefanie (2013-12-10). "Quaternary Diamond-Like Chalcogenidometalate Networks as Efficient Anode Material in Lithium-Ion Batteries". Advanced Functional Materials. 23 (46): 5693–5699. doi:10.1002/adfm.201301025. S2CID 93236286.
  62. ^ a b c Xiong, Wei-Wei; Li, Pei-Zhou; Zhou, Tian-Hua; Zhao, Yanli; Xu, Rong; Zhang, Qichun (August 2013). "Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M1/2Sn1/2Se2] (M=Mn, Zn, Hg)". Journal of Solid State Chemistry. 204: 86–90. doi:10.1016/j.jssc.2013.05.023.
  63. ^ a b Tang, Chunying; Wang, Fang; Lu, Jialin; Jia, Dingxian; Jiang, Wenqing; Zhang, Yong (2014-09-02). "Novel One-, Two-, and Three-Dimensional Selenidostannates Templated by Iron(II) Complex Cation". Inorganic Chemistry. 53 (17): 9267–9273. doi:10.1021/ic501381v. ISSN 0020-1669. PMID 25119287.
  64. ^ Zimmermann, Christian; Anson, Christopher E.; Dehnen, Stefanie (2007-09-04). "Chalcogenido-Bridged Clusters by Reactions of Chalcogenostannate Salts". Journal of Cluster Science. 18 (3): 618–629. doi:10.1007/s10876-007-0130-0. ISSN 1040-7278. S2CID 95226865.
  65. ^ a b c Tian, Xinyu; Teri, Gele; Shele, Muge; E, Namila; Qi, Liming; Liu, Min; Baiyin, Menghe (May 2022). "Five new TM-Sn-Q (TM = transition metals;Q = S,Se) photoelectrocatalytic materials". Polyhedron. 217: 115729. doi:10.1016/j.poly.2022.115729. S2CID 246929971.
  66. ^ Ren, Hai-Yun; Ning, Zhi-Xue; Hou, Juan-Juan (2014-03-19). "Ultrasound and solvent-induced reversible chromism in a luminescent chalcogenidostannate". Journal of Coordination Chemistry. 67 (6): 1079–1087. doi:10.1080/00958972.2014.901505. ISSN 0095-8972. S2CID 95732554.
  67. ^ a b Liang, Jingjing; Chen, Jiangfang; Zhao, Jing; Pan, Yingli; Zhang, Yong; Jia, Dingxian (March 2011). "Solvothermal Syntheses, Crystal Structures, and Thermal Properties of the First Example of Selenidostannates with Mixed Ethylene Polyamine-Coordinated Transition Metal Complexes as Counterions". Zeitschrift für anorganische und allgemeine Chemie. 637 (3–4): 445–449. doi:10.1002/zaac.201000336.
  68. ^ Tan, Hong-Hui; Liu, Xing; Huang, Chun-Mei; Zhou, Jian (2023-07-17). "One-Dimensional Selenidostannates Based on an Infrequent Tetrameric Cluster [Sn 4 Se 12 ] Exhibiting Electro-Catalytic Properties". Inorganic Chemistry. 62 (28): 11240–11247. doi:10.1021/acs.inorgchem.3c01538. ISSN 0020-1669. PMID 37390501. S2CID 259303457.
  69. ^ Zhang, Bo; Li, Lian-Zhi; Li, Jun; Zhang, Yue-Chan; Liu, Shu-Hua; Deng, Yan-Li; Huang, Xiao-Ying (August 2019). "[Ni(phen)3]Sn3Se7·1.5H2O: A new two-dimensional layered selenidostannate templated by [Ni(phen)3]2+ complexes". Inorganic Chemistry Communications. 106: 76–80. doi:10.1016/j.inoche.2019.05.035. S2CID 191160741.
  70. ^ a b c d Du, Cheng-Feng; Shen, Nan-Nan; Li, Jian-Rong; Hao, Min-Ting; Wang, Zi; Huang, Xiao-Ying (2016-05-20). "Synthesizing 2D and 3D Selenidostannates in Ionic Liquids: The Synergistic Structure-Directing Effects of Ionic Liquids and Metal-Amine Complexes". Chemistry: An Asian Journal. 11 (10): 1555–1564. doi:10.1002/asia.201600073. PMID 27037731.
  71. ^ a b Du, Cheng-Feng; Shen, Nan-Nan; Li, Jian-Rong; Hao, Min-Ting; Wang, Zi; Cheng, Chu-Chu; Huang, Xiao-Ying (2016). "Two novel selenidostannates from mixed structure-directing systems: the large ten-membered ring of [Sn 3 Se 4 ] semicubes and the 3D [Sn 4 Se 9 ] n 2n− with multi-channels". Dalton Transactions. 45 (23): 9523–9528. doi:10.1039/C6DT01482H. ISSN 1477-9226. PMID 27193871.
