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Didier Astruc

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Didier Astruc
Astruc in 2015
Born9 June 1946
Versailles, France
Scientific career
FieldsChemistry, Dendrimers
InstitutionsUniversity Bordeaux
Doctoral advisorR. Dabard

Didier Astruc (born 9 June 1946 in Versailles) carried out his studies in chemistry in Rennes. After a Ph. D. with professor R. Dabard in organometallic chemistry, he did post-doctoral studies with professor R. R. Schrock (2005 Nobel Laureate) at the Massachusetts Institute of Technology Cambridge, Massachusetts, in the U.S. and later a sabbatical year with professor K. P. C. Vollhardt[1] at the University of California at Berkeley. He became a CNRS Director of research in Rennes, then in 1983 full Professor of Chemistry at the University Bordeaux 1. He is known for his work on electron-reservoir complexes[2] and dendritic molecular batteries,[3] catalytic processes (olefin metathesis,[4] C-C coupling,[5] catalysis in water)[6] using nanoreactors and molecular recognition using gold nanoparticles[7] and metallodendrimers.[8]

With his group, his recent and present research concerns green hydrogen production,[9][10][11] CO2 utilization for C-C bond formation including toward organic synthesis [12][13] and the use of ferrocene-containing macromolecules[14] for molecular batteries [15][16] and drug delivery.[17][18][19]

He is the author of three books, scientific publications and the editor of five books or special issues. He has been a member of the National CNRS committee from 2000 to 2008 and the President of the Coordination Chemistry Division of the Société Française de Chimie from 2000 to 2004. Didier Astruc is on the Thompson-Reuters list of the top 100 chemists who have achieved the highest citation impact scores for their chemistry papers published between 2000 and 2010,[20] and on the list of the Highest Cited Researchers 2015 and 2016 (Thomson-Reuters),[21] and 2017 to 2023 (Clarivate Analytics).[22]

Distinctions

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18-electron FeII metallodendrimer, exemplified by a G4-DAB-64-FeII complex with 64 equiv of Buckminsterfullerene C60•-.[23][24][25]

