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Benzyne Conversion:

The use of a carbon-13 labled precursor was used to determine the mechanism of the proposed 1,2- to 1,3-didehydrobenzene conversion of the phenyl substituted aryne precursor 1 to acenaphthylene.

  • blue = unscrambled position
  • red = scrambled position
  • purple = considering both positions together/cross-over product.
  • Compound A represents the intermediate meta-benzyene which interconverts the two ortho-benzyenes (2 and 2B)
Date
Source Reference: A m-Benzyne to o-Benzyne Conversion Through a 1,2-Shift of a Phenyl Group. Blake, M. E.; Bartlett, K. L.; Jones, M. Jr. J. Am. Chem. Soc. 2003, 125, 6485. doi:10.1021/ja0213672
Author Original PNG by V8rik, coloured adaptation by Quantockgoblin
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19 March 2008

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current00:40, 19 March 2008Thumbnail for version as of 00:40, 19 March 20081,232 × 1,116 (69 KB)Quantockgoblin~commonswiki{{Information |Source=self-made == Summary == {{Information |Description= Benzyne Conversion Blake, M. E.; Bartlett, K. L.; Jones, M. Jr. J. Am. Chem. Soc. 2003, 125, 6485 |Source= |Date= |Author= Original PNG by V8rik, coloured adaptation by [[U

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