  72. ^ Jia, Guo-Xin; Jiang, Qi-Qi; Baiyin, Menghe; Teri, Gele (2022-09-28). Solvothermal synthesis, crystal structure and properties of selenidostannate containing zero-dimensional cluster structure (Report). In Review. doi:10.21203/rs.3.rs-2091815/v1.
  73. ^ a b c d e f Hilbert, Jessica; Näther, Christian; Bensch, Wolfgang (2017-09-06). "Applying Ni(II) Amine Complexes and Sodium Thiostannate as Educts for the Generation of Thiostannates at Room Temperature". Crystal Growth & Design. 17 (9): 4766–4775. doi:10.1021/acs.cgd.7b00728. ISSN 1528-7483.
  74. ^ a b Benkada, Assma; Näther, Christian; Bensch, Wolfgang (2020-08-31). "Room Temperature Synthesis of New Thiostannates by Slow Interdiffusion of Different Solvents". Zeitschrift für anorganische und allgemeine Chemie. 646 (16): 1352–1358. doi:10.1002/zaac.202000199. ISSN 0044-2313. S2CID 225776922.
  75. ^ a b c Zheng, Li-Xian; Hu, Jian-Feng; Luo, Jun (2020). "Thermoelectric properties of Cu-doped Cu<sub>2</sub>SnSe<sub>4</sub> compounds". Acta Physica Sinica. 69 (24): 247102. doi:10.7498/aps.69.20200861. ISSN 1000-3290.
  76. ^ Teri, Gele; Li, Na; Bai, Sagala; E., Namila; Baiyin, Menghe (2021). "Synthesis, crystal structure, photocatalysis, photocurrent response: one-dimensional K 2 HgSnSe 4 and three-dimensional Na 6 Cu 8 Sn 3 Se 13". CrystEngComm. 23 (35): 6079–6085. doi:10.1039/D1CE00821H. ISSN 1466-8033. S2CID 237735630.
  77. ^ Zhang, Yingying; Hu, Dandan; Yang, Huajun; Lin, Jian; Wu, Tao (July 2017). "Synthesis, crystal structure, near-IR photoelectric response of two 1-D selenides: [Cu 2 MSe 5 ]·[Mn(H + -en) 2 (en)] (M=Ge, Sn)". Journal of Solid State Chemistry. 251: 61–64. doi:10.1016/j.jssc.2017.04.006.
  78. ^ a b Liao, Ju Hsiou; Kanatzidis, Mercouri G. (1993-10-01). "Quaternary rubidium copper tin sulfides (Rb2Cu2SnS4, A2Cu2Sn2S6 (A = Na, K, Rb, Cs), A2Cu2Sn2Se6 (A = K, Rb), potassium gold tin sulfides, K2Au2SnS4, and K2Au2Sn2S6. Syntheses, structures, and properties of new solid-state chalcogenides based on tetrahedral [SnS4]4- units". Chemistry of Materials. 5 (10): 1561–1569. doi:10.1021/cm00034a029. ISSN 0897-4756.
  79. ^ a b Sun, Pei-pei; Liu, Shu-zhen; Shen, Ya-li; Tang, Chun-ying; Han, Jing-yu; Liu, Yun; Jiang, Wen-qing; Jia, Ding-xian (October 2017). "Solvothermal Syntheses, Crystal Structures and Optical Properties of New Members of Transition Metal Complexes Based on Hexaselenidobistannate Ligand". Journal of Chemical Crystallography. 47 (5): 133–139. doi:10.1007/s10870-017-0689-8. ISSN 1074-1542. S2CID 104123444.
  80. ^ a b c Zhang, Bo; Feng, Mei-Ling; Li, Jun; Hu, Qian-Qian; Qi, Xing-Hui; Huang, Xiao-Ying (2017-03-01). "Syntheses, Crystal Structures, and Optical and Photocatalytic Properties of Four Small-Amine-Molecule-Directed M–Sn–Q (M = Zn, Ag; Q = S, Se) Compounds". Crystal Growth & Design. 17 (3): 1235–1244. doi:10.1021/acs.cgd.6b01619. ISSN 1528-7483.
  81. ^ Tsamourtzi, Konstantina; Song, Jung-Hwan; Bakas, Thomas; Freeman, Arthur J.; Trikalitis, Pantelis N.; Kanatzidis, Mercouri G. (2008-12-15). "Straightforward Route to the Adamantane Clusters [Sn 4 Q 10 ] 4− (Q = S, Se, Te) and Use in the Assembly of Open-Framework Chalcogenides (Me 4 N) 2 M[Sn 4 Se 10 ] (M = Mn II , Fe II , Co II , Zn II ) Including the First Telluride Member (Me 4 N) 2 Mn[Ge 4 Te 10 ]". Inorganic Chemistry. 47 (24): 11920–11929. doi:10.1021/ic801762h. ISSN 0020-1669. PMID 18998670.
