Pentadentate ligand

A pentadentate ligand is a ligand that coordinates via five donor atoms.^[1]

There are different possible ways for a ligand to arrange around an ion. For an octahedral coordination with six positions, the possible arrangements of a linear pentadentate ligand are designated by ffm_s ffm_a fff fmf fm_am_a fm_sm_a fm_sm_s fm_am_s where each letter f or s represents three consecutive donor atoms: f represents facial fac arrangement, m is meridianal mer a is "anti" and s is "syn" for positioning of the mer arrangement relative to other donors.^[1]

For a chain branched at the donor atom the tertiary atom will have two chains of length one and one of length one attached. The pattern can use parenthesis: () to indicate a side chain, eg NNM(N)N. For octahedral coordination there are four arrangements designated: f(m)m f(f)f f(f)m_a and f(f)m_s where the parenthesis ow indicate how the side chain participates in coordination.^[1]

Ligands with four donor atoms on four chains around a central donor atom, will organise around the metal atom equatorially.^[1]

The metal may be five-coordinate with arrangements being square-pyramidal or trigonal-bipyramidal, or somewhere between the two.

2,2':6',2'':6'',2''':6''',2''''-Quinquepyridine is fairly rigid, and tries to be in a plane, so coordination will be pentagonal planar. For silver it is planar, but for rhenium it slightly twists to a helix.^[1]

Examples

IUPAC name	name	abbreviation	type	pKa	Metals	ref
N¹-(2-aminoethyl)-N²-(2-((2-aminoethyl)amino)ethyl)ethane-1,2-diamine	tetraethylenepentamine	tepa	NNNNN	2.65, 4.25, 7.87, 9.08 and 9.92	Mn Fe Co Ni Cu Zn
N1-(2-(dimethylamino)ethyl)-N2-(2-((2-(dimethylamino)ethyl)(methyl)amino)ethyl)-N1,N2-dimethylethane-1,2-diamine		Me7-tetren	NNNNN		Co(II), Ni(II), Cu(I), Cu(II) and Zn(II)

References

^ ^a ^b ^c ^d ^e Blackman, Allan G. (March 2019). "The coordination chemistry of acyclic pentadentate pentaamine ligands". Polyhedron. 161: 1–33. doi:10.1016/j.poly.2018.12.004.

[black-1] Blackman, Allan G. (March 2019). "The coordination chemistry of acyclic pentadentate pentaamine ligands". Polyhedron. 161: 1–33. doi:10.1016/j.poly.2018.12.004.

[1]