Boroantimonate

Boroantimonates are chemical compounds in which borate and antimonate groups share oxygen atoms. Known compounds are transparent. Antimony is in the +5 oxidation state and is in octahedral coordination by oxygen.^[1]

List

formula	mw	crystal system	space group	unit cell Å	volume	density	comment	references
SbB₃O₆	414.11	monoclinic	C2	a=7.143 b=4.953 c=6.393 β=105.70 Z=2	217.71	3.816	band gap 4.083 eV; birefringence Δn=0.290 at 546 nm; NLO 3.5 × KH₂PO₄	^[2]
Na₂SbB₃O₈	328.16	monoclinic	P2₁/c	a=5.8278 b=10.3521 c=10.4775 β=102.948° Z=4	616.04	3.538	colourless	^[3]
KSbB₂O₆		monoclinic	Cc	a=11.458 b=7.019 c=7.324 β=124.413°				^[4]
K₂SbB₃O₈	360.38	monoclinic	P2₁/c	a=5.9013 b=11.088 c=10.950 β=103.218° Z=4	697.5	3.432	colourless	^[3]^[5]
α-K₃Sb₄BO₁₃	823.11	monoclinic	C2/m	a=12.2032 b=7.4881 c=13.070 β=101.636° Z=4	1169.8	4.674	200K	^[6]
β-K₃Sb₄BO₁₃	823.11	triclinic	P1	a=7.1168 b=7.211 c=13.2218 α=81.923 β=99.760 γ=117.10 Z=2	593.79	4.602	250K	^[6]
β-RbSbB₂O₆	324.84	monoclinic	Cc	a=11.715 b=7.1633 c=7.4109 β=125.43°	506.71	4.258	colourless	^[3]
Rb₂SbB₃O₈	453.12	monoclinic	P2₁/c	a=5.9381 b=11.2928 c=11.318 β=103.7° Z=4	737.2	4.083	colourless	^[3]
KRb₂Sb₄BO₁₃	916.31	triclinic	P1	a=7.1456 b=7.2390 c=13.4113 α=82.058 β=100.051 γ=117.205 Z=2	606.16	5.020	colourless	^[7]
Rb₃Sb₄BO₁₃	962.22	triclinic	P1	a=7.1593 b=7.2533 c=13.4894 α=82.358° β=99.999° γ=117.321° Z=2	611.75	5.224	colourless	^[7]
BaSb₂B₄O₁₂		monoclinic	C2/c	a=6.9818 b=11.8452 c=11.089 β=102.772°				^[4]
SmBSb₂O₈		orthorhombic	Pnma	a=12.6155 b=7.2702 c=12.7086				^[8]
EuBSb₂O₈		orthorhombic	Pnma	a=12.5730 b=7.2605 c=12.6920				^[8]
GdBSb₂O₈		orthorhombic	Pnma	a=12.5594 b=7.2369 c=12.6913				^[8]
TbBSb₂O₈		orthorhombic	Pnma	a=12.532 b=7.236 c=12.671				^[8]