  82. ^ Zhou, Molin; Jiang, Xingxing; Yang, Yi; Guo, Yangwu; Lin, Zheshuai; Yao, JJiyong; Wu, Yicheng (2017-06-19). "K 2 ZnSn 3 Se 8 : A Non-Centrosymmetric Zinc Selenidostannate(IV) Featuring Interesting Covalently Bonded [ZnSn 3 Se 8 ] 2− Layer and Exhibiting Intriguing Second Harmonic Generation Activity". Chemistry: An Asian Journal. 12 (12): 1282–1285. doi:10.1002/asia.201700426. PMID 28436178.
  83. ^ Wang, Jingrui; Li, Peng; Cai, Ting; Yang, Dan-Dan; Xiong, Wei-Wei (July 2018). "Four two-dimensional ternary selenides based on group 13 and 14 metals: Syntheses, crystal structures, and electrochemical properties". Journal of Solid State Chemistry. 263: 88–93. Bibcode:2018JSSCh.263...88W. doi:10.1016/j.jssc.2018.04.018. S2CID 103292702.
  84. ^ a b Yu, Ji-Ming; Yu, Ji-Peng; Wang, Ning; Xiao, Lu-Lu; Wang, Huan; Xu, Qi; Zheng, Bing; Cheng, Fang-Fang; Xiong, Wei-Wei (2021-04-05). "Two Series of Main-Group Heterometallic Selenides Synthesized in Two Different Types of Ionic Liquids". Inorganic Chemistry. 60 (7): 4337–4341. doi:10.1021/acs.inorgchem.0c03630. ISSN 0020-1669. PMID 33749258. S2CID 232311478.
  85. ^ a b Hwang, Seong-Ju; Iyer, Ratnasabapathy G.; Kanatzidis, Mercouri G. (October 2004). "Quaternary selenostannates Na2−xGa2−xSn1+xSe6 and AGaSnSe4 (A=K, Rb, and Cs) through rapid cooling of melts. Kinetics versus thermodynamics in the polymorphism of AGaSnSe4". Journal of Solid State Chemistry. 177 (10): 3640–3649. doi:10.1016/j.jssc.2004.06.019.
  86. ^ a b c d e Friedrich, Daniel; Byun, Hye Ryung; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Jang, Joon Ik; Kanatzidis, Mercouri G. (2020-10-14). "Layered and Cubic Semiconductors A Ga M ′ Q 4 ( A + = K + , Rb + , Cs + , Tl + ; M ′ 4+ = Ge 4+ , Sn 4+ ; Q 2– = S 2– , Se 2– ) and High Third-Harmonic Generation". Journal of the American Chemical Society. 142 (41): 17730–17742. doi:10.1021/jacs.0c08638. ISSN 0002-7863. PMID 32933252. S2CID 221748402.
  87. ^ Xu, Guohai; Guo, Peng; Song, Shuyan; Zhang, Hongjie; Wang, Cheng (2009-06-01). "Molecular Nanocluster with a [Sn 4 Ga 4 Zn 2 Se 20 ] 8− T3 Supertetrahedral Core". Inorganic Chemistry. 48 (11): 4628–4630. doi:10.1021/ic900376h. ISSN 0020-1669. PMID 19466797.
  88. ^ Schmidtke, Markus; Krautscheid, Harald (July 2006). "[Sn 6 Se 10 Br 6 ] 2− – Ein Zinnselenidcluster mit trigonal prismatischer Struktur". Zeitschrift für anorganische und allgemeine Chemie. 632 (8–9): 1399–1401. doi:10.1002/zaac.200600067. ISSN 0044-2313.
  89. ^ Sheldrick, W. S.; Braunbeck, H.-G. (1992-01-01). "Darstellung und Kristallstruktur von Rb 2 Sn 2 Se 5 , ein Rubidium- Selenostannat(IV) mit Raumnetzstruktur/Preparation and Crystal Structure of Rb 2 Sn 2 Se 5 , a Rubidium Selenostannate(IV) with Framework Structure". Zeitschrift für Naturforschung B. 47 (1): 151–153. doi:10.1515/znb-1992-0127. ISSN 1865-7117.
  90. ^ a b c Loose, Anja; Sheldrick, William S. (1998-03-01). "Solventothermal Synthesis of the Lamellar Selenidostannates(IV) A 2 Sn 4 Se 9 · H 2 O (A = Rb, Cs) and Cs 2 Sn 2 Se 6". Zeitschrift für Naturforschung B. 53 (3): 349–354. doi:10.1515/znb-1998-0313. ISSN 1865-7117. S2CID 93566497.
