Angustmycin A

Angustmycin A
Names
	IUPAC name 2-(6-aminopurin-9-yl)-2-(hydroxymethyl)-5-methylideneoxolane-3,4-diol
	Other names Decoyinine; 4′,5′-Didehydro-1′-C-(hydroxymethyl)adenosine
Identifiers
CAS Number	2004-04-8 ;
3D model (JSmol)	Interactive image;
ChEMBL	ChEMBL1444741;
ChemSpider	108484;
ECHA InfoCard	100.213.257
EC Number	687-357-1;
PubChem CID	121578;
CompTox Dashboard (EPA)	DTXSID50173859 ;
	InChI InChI=1S/C11H13N5O4/c1-5-7(18)8(19)11(2-17,20-5)16-4-15-6-9(12)13-3-14-10(6)16/h3-4,7-8,17-19H,1-2H2,(H2,12,13,14) Key: UZSSGAOAYPICBZ-UHFFFAOYSA-N;
	SMILES C=C1[C@H]([C@H]([C@](O1)(CO)N2C=NC3=C(N=CN=C32)N)O)O;
Properties
Chemical formula	C11H13N5O4
Molar mass	279.256 g·mol−1
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Angustmycin A is a purine antibiotic and metabolite from Streptomyces bacteria with the molecular formula C₁₁H₁₃N₅O₄.^[3]^[1] Angustmycin A is also a cytokinin.^[4]^[5]^[6]

References

^ ^a ^b "Angustmycin A". Pubchem.ncbi.NLM.nih.gov.
^ "Decoyinine". pubchem.ncbi.nlm.nih.gov. Retrieved 18 May 2022.
^ Scott, Thomas (20 January 2020). Concise encyclopedia of biochemistry. Walter de Gruyter GmbH & Co KG. p. 32. ISBN 978-3-11-171099-0.
^ Yu, Le; Zhou, Wenting; She, Yixuan; Ma, Hongmin; Cai, You-Sheng; Jiang, Ming; Deng, Zixin; Price, Neil P. J.; Chen, Wenqing (17 November 2021). "Efficient biosynthesis of nucleoside cytokinin angustmycin A containing an unusual sugar system". Nature Communications. 12 (1): 6633. Bibcode:2021NatCo..12.6633Y. doi:10.1038/s41467-021-26928-y. ISSN 2041-1723. PMC 8599513. PMID 34789759.
^ Gottlieb, David; Shaw, Paul D. (6 December 2012). Mechanism of Action. Springer Science & Business Media. p. 465. ISBN 978-3-642-46051-7.
^ Korzybski, Tadeusz; Kowszyk-Gindifer, Zuzanna; Kurylowicz, Wlodzimierz (3 September 2013). Antibiotics: Origin, Nature and Properties. Elsevier. ISBN 978-1-4832-2305-6.

Hoeksema, H.; Slomp, G.; van Tamelen, E. E. (1 January 1964). "Angustmycin A and decoyinine". Tetrahedron Letters. 5 (27): 1787–1795. doi:10.1016/S0040-4039(01)89489-2. ISSN 0040-4039.
McCarthy, James R.; Robins, Roland K.; Robins, Morris J. (August 1968). "Purine nucleosides. XXII. Synthesis of angustmycin A (decoyinine) and related unsaturated nucleosides". Journal of the American Chemical Society. 90 (18): 4993–4999. doi:10.1021/ja01020a038. PMID 5665542.

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