References

^ Kong, Fang; Ma, Yunxiang; Mao, Jianggao (January 2018). "Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations". Chinese Journal of Chemistry. 36 (1): 63–72. doi:10.1002/cjoc.201700597.
^ Liu, Youchao; Liu, Xiaomeng; Liu, Shuai; Ding, Qingran; Li, Yanqiang; Li, Lina; Zhao, Sangen; Lin, Zheshuai; Luo, Junhua; Hong, Maochun (2020-05-11). "An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses". Angewandte Chemie International Edition. 59 (20): 7793–7796. doi:10.1002/anie.202001042. ISSN 1433-7851. PMID 32056339.
^ ^a ^b ^c ^d Yan, Dong; Hu, Chun-Li; Mao, Jiang-Gao (2016). "A 2 SbB 3 O 8 (A = Na, K, Rb) and β-RbSbB 2 O 6 : two types of alkali boroantimonates with 3D anionic architectures composed of SbO 6 octahedra and borate groups". CrystEngComm. 18 (9): 1655–1664. doi:10.1039/C5CE02324F. ISSN 1466-8033.
^ ^a ^b Huang, Chao; Zhang, Jian-Han; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2014-04-07). "KSbB 2 O 6 and BaSb 2 B 4 O 12 : Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO 6 Octahedra and B 2 O 5 Groups". Inorganic Chemistry. 53 (7): 3847–3853. doi:10.1021/ic5001842. ISSN 0020-1669. PMID 24665931.
^ "K2SbB3O8： A Novel Boroantimonate)with Isolated [B3O8]^7- Groups". Chinese Journal of Structural Chemistry. 2016.
^ ^a ^b Quarez, Eric; Gautron, Eric; Paris, Michael; Gajan, David; Mevellec, Jean-Yves (15 February 2021). "Toward the Coordination Fingerprint of the Edge-Sharing BO 4 Tetrahedra" (PDF). Inorganic Chemistry. 60 (4): 2406–2413. doi:10.1021/acs.inorgchem.0c03272. PMID 33478208.
^ ^a ^b Doux, Jean-Marie; Stephant, Nicolas; La Salle, Annie Le Gal; Joubert, Olivier; Guyomard, Dominique; Quarez, Eric (2019). "New KRb 2 Sb 4 BO 13 and Rb 3 Sb 4 BO 13 compounds prepared by Rb + /K + ion exchange from the K 3 Sb 4 BO 13 ion conductor". CrystEngComm. 21 (4): 594–601. doi:10.1039/C8CE01712C. ISSN 1466-8033.
^ ^a ^b ^c ^d Yan, Dong; Mao, Fei-Fei; Mao, Jiang-Gao (2016-10-17). "LnBSb 2 O 8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures". Inorganic Chemistry. 55 (20): 10558–10566. doi:10.1021/acs.inorgchem.6b01790. ISSN 0020-1669. PMID 27690146.

[1] Kong, Fang; Ma, Yunxiang; Mao, Jianggao (January 2018). "Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations". Chinese Journal of Chemistry. 36 (1): 63–72. doi:10.1002/cjoc.201700597.

[2] Liu, Youchao; Liu, Xiaomeng; Liu, Shuai; Ding, Qingran; Li, Yanqiang; Li, Lina; Zhao, Sangen; Lin, Zheshuai; Luo, Junhua; Hong, Maochun (2020-05-11). "An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses". Angewandte Chemie International Edition. 59 (20): 7793–7796. doi:10.1002/anie.202001042. ISSN 1433-7851. PMID 32056339.

[:3-3] Yan, Dong; Hu, Chun-Li; Mao, Jiang-Gao (2016). "A 2 SbB 3 O 8 (A = Na, K, Rb) and β-RbSbB 2 O 6 : two types of alkali boroantimonates with 3D anionic architectures composed of SbO 6 octahedra and borate groups". CrystEngComm. 18 (9): 1655–1664. doi:10.1039/C5CE02324F. ISSN 1466-8033.

[:4-4] Huang, Chao; Zhang, Jian-Han; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2014-04-07). "KSbB 2 O 6 and BaSb 2 B 4 O 12 : Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO 6 Octahedra and B 2 O 5 Groups". Inorganic Chemistry. 53 (7): 3847–3853. doi:10.1021/ic5001842. ISSN 0020-1669. PMID 24665931.

[5] "K2SbB3O8： A Novel Boroantimonate)with Isolated [B3O8]^7- Groups". Chinese Journal of Structural Chemistry. 2016.

[:0-6] Quarez, Eric; Gautron, Eric; Paris, Michael; Gajan, David; Mevellec, Jean-Yves (15 February 2021). "Toward the Coordination Fingerprint of the Edge-Sharing BO 4 Tetrahedra" (PDF). Inorganic Chemistry. 60 (4): 2406–2413. doi:10.1021/acs.inorgchem.0c03272. PMID 33478208.

[:1-7] Doux, Jean-Marie; Stephant, Nicolas; La Salle, Annie Le Gal; Joubert, Olivier; Guyomard, Dominique; Quarez, Eric (2019). "New KRb 2 Sb 4 BO 13 and Rb 3 Sb 4 BO 13 compounds prepared by Rb + /K + ion exchange from the K 3 Sb 4 BO 13 ion conductor". CrystEngComm. 21 (4): 594–601. doi:10.1039/C8CE01712C. ISSN 1466-8033.

[:2-8] Yan, Dong; Mao, Fei-Fei; Mao, Jiang-Gao (2016-10-17). "LnBSb 2 O 8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures". Inorganic Chemistry. 55 (20): 10558–10566. doi:10.1021/acs.inorgchem.6b01790. ISSN 0020-1669. PMID 27690146.

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