  91. ^ a b Hu, Xiao-Ning; Xiong, Lin; Wu, Li-Ming (2018-05-02). "Six New Members of the A 2 M II M IV 3 Q 8 Family and Their Structural Relationship". Crystal Growth & Design. 18 (5): 3124–3131. doi:10.1021/acs.cgd.8b00247. ISSN 1528-7483.
  92. ^ a b Teri, Gele; Liu, Xin; Li, Na; Shele, Muge; E, Namila; Qi, Liming; Bai, Sagala; Baiyin, Menghe (2023-01-10). "Strong Photoelectric Properties of Mn-Based Seleniumstannates with Alkali Metals as Structure-Directing Agents". European Journal of Inorganic Chemistry. 26 (2). doi:10.1002/ejic.202200607. ISSN 1434-1948.
  93. ^ a b Li, Yanhua; Cao, Xiaoyu; Ji, Min; You, Zhonglu; An, Yonglin (May 2022). "Solvothermal syntheses, characterizations and photocatalytic properties of two copper-rich thiostannates". Inorganic Chemistry Communications. 139: 109323. doi:10.1016/j.inoche.2022.109323. S2CID 246993618.
  94. ^ Pang, Xin; Wang, Ruiqi; Che, Xiangli; Huang, Fuqiang (May 2021). "SrZnSnSe4: Synthesis, crystal structure and nonlinear optical properties". Journal of Solid State Chemistry. 297: 122092. doi:10.1016/j.jssc.2021.122092. S2CID 233906609.
  95. ^ a b c d e f g h i Zhou, Jian; Xiao, Hong; Xiao, Hong-Ping; Yang, Tao; Zou, Hua-Hong; Liu, Xing; Zhao, Rong-Qing; Tang, Qiuling (2015). "Two types of lanthanide selenidostannates( iv ) first prepared under the same solvothermal conditions". Dalton Transactions. 44 (3): 1350–1357. doi:10.1039/C4DT03099K. ISSN 1477-9226. PMID 25421214.
  96. ^ Zhang, Tao; Hu, Yue-Qiao; Li, Qian-Wen; Chen, Wei-Peng; Zheng, Yan-Zhen (2021). "Coupling an organic photosensitizer and an inorganic framework into a single-phase material that shows visible-light photocurrent response". CrystEngComm. 23 (9): 1881–1884. doi:10.1039/D0CE01685C. ISSN 1466-8033. S2CID 234005527.
  97. ^ Du, Ke-Zhao; Qi, Xing-Hui; Feng, Mei-Ling; Li, Jian-Rong; Wang, Xing-Zhi; Du, Cheng-Feng; Zou, Guo-Dong; Wang, Meng; Huang, Xiao-Ying (2016-06-06). "Synthesis, Structure, Band Gap, and Near-Infrared Photosensitivity of a New Chalcogenide Crystal, (NH 4 ) 4 Ag 12 Sn 7 Se 22". Inorganic Chemistry. 55 (11): 5110–5112. doi:10.1021/acs.inorgchem.6b00803. ISSN 0020-1669. PMID 27228165.
  98. ^ Li, Jian-Rong; Huang, Xiao-Ying (2011). "[(Me)2NH2]0.75[Ag1.25SnSe3]: A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange". Dalton Transactions. 40 (17): 4387–4390. doi:10.1039/c0dt01381a. ISSN 1477-9226. PMID 21225068.
  99. ^ Ding, Dong; Cheng, Lin; Wang, Kai-Yao; Liu, Hua-Wei; Sun, Meng; Wang, Cheng (2020-07-20). "Efficient Cs + –Sr 2+ Separation over a Microporous Silver Selenidostannate Synthesized in Deep Eutectic Solvent". Inorganic Chemistry. 59 (14): 9638–9647. doi:10.1021/acs.inorgchem.0c00770. ISSN 0020-1669. PMID 32479064. S2CID 219170148.
  100. ^ Tian, Yiming; Zhang, Jiahua; Wang, Wenbao; Jia, Dingxian (September 2021). "Ternary 3D framework [Ag5Sn4Se12]3−: Solvothermal synthesis, crystal structure and photoelectric properties of an organic silver-rich selenidostannate hybrid". Inorganic Chemistry Communications. 131: 108799. doi:10.1016/j.inoche.2021.108799.
  101. ^ a b Xiong, Wei-Wei; Miao, Jianwei; Li, Pei-Zhou; Zhao, Yanli; Liu, Bin; Zhang, Qichun (October 2014). "{[M(NH3)6][Ag4M4Sn3Se13]}∞ (M=Zn, Mn): Three-dimensional chalcogenide frameworks constructed from quaternary metal selenide clusters with two different transition metals". Journal of Solid State Chemistry. 218: 146–150. doi:10.1016/j.jssc.2014.06.035.
