Preakuammicine
Appearance
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Names | |
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IUPAC name
Methyl (16α,19E)-16-(hydroxymethyl)-1,2-didehydrocur-19-en-17-oate
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Other names
methyl (11S,12E,17S)-12-ethylidene-10-(hydroxymethyl)-8,14-diazapentacyclo[9.5.2.01,9.02,7.014,17]octadeca-2,4,6,8-tetraene-10-carboxylate
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
PubChem CID
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Properties | |
C21H24N2O3 | |
Molar mass | 352.434 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preakuammicine is a terpene indole alkaloid.[2] Preakuammicine is thought to be formed from 4,21-dehydrogeissoschizine and lead to synthesis of stemmadenine. The enzymes involved in preakuammicine formation and those which use it as a substrate are currently unknown.
References
[edit]- ^ "Preakuammicine | Chemical Substance Information". J-GLOBAL.
- ^ Benayad, Sarah; Ahamada, Kadiria; Lewin, Guy; Evanno, Laurent; Poupon, Erwan (March 2016). "Preakuammicine: A Long-Awaited Missing Link in the Biosynthesis of Monoterpene Indole Alkaloids". European Journal of Organic Chemistry. 2016 (8): 1494–1499. doi:10.1002/ejoc.201600102.