Methanetellurol

Methanetellurol
Identifiers
CAS Number	25284-83-7;
3D model (JSmol)	Interactive image;
ChemSpider	14564633;
PubChem CID	356643;
CompTox Dashboard (EPA)	DTXSID10326743 ;
	InChI InChI=1S/CH4Te/c1-2/h2H,1H3 Key: JNLXBRURJAYDTD-UHFFFAOYSA-N;
	SMILES C[TeH];
Properties
Chemical formula	CH3TeH
Molar mass	143.64 g·mol−1
Appearance	colorless gas
Related compounds
Related compounds	Methanol; Methanethiol; Methaneselenol;
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Methanetellurol is the organotellurium compound with the formula C H₃TeH. It is the simplest organotellurium compound that has been purified in bulk. It is classified as a tellurol. A colorless gas, it decomposes to Te and methane near room temperature. It is prepared by reduction of dimethyl ditelluride using Na/NH₃ followed by protonation of the CH₃Te⁻Na⁺ (sodium methanetellurolate) with sulfuric acid.^[1] Few publications describe this compound as a consequence of its instability and paucity of applications.

According to IR spectroscopy, ν_Te-H = 1995 cm⁻¹. For the lighter homologues, ν_E-H = 2342 (E = Se), 2606 (E = S), and 3710 cm⁻¹ (E = O) for methaneselenol, methanethiol, and methanol.^[1]

References

^ ^a ^b Hamada, K.; Morishita, H. (1977). "The Synthesis and the Raman and Infrared Spectra of Methanetellurol". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 7 (4): 355–366. doi:10.1080/00945717708069709.

[Hamada-1] Hamada, K.; Morishita, H. (1977). "The Synthesis and the Raman and Infrared Spectra of Methanetellurol". Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 7 (4): 355–366. doi:10.1080/00945717708069709.

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