  102. ^ Xiong, Wei-Wei; Miao, Jianwei; Li, Pei-Zhou; Zhao, Yanli; Liu, Bin; Zhang, Qichun (2014). "[enH][Cu 2 AgSnS 4 ]: a quaternary layered sulfide based on Cu–Ag–Sn–S composition". CrystEngComm. 16 (27): 5989–5992. doi:10.1039/C4CE00740A. ISSN 1466-8033.
  103. ^ Teri, Gele; Tong, Qian; Jia, Qiang-Qiang (November 2023). "Solvothermal syntheses and characterization of one-dimensional (1,4-dabH2)Cu1.72Ag0.28SnSe4 (1) and (1,4-dabH2)Cu2SnSe4 (2)". Inorganic Chemistry Communications. 157: 111413. doi:10.1016/j.inoche.2023.111413. S2CID 261675566.
  104. ^ Guo, Yangwu; Li, Xiaoshuang; Feng, Kai; Li, Chao; Zhou, Molin; Wu, Yicheng; Yao, Jiyong (2018-04-04). "Li 7 Cd 4.5 Ge 4 Se 16 and Li 6.4 Cd 4.8 Sn 4 Se 16 : Strong Nonlinear Optical Response in Quaternary Diamond-Like Selenide Networks". Chemistry: An Asian Journal. 13 (7): 871–876. doi:10.1002/asia.201800090. PMID 29392886.
  105. ^ a b Xiong, Wei-Wei; Ye, Kaiqi; Ye, Ling; Zhang, Qichun (September 2013). "Syntheses, crystal structures, and properties of two new one-dimensional heterometallic selenides: [DBNH]4[M3Sn4Se11(Se2)2] (M=Cd, Hg)". Inorganic Chemistry Communications. 35: 337–341. doi:10.1016/j.inoche.2013.07.015.
  106. ^ Qi, F.-Y.; Baiyin, M.-H. "硒代锡酸盐Cd(tren)SnSe3的溶剂热合成与晶体结构" [Solvothermal Synthesis and Crystal Structure of Selenidostannate Cd(tren)SnSe3]. Rengong Jingti Xuebao/Journal of Synthetic Crystals. 46 (12): 2422–2426 – via Scopus.
  107. ^ Sun, Baohua; He, Jianqiao; Song, Changsheng; Wang, Dong; Bu, Kejun; Yin, Guoheng; Zhang, Xian; Huang, Fuqiang (2017-07-11). "An Intermediate Band Material K 2 CdSnSe 4 and Its Visible-Light Photocatalytic Activity". ChemistrySelect. 2 (20): 5655–5659. doi:10.1002/slct.201700731.
  108. ^ a b Wu, Jing; Pu, Ya-Yang; Zhao, Xiao-Wei; Qian, Li-Wen; Bian, Guo-Qing; Zhu, Qin-Yu; Dai, Jie (2015). "Photo-electroactive ternary chalcogenido-indate-stannates with a unique 2-D porous structure". Dalton Transactions. 44 (10): 4520–4525. doi:10.1039/C4DT03333G. ISSN 1477-9226. PMID 25653182.
  109. ^ a b c Friedrich, Daniel; Hao, Shiqiang; Patel, Shane; Wolverton, Chris; Kanatzidis, Mercouri G. (2021-08-24). "Vast Structural and Polymorphic Varieties of Semiconductors AMM′Q 4 (A = K, Rb, Cs, Tl; M = Ga, In; M′ = Ge, Sn; Q = S, Se)". Chemistry of Materials. 33 (16): 6572–6583. doi:10.1021/acs.chemmater.1c02211. ISSN 0897-4756. S2CID 238682020.
  110. ^ Wang, Yingqi; Wang, Ruiqi; Liu, Qinglong; Lai, Xiaofang; Zhang, Xian; Chen, Haijie; Zheng, Chong; Lin, Jianhua; Huang, Fuqiang (2016). "Solvothermal synthesis, structure and physical properties of Cs[Cr(en) 2 MSe 4 ] (M = Ge, Sn) with [MSe 4 ] 4− tetrahedra as chelating ligand". Dalton Transactions. 45 (22): 9097–9102. doi:10.1039/C6DT00233A. ISSN 1477-9226. PMID 27164409.
  111. ^ a b c d Morris, Collin D.; Li, Hao; Jin, Hosub; Malliakas, Christos D.; Peters, John A.; Trikalitis, Pantelis N.; Freeman, Arthur J.; Wessels, Bruce W.; Kanatzidis, Mercouri G. (2013-08-27). "Cs 2 M II M IV 3 Q 8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps". Chemistry of Materials. 25 (16): 3344–3356. doi:10.1021/cm401817r. ISSN 0897-4756.
  112. ^ a b Wu, Kui; Su, Xin; Yang, Zhihua; Pan, Shilie (2015). "An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 6". Dalton Transactions. 44 (46): 19856–19864. doi:10.1039/C5DT03215F. ISSN 1477-9226. PMID 26509847.
