File:Artemisinin synthesis.svg
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Summary
| Description |
English: Biosynthesis of Artemisinin |
| Date | |
| Source | Own work |
| Author | Krishnavedala |
W3C-validity not checked.
LaTeX source code
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|---|
\documentclass[12pt,border=1pt,crop,multi=false,tikz,class=scrartcl]{standalone}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage{chemfig,chemmacros,chemformula}
\usepackage{lmodern}
\usetikzlibrary{decorations.pathmorphing}
\chemsetup[chemformula]{font-shape=sf,format=\sffamily}
\chemsetup[option]{circletype=math}
\renewcommand*{\familydefault}{\sfdefault}
\renewcommand*\printatom[1]{\ensuremath{\mathsf{#1}}}
\setatomsep{1.8em}
\setdoublesep{.6ex}
\setarrowdefault{,.8,semithick}
\setbondstyle{thick}
\makeatother
\begin{document}
\definesubmol\nobond{-[,0.2,,,draw=none]}
\schemestart
\chemfig{PPO-[::30]-[2]=^[::60](-[::60])-[2]-[::-60]-[::-60]=^[::60](-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow
\chemfig{@{d21}\fmch OPP-[::30,.2,,,draw=none]-[2,,,,draw=none](-[@{d24}::-60](!\nobond\fpch))=_[@{d23}::60]@{d22}(-[::60])-[2]-[::-60]-[::-60]=^[::60](-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow
\chemfig{@{d32}OPP-[@{d31}2,1.2,1](-[:-150])(-[@{d34}:-30]=^[@{d33}::60]@{d36})-[2]-[::-60]-[::-60]=^[@{d35}::60](-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)(<[@{d41}:20]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60]@{d42}(!\nobond\fpch)(-[2])-[::-60]-[6]-[::-60]=^[6](-[::60])-[::-60]}
\arrow[-110]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60]@{d52}(<:[6]H)(!\nobond\fpch)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60]=_[@{d51}6](-[::60])-[::-60]}
\arrow[180]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](-[6,.4,,,draw=none]\fpch)(-[@{d62}::60]-[@{d61}::60]H)-[::-60]}
\arrow[180]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60]}
\arrow[-90]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60]-[::-60]HO}
\arrow[,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60]=_[::-60]O}
\arrow[,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60](-[6]OH)=[::-60]O}
\arrow(@c8--)[-90,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](<[::60])-[::-60]-[::-65]HO}
\arrow(@c9--)[-90,,dashed]
\chemfig{-[::30,.2,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](<[::60])-[::-60]=_[::-60]O}
\arrow(@c10--)[-90,.6,dashed]
\chemfig{@{d132}O=[@{d131}]@{d134}O-[::30,.7,,,draw=none]-[2,,,,draw=none](-[::-60](<:[6]H)-[2](<:[2]H))=_[@{d133}::60](-[::60])-[2]-[::-60]-[::-60]-[::60](<[:20]H)(<:[2])-[::-60]-[6]-[::-60](-[::-60])<[6](=[::60])-[::-60](-[6]OH)=[::-60]O}
\arrow[-55,.7]
\chemfig{*6((-[4])(<:[:-135]O-[::60]OH)--(*6(-(<(<[::60])-[::-60](-[::60]OH)=[::-60]O)---(<:[2])(<[:20]H)-))(<:[6]H)-(<:[2]H)---) }
\arrow[180]
\subscheme{
\chemfig{H_2O}
\arrow[-30,.1,draw=none]
\chemfig{*6((-[@{d172}4])(<:[:-135]@{d174}O-[@{d175}::60]@{d176}OH)-[@{d173}]-(*6(-(<(<[::60])-[::-60](-[::60]OH)=[::-60]O)---(<:[2])(<[:20]H)-))----) }
}
\arrow[180]
\chemfig{[:-25.71]*7((-[::-120])(-OH)-O-=(*6(-(<(<[::60])-[::-60](-[::60]OH)=[::-60]O)---(<:[2])(<[:20]H)-))-(<:[2]H)---) }
\arrow[180]
\chemfig{-[:30](=[::60]O)-[::-60]-[::60]-[::-60](*6(-(-=^[::60]O)-(<(<[::60])-[::-60]HO_2C)---(<:[2])(<[:20]H)-))<:[2]H}
\arrow{->[*0{\ch{O2}}]}[-90]
\chemfig{-[:30]@{d202}(=[::60]O)-[::-60]-[::60]-[::-60](*6(-(-[:150]H|@{d201}O|O)(-=^[::60]O)-(<(<[::60])-[::-60]HO_2C)---(<:[2])(<[:20]H)-))<:[2]H}
\arrow[,1]
\chemfig{[:-25.71]*7((-[::-120]H|@{d211}O)(-)(<:[:20]O?)-[,,,,draw=none]-[,,,,draw=none]@{d212}(=^[@{d213}6]O)-(<:[180]O?)(*6(-(<(<[::60])-[::-60]HO_2|@{d214}C)---(<:[2])(<[:20]H)-))-(<:[2]H)---) }
\arrow[,1]
\chemfig{[:-25.71]*7((<)(<:[:20]O?[a])-O-(<:[6]O?[b])-(<:[180]O?[a])(*6(-(<(<[::60])-[::-60]?[b]=[::60]O)---(<:[2])(<[:20]H)-))-(<:[2]H)---) }
\chemmove[-stealth, shorten >=2pt, shorten <=2pt]{
\draw (d21) .. controls +(north west:12mm) and +(north west:5mm) .. (d22);
\draw (d23) .. controls +(north:5mm) and +(north:5mm) .. (d24);
\draw (d31) .. controls +(west:5mm) and +(north west:5mm) .. (d32);
\draw (d33) .. controls +(north:5mm) and +(north:5mm) .. (d34);
\draw (d35) .. controls +(south:5mm) and +(north east:5mm) .. (d36);
\draw (d41) .. controls +(north:5mm) and +(south:5mm) .. (d42);
\draw (d51) .. controls +(west:5mm) and +(south east:5mm) .. (d52);
\draw (d61) .. controls +(north:5mm) and +(north east:5mm) .. (d62);
\draw (d131) .. controls +(north:5mm) and +(north:5mm) .. (d132);
\draw (d133) .. controls +(south west:5mm) and +(north:5mm) .. (d134);
\draw (c16) .. controls +(north east:15mm) and +(north:5mm) .. (d172);
\draw (d173) .. controls +(south:5mm) and +(east:5mm) .. (d174);
\draw (d175) .. controls +(west:5mm) and +(west:5mm) .. (d176);
\draw (d201) .. controls +(south:5mm) and +(south:5mm) .. (d202);
\draw (d211) .. controls +(south:5mm) and +(west:5mm) .. (d212);
\draw (d213) .. controls +(east:5mm) and +(north:5mm) .. (d214);
}
\schemestop
\end{document}
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Licensing
I, the copyright holder of this work, hereby publish it under the following license:
This file is licensed under the Creative Commons Attribution-Share Alike 4.0 International license.
- You are free:
- to share – to copy, distribute and transmit the work
- to remix – to adapt the work
- Under the following conditions:
- attribution – You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- share alike – If you remix, transform, or build upon the material, you must distribute your contributions under the same or compatible license as the original.
File history
Click on a date/time to view the file as it appeared at that time.
| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 15:34, 11 April 2015 | | 724 × 1,000 (99 KB) | Krishnavedala | optimized regenering using dvisvgm |
| 15:25, 16 October 2014 |  | 754 × 1,069 (165 KB) | Krishnavedala | User created page with UploadWizard |
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