References

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  1. ^ "Faculty & Research | College of Chemistry".
  2. ^ D. Astruc, Electron Transfer and Radical Processes in Transition-Metal Chemistry, VCH, New York, 1995 (630 pp., preface by Henry Taube).
  3. ^ C. Ornelas; J. Ruiz; C. Belin; D. Astruc. (2009). "Giant Dendritic Molecular Electrochrome Batteries with Ferrocenyl and Pentamethylferrocenyl Termini". J. Am. Chem. Soc. 131 (2): 590–601. doi:10.1021/ja8062343. PMID 19113856.
  4. ^ C. Ornelas; D. Méry; E. Cloutet; J. Ruiz; D. Astruc. (2008). "Cross Olefin Metathesis for the Selective Functionalization, Ferrocenylation, and Solubilization in Water of Olefin-Terminated Dendrimers, Polymers, and Gold Nanoparticles and for a Divergent Dendrimer Construction". J. Am. Chem. Soc. 130 (4): 1495–1506. doi:10.1021/ja077392v. PMID 18177046.
  5. ^ A. K. Diallo; C. Ornelas; L. Salmon; J. Ruiz; D. Astruc (2007). ""Homeopathic" Catalytic Activity and Atom-Leaching Mechanism in Miyaura–Suzuki Reactions under Ambient Conditions with Precise Dendrimer-Stabilized Pd Nanoparticles". Angewandte Chemie International Edition. 46 (45): 8644–8648. doi:10.1002/anie.200703067. PMID 17929338.
  6. ^ Astruc, Didier (14 August 2007). Organometallic Chemistry and Catalysis. Berlin New York: Springer Science & Business Media. ISBN 978-3-540-46129-6.
  7. ^ E. Boisselier; A. K. Diallo; L. Salmon; C. Ornelas; J. Ruiz; D. Astruc. (2010). "Encapsulation and Stabilization of Gold Nanoparticles with "Click" Polyethyleneglycol Dendrimers". J. Am. Chem. Soc. 132 (8): 2729–2742. doi:10.1021/ja909133f. PMID 20131826.
  8. ^ D. Astruc; E. Boisselier; C. Ornelas (2010). "Dendrimers Designed for Functions: From Physical, Photophysical, and Supramolecular Properties to Applications in Sensing, Catalysis, Molecular Electronics, and Nanomedicine". Chem. Rev. 110 (4): 1857–1959. doi:10.1021/cr900327d. PMID 20356105.
  9. ^ Wang, Changlong; Tuninetti, Jimena; Wang, Zhao; Zhang, Chen; Ciganda, Roberto; Salmon, Lionel; Moya, Sergio; Ruiz, Jaime; Astruc, Didier (23 August 2017). "Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release". Journal of the American Chemical Society. 139 (33): 11610–11615. doi:10.1021/jacs.7b06859. hdl:11336/64286. ISSN 0002-7863. PMID 28763209.
  10. ^ Fu, Fangyu; Wang, Changlong; Wang, Qi; Martinez-Villacorta, Angel M.; Escobar, Ane; Chong, Hanbao; Wang, Xin; Moya, Sergio; Salmon, Lionel; Fouquet, Eric; Ruiz, Jaime; Astruc, Didier (8 August 2018). "Highly Selective and Sharp Volcano-type Synergistic Ni 2 Pt@ZIF-8-Catalyzed Hydrogen Evolution from Ammonia Borane Hydrolysis". Journal of the American Chemical Society. 140 (31): 10034–10042. doi:10.1021/jacs.8b06511. ISSN 0002-7863. PMID 29996053.
  11. ^ Wang, Changlong; Wang, Qi; Fu, Fangyu; Astruc, Didier (20 October 2020). "Hydrogen Generation upon Nanocatalyzed Hydrolysis of Hydrogen-Rich Boron Derivatives: Recent Developments". Accounts of Chemical Research. 53 (10): 2483–2493. doi:10.1021/acs.accounts.0c00525. ISSN 0001-4842. PMID 33034454.
  12. ^ Woldu, Abebe Reda; Huang, Zanling; Zhao, Pengxiang; Hu, Liangsheng; Astruc, Didier (1 March 2022). "Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts". Coordination Chemistry Reviews. 454: 214340. doi:10.1016/j.ccr.2021.214340. ISSN 0010-8545.
  13. ^ Fu, Wengang; Yun, Yapei; Sheng, Hongting; Liu, Xiaokang; Ding, Tao; Hu, Shuxian; Yao, Tao; Ge, Binghui; Du, Yuanxin; Astruc, Didier; Zhu, Manzhou (1 May 2024). "Design of bifunctional single-atom catalysts NiSA/ZIF-300 for CO2 conversion by ligand regulation strategy". Nano Research. 17 (5): 3827–3834. doi:10.1007/s12274-023-6334-2. ISSN 1998-0000.
  14. ^ Astruc, Didier (November 2023). "The numerous paths of ferrocene". Nature Chemistry. 15 (11): 1650. Bibcode:2023NatCh..15.1650A. doi:10.1038/s41557-023-01348-1. ISSN 1755-4349. PMID 37907604.
  15. ^ Gu, Haibin; Ciganda, Roberto; Castel, Patricia; Moya, Sergio; Hernandez, Ricardo; Ruiz, Jaime; Astruc, Didier (19 February 2018). "Tetrablock Metallopolymer Electrochromes". Angewandte Chemie International Edition. 57 (8): 2204–2208. doi:10.1002/anie.201712945. ISSN 1433-7851. PMID 29327792.
  16. ^ Beladi-Mousavi, Seyyed Mohsen; Sadaf, Shamaila; Hennecke, Ann-Kristin; Klein, Jonas; Mahmood, Arsalan Mado; Rüttiger, Christian; Gallei, Markus; Fu, Fangyu; Fouquet, Eric; Ruiz, Jaime; Astruc, Didier; Walder, Lorenz (7 June 2021). "The Metallocene Battery: Ultrafast Electron Transfer Self Exchange Rate Accompanied by a Harmonic Height Breathing". Angewandte Chemie International Edition. 60 (24): 13554–13558. doi:10.1002/anie.202100174. ISSN 1433-7851. PMC 8252062. PMID 33730408.
  17. ^ Perli, Gabriel; Wang, Qi; Braga, Carolyne B.; Bertuzzi, Diego L.; Fontana, Liniquer A.; Soares, Marco C. P.; Ruiz, Jaime; Megiatto, Jackson D.; Astruc, Didier; Ornelas, Catia (25 August 2021). "Self-Assembly of a Triazolylferrocenyl Dendrimer in Water Yields Nontraditional Intrinsic Green Fluorescent Vesosomes for Nanotheranostic Applications". Journal of the American Chemical Society. 143 (33): 12948–12954. doi:10.1021/jacs.1c05551. ISSN 0002-7863. PMID 34291930.
  18. ^ Ornelas, Catia; Astruc, Didier (August 2023). "Ferrocene-Based Drugs, Delivery Nanomaterials and Fenton Mechanism: State of the Art, Recent Developments and Prospects". Pharmaceutics. 15 (8): 2044. doi:10.3390/pharmaceutics15082044. ISSN 1999-4923. PMC 10458437. PMID 37631259.
  19. ^ Astruc, Didier (13 June 2023). "From sandwich complexes to dendrimers: journey toward applications to sensing, molecular electronics, materials science, and biomedicine". Chemical Communications. 59 (48): 7321–7345. doi:10.1039/D3CC01175E. ISSN 1364-548X. PMID 37191211.
  20. ^ sciencewatch link
  21. ^ sciencewatch link
  22. ^ "Highly Cited Researchers".
  23. ^ Didier Astruc. (2012). "Electron-transfer processes in dendrimers and their implication in biology, catalysis, sensing and nanotechnology". Nature Chemistry. 4 (4): 255–267. Bibcode:2012NatCh...4..255A. doi:10.1038/nchem.1304. PMID 22437709.
  24. ^ C. Wang; R. Ciganda; L. Salmon; D. Gregurec; J. Irigoyen; S. Moya; J. Ruiz; D. Astruc (2016). "Highly efficient transition metal nanoparticle catalysts in aqueous solutions". Angew. Chem. Int. Ed. 55 (9): 3091–3095. doi:10.1002/anie.201511305. PMID 26822288.
  25. ^ X. Liu; D. Gregurec; J. Irigoyen; A. Martinez; S. Moya; R. Ciganda; P. Hermange; J. Ruiz; D. Astruc (2016). "Precise Localization of Metal Nanoparticles in Dendrimer Nanosnakes or Inner Periphery and Consequences in Catalysis". Nat. Commun. 7: 13152. Bibcode:2016NatCo...713152L. doi:10.1038/ncomms13152. PMC 5075800. PMID 27759006.
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