  113. ^ a b Zelinska, Mariya; Assoud, Abdeljalil; Graf, Christian; Kleinke, Holger (2010-02-01). "Reversible Reconstructive Phase Transition of Ba 2 SnSe 5 : A New High Temperature Modification with Completely Different Structural Motifs". Inorganic Chemistry. 49 (3): 1090–1093. doi:10.1021/ic901989j. ISSN 0020-1669. PMID 20038157.
  114. ^ Graf, Christian; Assoud, Abdeljalil; Zelinska, Mariya; Kleinke, Holger (September 2010). "The metastable m -Ba 2 SnSe 5 – Synthesis, Phase Transition, Crystal Structure, Structural Relations and Electronic Structure". Zeitschrift für anorganische und allgemeine Chemie. 636 (9–10): 1821–1826. doi:10.1002/zaac.201000058. ISSN 0044-2313.
  115. ^ Feng, Kai; Jiang, Xingxing; Kang, Lei; Yin, Wenlong; Hao, Wenyu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng; Chen, Chuangtian (2013). "Ba6Sn6Se13: a new mixed valence selenostannate with NLO property". Dalton Transactions. 42 (37): 13635–13641. doi:10.1039/c3dt51317c. ISSN 1477-9226. PMID 23900234.
  116. ^ a b Abudurusuli, Ailijiang; Wu, Kui; Pan, Shilie (2018). "Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation". New Journal of Chemistry. 42 (5): 3350–3355. doi:10.1039/C7NJ04288D. ISSN 1144-0546.
  117. ^ Li, Ya-Nan; Chen, Zi-Xia; Yao, Wen-Dong; Tang, Ru-Ling; Guo, Sheng-Ping (2021). "Heterovalent cations substitution to design asymmetric chalcogenides with promising nonlinear optical performances". Journal of Materials Chemistry C. 9 (27): 8659–8665. doi:10.1039/D1TC01806J. ISSN 2050-7526. S2CID 236246609.
  118. ^ Li, Xiaoshuang; Li, Chao; Gong, Pifu; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2015). "BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response". Journal of Materials Chemistry C. 3 (42): 10998–11004. doi:10.1039/C5TC02337H. ISSN 2050-7526.
  119. ^ Azam, Sikander; Khan, Saleem Ayaz; Goumri-Said, Souraya (September 2015). "Exploring the electronic structure and optical properties of the quaternary selenide compound, Ba4Ga4SnSe12: For photovoltaic applications". Journal of Solid State Chemistry. 229: 260–265. Bibcode:2015JSSCh.229..260A. doi:10.1016/j.jssc.2015.06.015.
  120. ^ Nian, Leyan; Wu, Kui; He, Guijie; Yang, Zhihua; Pan, Shilie (2018-03-19). "Effect of Element Substitution on Structural Transformation and Optical Performances in I 2 BaM IV Q 4 ( I = Li, Na, Cu, and Ag; M IV = Si, Ge, and Sn; Q = S and Se)". Inorganic Chemistry. 57 (6): 3434–3442. doi:10.1021/acs.inorgchem.8b00220. ISSN 0020-1669. PMID 29509412.
  121. ^ a b c Tang, Weiwei; Chen, Ruihong; Jiang, Wenqing; Zhang, Yong; Jia, Dingxian (October 2012). "The First Tetradentate μ-1κ 2 :2κ 2 -Sn 2 Se 6 Ligand to a Lanthanide(III) Center: Solvothermal Syntheses and Characterizations of Lanthanide Selenidostannate Polymers with Tetraethylenepentamine as a Second Ligand". European Journal of Inorganic Chemistry. 2012 (30): 4907–4913. doi:10.1002/ejic.201200649. ISSN 1434-1948.
  122. ^ a b c d Liu, Shuzhen; Sun, Peipei; Shen, Yali; Han, Jingyu; Sun, Hui; Jia, Dingxian (2017-04-01). "Lanthanide(III) complexes with μ-SnSe 4 and μ-Sn 2 Se 6 linkers: solvothermal syntheses and properties of new Ln(III) selenidostannates decorated with linear polyamine". Zeitschrift für Naturforschung B. 72 (4): 231–240. doi:10.1515/znb-2016-0236. ISSN 1865-7117. S2CID 199060493.
  123. ^ a b Chen, Jiang-Fang; Jin, Qin-Yan; Pan, Ying-Li; Zhang, Yong; Jia, Ding-Xian (2009). "An unprecedented μ4-Sn2Se9 ligand: solvothermal syntheses and characterizations of novel lanthanum selenidostannates [{La(dien)2}4(μ4-Sn2Se9)(μ-Sn2Se6)]∞ and [La2(en)8(μ-Se2)]Sn2Se6". Chemical Communications (46): 7212–7214. doi:10.1039/b914603b. ISSN 1359-7345.
