Hexafluorophosphazene
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IUPAC name
2,2,4,4,6,6-Hexafluoro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine
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Other names
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.150.019 |
EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
(NPF2)3 | |
Molar mass | 248.933 g·mol−1 |
Appearance | White powder or lumps[1] |
Melting point | 27 °C (81 °F; 300 K) |
Boiling point | 51 °C (124 °F; 324 K) |
decomposes | |
Solubility | Toluene[1] |
Structure | |
Planar P3N3 ring | |
0 D | |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards
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Corrosive |
GHS labelling: | |
Danger | |
H314 | |
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340+P310, P305+P351+P338+P310, P363, P405, P501 | |
Related compounds | |
Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Hexafluorophosphazene is an inorganic compound with the formula (NPF2)3. It takes the form of a white powder or lumps. It is sensitive to moisture and heat.[1]
Structure
[edit]The molecule has a cyclic, unsaturated P3N3 backbone consisting of alternating phosphorus and nitrogen atoms, and can be viewed as a trimer of the hypothetical compound N≡PF2 (phosphazyl difluoride). Its classification as a phosphazene highlights its relationship to benzene. Hexafluorophosphazene has a hexagonal P3N3 ring with six equivalent P–N bonds. Each phosphorus atom is additionally bonded to two fluorine atoms.[2]
The molecule possesses D3h symmetry, and each phosphorus center is tetrahedral.
The P3N3 ring in hexachlorophosphazene deviates from planarity and is slightly ruffled (see chair conformation). By contrast, the P3N3 ring in hexafluorophosphazene is completely planar.[3]
References
[edit]- ^ a b c "Hexafluorocyclotriphosphazene 15599-91-4 | TCI AMERICA". www.tcichemicals.com.
- ^ Allen, Christopher W. (1991-03-01). "Regio- and stereochemical control in substitution reactions of cyclophosphazenes". Chemical Reviews. 91 (2): 119–135. doi:10.1021/cr00002a002. ISSN 0009-2665.
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.