Organoyttrium chemistry

Structure of Y(CH(tms)₂)₃ (tms = SiMe₃).^[1]

Organoyttrium chemistry is the study of compounds containing carbon-yttrium bonds. These compounds are almost invariably formal Y³⁺ derivatives, are generally diamagnetic and colorless, a consequence of the closed-shell configuration of the trication.^[2] Organoyttrium compounds are mainly of academic interest.

Organoytrium compounds are often prepared by alkylation of YCl
₃.^[3]

References

^ Avent, Anthony G.; Caro, Catherine. F.; Hitchcock, Peter B.; Lappert, Michael F.; Li, Zhengning; Wei, Xue-Hong (2004). "Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium β-diketiminates". Dalton Trans (10): 1567–1577. doi:10.1039/b316695n. PMID 15252606.
^ Schumann, H.; Fedushkin, I. L. (2006). "Scandium, Yttrium & The Lanthanides: Organometallic Chemistry". Encyclopedia of Inorganic Chemistry. John Wiley & Sons. doi:10.1002/0470862106.ia212.
^ King, R. (2005). Encyclopedia of Inorganic Chemistry [10 Volumes]. Wiley. pp. 4238–4290. ISBN 9780470860786.

[1] Avent, Anthony G.; Caro, Catherine. F.; Hitchcock, Peter B.; Lappert, Michael F.; Li, Zhengning; Wei, Xue-Hong (2004). "Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium β-diketiminates". Dalton Trans (10): 1567–1577. doi:10.1039/b316695n. PMID 15252606.

[2] Schumann, H.; Fedushkin, I. L. (2006). "Scandium, Yttrium & The Lanthanides: Organometallic Chemistry". Encyclopedia of Inorganic Chemistry. John Wiley & Sons. doi:10.1002/0470862106.ia212.

[King-3] King, R. (2005). Encyclopedia of Inorganic Chemistry [10 Volumes]. Wiley. pp. 4238–4290. ISBN 9780470860786.

[1]

[2]

[3]