  124. ^ a b c d e Tang, Chunying; Wang, Fang; Chen, Ruihong; Jiang, Wenqing; Zhang, Yong; Jia, Dingxian (August 2013). "Complexation of Sn2Se6 with lanthanide(III) centers influenced by ethylene polyamines: Solvothermal syntheses, crystal structures, and optical properties of lanthanide selenidostannates". Journal of Solid State Chemistry. 204: 70–77. Bibcode:2013JSSCh.204...70T. doi:10.1016/j.jssc.2013.05.008.
  125. ^ a b c d e f g Liang, Jingjing; Chen, Jiangfang; Zhao, Jing; Pan, Yingli; Zhang, Yong; Jia, Dingxian (2011). "Effects of lanthanide metal size and amino ligand denticity on the solvothermal systems Ln/Sn/Se/en and Ln/Sn/Se/dien (Ln = lanthanide)". Dalton Transactions. 40 (11): 2631–2637. doi:10.1039/c0dt01424a. ISSN 1477-9226. PMID 21293819.
  126. ^ Feng, Kai; Zhang, Xu; Yin, Wenlong; Shi, Youguo; Yao, Jiyong; Wu, Yicheng (2014-02-17). "New Quaternary Rare-Earth Chalcogenides Ba Ln Sn 2 Q 6 ( Ln = Ce, Pr, Nd, Q = S; Ln = Ce, Q = Se): Synthesis, Structure, and Magnetic Properties". Inorganic Chemistry. 53 (4): 2248–2253. doi:10.1021/ic402934m. ISSN 0020-1669. PMID 24498849.
  127. ^ a b c Tang, Chunying; Liu, Yun; Wang, Fang; Lu, Jialin; Shen, Yali; Zhang, Yong; Jia, Dingxian (April 2015). "Solvothermal syntheses and characterizations of the first example of lanthanide selenidostannates prepared in mixed ethylene polyamines". Inorganica Chimica Acta. 429: 67–72. doi:10.1016/j.ica.2014.12.038.
  128. ^ a b c Zhu, Ai-Mei; Jin, Qin-Yan; Jia, Ding-Xian; Gu, Jian-Sheng; Zhang, Yong (October 2008). "The First Example of the Tetraselenidostannate Anion [SnSe 4 ] 4– as a Chelating Ligand to a Lanthanide Complex Ion: Solvothermal Synthesis and Characterization of Lanthanoid Selenidostannates [Hdien][Ln(dien) 2 (μ-SnSe 4 )] (Ln = Sm, Eu) and [Eu 2 (dien) 4 (μ-OH) 2 ]Sn 2 Se 6". European Journal of Inorganic Chemistry. 2008 (30): 4756–4761. doi:10.1002/ejic.200800577. ISSN 1434-1948.
  129. ^ Evenson IV, Carl R.; Dorhout, Peter K. (September 2001). "Synthesis, Structural, and Optical Characterization of a New Europium(II) Tin Selenide, Eu8(Sn4Se14)(Se3)2 with a (Sn4Se14)12– Building Block". Zeitschrift für anorganische und allgemeine Chemie. 627 (9): 2178. doi:10.1002/1521-3749(200109)627:9<2178::AID-ZAAC2178>3.0.CO;2-S.
  130. ^ Chen, Rui-hong; Wang, Fang; Tang, Chun-ying; Zhang, Yong; Jia, Ding-xian (June 2013). "Solvothermal Syntheses and Crystal Structures of Hexachalcogenidodistannates with Europium Complexes of Different Ethylene Polyamine Ligands". Journal of Chemical Crystallography. 43 (6): 319–324. doi:10.1007/s10870-013-0423-0. ISSN 1074-1542. S2CID 97917911.
  131. ^ a b c d Xiao, Hong; Liu, Xing; Zhou, Jian; Wang, Miaohui; Wang, Peng; Zhang, Xiaoyan (July 2016). "Solvothermal Syntheses and Characterization of a Series of New Selenidostannates with Lanthanide Complexes as Counterions". Journal of Cluster Science. 27 (4): 1475–1484. doi:10.1007/s10876-016-1013-z. ISSN 1040-7278. S2CID 102278560.
  132. ^ "Solvothermal Synthesis,Crystal Structure and Optical Property of Lanthanide Selenidostannate [{Tb(en)_3}_2(μ-OH)_2]Sn_2Se_6 with a 3-D H-bonded Network". Chinese Journal of Structural Chemistry (12): 1869–1873. December 2010.
  133. ^ a b Jia, Ding-Xian; Zhu, Ai-Mei; Deng, Jie; Suzhou, Yong Zhang (July 2007). "Solvothermal Synthesis and Characterization of Lanthanide Chalcogenidostannates [Ln2(en)6(μ2-OH)2][Sn2S6] (Ln = Dy, Er) and [Dy2(en)6(μ2-OH)2][Sn2Se6]". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (8): 1246–1250. doi:10.1002/zaac.200700035.
