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Blasticidin A

From Wikipedia, the free encyclopedia
Blasticidin A
Names
IUPAC name
1-methyl-3-[1,8,9,11,13,15,17,19,21,23,25,26,27,28,29-pentadecahydroxy-2,4,6,10,14,16-hexamethyl-30-[3,4,5,6-tetrahydroxy-6-(2-hydroxydodecyl)oxan-2-yl]triacont-2-enylidene]pyrrolidine-2,4-dione
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C58H107NO23/c1-9-10-11-12-13-14-15-16-17-35(60)27-58(81)56(79)55(78)53(76)46(82-58)26-44(69)52(75)54(77)51(74)43(68)24-38(63)22-36(61)21-37(62)23-39(64)32(5)49(72)33(6)40(65)25-41(66)34(7)50(73)42(67)20-30(3)18-29(2)19-31(4)48(71)47-45(70)28-59(8)57(47)80/h19,29-30,32-44,46,49-56,60-69,71-79,81H,9-18,20-28H2,1-8H3
    Key: VVBSMETZVCGSHB-UHFFFAOYSA-N
  • CCCCCCCCCCC(CC1(C(C(C(C(O1)CC(C(C(C(C(CC(CC(CC(CC(C(C)C(C(C)C(CC(C(C)C(C(CC(C)CC(C)/C=C(\C)/C(=C/2\C(=O)CN(C2=O)C)/O)O)O)O)O)O)O)O)O)O)O)O)O)O)O)O)O)O)O)O
Properties
C58H107NO23
Molar mass 1186.463 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Blasticidin A is an antibiotic produced by Streptomyces sp. that has antifungal and antibacterial activity. The antibiotic function and structure of blasticidin A has been observed since 1955 by Fukunaga et al. in which the blasticidin A resembles aflastatin A.[1]

References

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  1. ^ Biologically Active Natural Products: Argochemicals. Cutler G. G., Cutler S. J.; p 193-198. (1999)