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Isotopocule

From Wikipedia, the free encyclopedia
Example of six stable isotopocules of ethanol (i.e. with stable isotopes) out of the total number of 288 stable isotopocules

Isotopocules are isotopically substituted molecule, which differ only in their isotopic composition or their isotopes' intramolecular position.[1] It is also an umbrella term for the more specific terms "isotopologue" and "isotopomer", coined by Jan Kaiser and Thomas Röckmann in 2008.[2][3]

References

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  1. ^ Toyoda, Sakae; Yoshida, Naohiro; Koba, Keisuke (2017). "Isotopocule analysis of biologically produced nitrous oxide in various environments". Mass Spectrometry Reviews. 36 (2): 135–160. Bibcode:2017MSRv...36..135T. doi:10.1002/mas.21459. PMID 25869149.
  2. ^ Kaiser, Jan; Röckmann, Thomas (2008). "Correction of mass spectrometric isotope ratio measurements for isobaric isotopologues of O2, CO, CO2, N2O and SO2". Rapid Communications in Mass Spectrometry. 22 (24): 3997–4008. Bibcode:2008RCMS...22.3997K. doi:10.1002/rcm.3821. PMID 19016255.
  3. ^ Werner, Roland A.; Cormier, Marc-André (2022). "Isotopes—Terminology, Definitions and Properties". Stable Isotopes in Tree Rings. Cham: Springer International Publishing. pp. 253–289. doi:10.1007/978-3-030-92698-4_8. ISBN 978-3-030-92697-7. ISSN 1568-2544.