  134. ^ a b c Xiao, Hong-Ping; Zhou, Jian; Wang, Xiao-Li; Zou, Hua-Hong; Zhao, Rong-Qing; Xiao, Hong (2014-07-02). "Solvothermal syntheses and characterizations of three new holmium selenidostannates( iv ): a rare example of adamantane-like [Sn 4 Se 10 ] 4− selenidostannate( iv ) with lanthanide complexes". Dalton Transactions. 43 (32): 12306–12312. doi:10.1039/C4DT00972J. ISSN 1477-9226. PMID 24986054.
  135. ^ Han, Jingyu; Liu, Yun; Lu, Jialin; Tang, Chunying; Wang, Fang; Shen, Yali; Zhang, Yong; Jia, Dingxian (August 2015). "Heterometallic sulfide cluster [Ag6Sn6S20]10−: Solvothermal syntheses and characterizations of silver thiostannates with lanthanide complex counter cations". Inorganic Chemistry Communications. 57: 18–21. doi:10.1016/j.inoche.2015.04.018.
  136. ^ a b Xiong, Wei-Wei; Li, Pei-Zhou; Zhou, Tian-Hua; Tok, Alfred Iing Yoong; Xu, Rong; Zhao, Yanli; Zhang, Qichun (2013-04-15). "Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media". Inorganic Chemistry. 52 (8): 4148–4150. doi:10.1021/ic4002169. ISSN 0020-1669. PMID 23556509.
  137. ^ Guo, Yangwu; Liang, Fei; Li, Zhuang; Xing, Wenhao; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2019-10-02). "Li 4 HgSn 2 Se 7 : The First Second-Order Nonlinear Optical-Active Selenide in the I 4 –II–IV 2 –VI 7 Diamond-like Family". Crystal Growth & Design. 19 (10): 5494–5497. doi:10.1021/acs.cgd.9b01074. ISSN 1528-7483. S2CID 203130669.
  138. ^ a b Gao, Lihua; Xu, Jingjing; Tian, Xinyu; Zhang, Bingbing; Wu, Xiaowen; Wu, Kui (2022-06-26). "AgGaSe 2 -Inspired Nonlinear Optical Materials: Tetrel Selenides of Alkali Metals and Mercury". Chemistry of Materials. 34 (13): 5991–5998. doi:10.1021/acs.chemmater.2c01011. ISSN 0897-4756. S2CID 250080020.
  139. ^ Li, Zhuang; Liu, Youquan; Zhang, Shengzi; Xing, Wenhao; Yin, Wenlong; Lin, Zheshuai; Yao, Jiyong; Wu, Yicheng (2020-06-01). "Functional Chalcogenide Na 2 HgSn 2 Se 6 and K 2 MnGe 2 Se 6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability". Inorganic Chemistry. 59 (11): 7614–7621. doi:10.1021/acs.inorgchem.0c00490. ISSN 0020-1669. PMID 32412240. S2CID 218647656.
  140. ^ Teri, Gele; Li, Na; Bai, Sagala; E., Namila; Baiyin, Menghe (2021). "Synthesis, crystal structure, photocatalysis, photocurrent response: one-dimensional K 2 HgSnSe 4 and three-dimensional Na 6 Cu 8 Sn 3 Se 13". CrystEngComm. 23 (35): 6079–6085. doi:10.1039/D1CE00821H. ISSN 1466-8033. S2CID 237735630.
  141. ^ a b Wang, Yu-Long; Feng, Mei-Ling; Wang, Kai-Yao; Li, Jian-Rong; Wang, Ze-Ping; Zou, Guo-Dong; Huang, Xiao-Ying (July 2013). "Two novel one-dimensional mercury selenidostannates with transition metal complexes: [Fe(phen)3]Hg2Sn2Se7·1.5eta·0.25H2O and [Ni2(teta)2(μ-teta)]HgSn3Se9". Inorganic Chemistry Communications. 33: 10–14. doi:10.1016/j.inoche.2013.03.033.
  142. ^ a b Guo, Yangwu; Liang, Fei; Li, Zhuang; Xing, Wenhao; Lin, Zhe-shuai; Yao, Jiyong; Mar, Arthur; Wu, Yicheng (2019-08-05). "AHgSnQ 4 (A = Sr, Ba; Q = S, Se): A Series of Hg-Based Infrared Nonlinear-Optical Materials with Strong Second-Harmonic-Generation Response and Good Phase Matchability". Inorganic Chemistry. 58 (15): 10390–10398. doi:10.1021/acs.inorgchem.9b01572. ISSN 0020-1669. PMID 31342744. S2CID 198494837.
Retrieved from "https://en.wikipedia.org/w/index.php?title=Selenidostannate&oldid=1236383232"